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Ultra thin perovskite solar cell for over 30% tandem solar cell and light confining bonding technology

Research Project

Project/Area Number 16H02451
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

Ihara Manabu  東京工業大学, 物質理工学院, 教授 (90270884)

Project Period (FY) 2016-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥44,070,000 (Direct Cost: ¥33,900,000、Indirect Cost: ¥10,170,000)
Fiscal Year 2020: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2019: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2018: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2017: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Fiscal Year 2016: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywordssolar cell / tandem solar cell / monocrystalline thin Si / perovskite / passivation / タンデム太陽電池 / ペロブスカイト太陽電池 / 単結晶シリコン太陽電池 / パッシベーション / 大粒径化 / 工学 / エネルギー生成・変換 / 総合工学 / エネルギー学
Outline of Final Research Achievements

To achieve the solar cell with above 30% conversion efficiency, to develop the tandem solar cells which have the multiple power generation layers is necessary with different bandgaps with minimizing the efficiency loss at top cells, bottom cells and their interface. The method to independently control the grain size of perovskite thin film was developed and the effect of grain size on the efficiency of perovskite solar cell was clarified. To reduce the cost of monocrystalline Si bottom cell, the fabrication process of wafer level thin monocrystalline Si was developed by nanometer-level smoothing of porous Si underlayer and the epitaxy by rapid vapor deposition on it. As for the Si/perovskite interface, the effect of thermal annealing process on the TiO2 interlayer was investigated which works as the passivation layer of the bottom Si surface and the electron transfer layer of perovskite top cell.

Academic Significance and Societal Importance of the Research Achievements

太陽電池の効率30%超を達成するためのタンデム太陽電池の開発は、脱炭素電源の主力化に向けて重要である。また、本研究の各項目において得られた学術的な意義は大きい。ペロブスカイト太陽電池においては、これまでできていなかった、発電効率に他の要素を一定にして結晶粒径のみを変化させる手法を確立し、発電特性との直接の関連性をはじめて明らかにした。Si単結晶薄膜製造プロセスでは、結晶化しながら急速に堆積する本プロセスにおいて、原子レベルの凹凸の違いが得られる単結晶の欠陥密度に大きな影響を与えるという、結晶学的に重要な知見となった。

Report

(6 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Annual Research Report
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (55 results)

All 2021 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 4 results) Presentation (46 results) (of which Int'l Joint Research: 19 results,  Invited: 3 results) Remarks (1 results)

  • [Int'l Joint Research] フランス国立応用科学院リヨン校(Insa de Lyon, リヨン大学)(フランス)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] フランス国立応用科学院リヨン 校(INSA de Lyon, リヨン大学)(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] フランス国立応用科学院リヨン校(INSA de Lyon, リヨン大学)(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] フランス国立応用科学院リヨン校(INSA de Lyon, リヨン大学)(フランス)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Nanostructure of Porous Si and Anodic SiO2 Surface Passivation for Improved Efficiency Porous Si Solar Cells2021

    • Author(s)
      Sundarapura Panus、Zhang Xiao-Mei、Yogai Ryoji、Murakami Kazuki、Fave Alain、Ihara Manabu
    • Journal Title

      Nanomaterials

      Volume: 11 Issue: 2 Pages: 459-459

    • DOI

      10.3390/nano11020459

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dominant effect of the grain size of the MAPbI3 perovskite controlled by the surface roughness of TiO2 on the performance of perovskite solar cells2020

    • Author(s)
      Nukunudompanich Methawee、Budiutama Gekko、Suzuki Kazuma、Hasegawa Kei、Ihara Manabu
    • Journal Title

      CrystEngComm

      Volume: 22 Issue: 16 Pages: 2718-2727

    • DOI

      10.1039/d0ce00169d

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Critical effect of nanometer-size surface roughness of a porous Si seed layer on the defect density of epitaxial Si films for solar cells by rapid vapor deposition2018

    • Author(s)
      Hasegawa Kei、Takazawa Chiaki、Fujita Makoto、Noda Suguru、Ihara Manabu
    • Journal Title

      CrystEngComm

      Volume: 20 Issue: 13 Pages: 1774-1778

    • DOI

      10.1039/c7ce02162c

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Free-standing epitaxial silicon thin films for solar cells grown on double porous layers of silicon and electrochemically oxidized porous silicon dioxide2018

    • Author(s)
      Anatolii Lukianov and Manabu Ihara
    • Journal Title

      Thin Solid Films

      Volume: 648 Pages: 1-7

    • DOI

      10.1016/j.tsf.2017.12.025

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] PASSIVATION OF Si/TiO2 USING SiOx INTERFACIAL LAYER BY ZONE HEATING RECRYSTALLIZATION FOR 2-TERMINAL PEROVSKITE/SI TANDEM SOLAR CELL2020

    • Author(s)
      Gekko Budiutama, Kei Hasegawa, Manabu Ihara
    • Organizer
      The 30th International Photovoltaic Science and Engineering Conference (PVSEC-30) & Global Photovoltaic Conference 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Formation of Intermediate SiO2 nano-Layer As Effective Passivation at Si/TiO2 Interface By Zone Heating Recrystallization Toward Perovskite/Silicon Tandem Solar Cell2020

    • Author(s)
      G. P. Budiutama, K. Hasegawa, and M. Ihara
    • Organizer
      ECS(PRiME2020)
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Passivation of Si-TiO2 Interface Using Controlled SiOx Layer by Zone Heating Recrystallization for Perovskite/Silicon Tandem Solar Cell2020

    • Author(s)
      Gekko Patria Budiutama, Kei Hasegawa, Manabu Ihara
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ゾーンヒーティング再結晶法によるペロブスカイト太陽電池光吸収層の大粒径化と発電特性の関係2020

    • Author(s)
      鈴木 一馬、Budiutama Gekko、長谷川 馨、伊原 学
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ナノ表面粗さ制御によるウエハレベル太陽電池用Si膜の高速成膜2019

    • Author(s)
      伊原学
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Correlation of surface roughness of TiO2, grain size of MAPbI3 and perovskite solar cell performance2019

    • Author(s)
      Methawee Nukunudompanich, Kazuma Suzuki, Kei Hasegawa, Manabu Ihara
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ゾーンヒーティング再結晶法によるペロブスカイト太陽電池光吸収層大粒径化の検討2019

    • Author(s)
      鈴木一馬, Nukunudompanich Methawee, 長谷川馨, 伊原学
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Study of Si/TiO2/Perovskite interfaces for perovskite/Si tandem solar cell2019

    • Author(s)
      Budiutama Gekko, Suzuki Kazuma, Nukunudompanich Methawee, Hasegawa Kei, Zhang Xiaomei, Fourmond Erwann, Fave Alain, Ihara Manabu
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Surface Passivation of Porous Silicon for Tandem Solar Cell2019

    • Author(s)
      Sundarapura Panus, Yogai Ryoji, Zhang Xiaomei, Hasegawa Kei, Fourmond Erwann, Fave Alain, Ihara Manabu
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical properties of monocrystalline Si film for solar cells fabricated by nano-surface controlling double layer porous Si in H2 atmosphere2019

    • Author(s)
      Ryotaro Shibahara, Kei Hasegawa, Alain Fave, Erwann Fourmond, Suguru Noda and Manabu Ihara
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] p-Type Doped Large-Area Multilayer MoS2 Enabled by Mild Plasma Treatment for Phototransistors Application2019

    • Author(s)
      Zhang Xiaomei, Sian-Hong TSENG, Ming-Yen LU
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical Properties of Monocrystalline Thin Film Si for Solar Cells Fabricated By Rapid Vapor Deposition with Nano-Surface Controlling Double Layer Porous Si in H22019

    • Author(s)
      R. Shibahara, K. Hasegawa, A. Fave, E. Fourmond, S. Noda, and M. Ihara
    • Organizer
      236th ECS Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノレベルで荒さ制御した下地への急速蒸着で作製したウェハー級の太陽電池用薄層Si2019

    • Author(s)
      長谷川 馨、柴原 竜太朗、松浦 明、高澤 千明、Fave Alain、Fourmond Erwann、野田 優、伊原 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2層多孔質Si基板ナノ表面制御と超高速成膜による太陽電池用薄膜Siの電気特性評価2019

    • Author(s)
      柴原 竜太朗、長谷川 馨、Fave Alain、Fourmond Erwann、野田 優、伊原 学
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Electrochemical Passivation of Nano-Porous Silicon Solar Cell2019

    • Author(s)
      Sundarapura Panus, Zhang Xiaomei, Hasegawa Kei, Ihara Manabu
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Investigation of Si/TiO2/Perovskite interfaces for tandem solar cells2019

    • Author(s)
      Budiutama Gekko Patria, Suzuki Kazuma, Nukunudompanich Methawee, Hasegawa Kei, Zhang Xiaomei, Ihara Manabu
    • Organizer
      化学工学会第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] タンデム化にむけたペロブスカイト太陽電池光吸収層の二次元結晶成長手法と構造解析2018

    • Author(s)
      鈴木 一馬、長谷川 馨、伊原 学
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Correlation between TiO2 roughness and perovskite grain size effect on solar cell performance2018

    • Author(s)
      Nukunudompanich Methawee, Suzuki Kazuma, Hasegawa Kei, Ihara Manabu
    • Organizer
      第50回化学工学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Influence of Perovskite Grain Size and TiO2 Surface States to the Performance of Perovskite Solar Cell2018

    • Author(s)
      Nukunudompanich Methawee, Suzuki Kazuma, Hasegawa Kei, Ihara Manabu
    • Organizer
      234th ECS and SMEQ2018 Joint International Meeting (AiMES 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Relationship between Suface state of compact TiO2, the grain size of Perovskite layer and the performance of Perovskite solar cell2018

    • Author(s)
      Nukunudompanich Methawee, Suzuki Kazuma, Hasegawa Kei, Ihara Manabu
    • Organizer
      The Asia-Oceania Top University League on Engineering (AOTULE 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plasma-Assisted Fabrication and Gate-Tunable Transport Properties of 'In-Depth' Doped MoS2 Vertical Homostructure2018

    • Author(s)
      X. M. Zhang, and M. Ihara
    • Organizer
      2018 MRS Fall Meeting & Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Monocrystalline Si Thin Film By High Speed Zone Melting / Heating Crystallization with Controlling Nano-Surface Roughness for Cost-Cutting Solar Cells with High Efficiency2018

    • Author(s)
      伊原学
    • Organizer
      234th ECS and SMEQ2018 Joint International Meeting (AiMES 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポーラスシリコンのナノ構造を利用した低コスト、高効率太陽電池へのアプローチ --低コスト剥離およびタンデムトップセルを目指して--2018

    • Author(s)
      伊原学
    • Organizer
      第100回ARS例会, 一般社団法人 表面技術協会 金属のアノード酸化皮膜の機能化部会(ARS)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 単結晶薄膜 Si 太陽電池作製のための2層多孔質Si基板のナノ表面制御と超高速成膜の評価2017

    • Author(s)
      松浦 明, 高澤 千明, 藤田 誠, 長谷川 馨, 野田 優, 伊原 学
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属ナノ粒子の形状変化による局所電場制御とプラズモニック太陽電池への応用2017

    • Author(s)
      用貝 亮二,村上 和生,長谷川 馨,張 暁梅,伊原 学
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] ペロブスカイト太陽電池の高効率化へ向けた光吸収層の結晶粒径制御と電池特性への影響2017

    • Author(s)
      鈴木 一馬, Nukunudompanich M. 長谷川 馨, 伊原 学
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] ペロブスカイト薄膜タンデム太陽電池に向けた光吸収層の二次元結晶成長手法の検討2017

    • Author(s)
      鈴木 一馬、長谷川 馨、伊原 学
    • Organizer
      第49回 化学工学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 多孔基板のナノ平滑化による高速で低欠陥な太陽電池用単結晶薄膜Siの作製2017

    • Author(s)
      長谷川 馨、高澤 千明、藤田 誠、野田 優、伊原 学
    • Organizer
      第49回 化学工学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of nano-roughness of compacted TiO2 layer by using various precursors and deposition techniques on characteristics of perovskite solar cell2017

    • Author(s)
      Nukunudompanich Methawee、Phaomethavarithorn Apatsanan、鈴木 一馬、長谷川 馨、伊原 学
    • Organizer
      第49回 化学工学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Monocrystalline Si Thin Film for Solar Cells Grown on Double Layer Porous Si Treated By Zone Heating Recrystallization2017

    • Author(s)
      K. Hasegawa, C. Takazawa, M. Fujita, S. Noda, and M. Ihara
    • Organizer
      232th ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of Reaction Conditions with Methylammonium Iodide on the Grain of CH3NH3PbI3 Perovskite for Thin Top Cell of Tandem Solar Cells2017

    • Author(s)
      K. Suzuki, K. Hasegawa, and M. Ihara
    • Organizer
      232th ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Zero and Two-Dimensional Nanomaterials Towards Solar Cells Applications2017

    • Author(s)
      Zhang Xiao-Mei, M. Ihara
    • Organizer
      Nano Science and Technology-2017 (Nano S&T-2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Temperature Dependence on Spray Pyrolysis of TiO2 and Its Perovskite Solar Cell Application2017

    • Author(s)
      Methawee Nukunudompanich, Kazuma Suzuki , Kei Hasegawa, and Manabu Ihara
    • Organizer
      The Sixth International Education Forum on Environment and Energy Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of 2-dimentional crystal growth of the light absorbing layer for perovskite thin film tandem solar cell2017

    • Author(s)
      Kazuma Suzuki, Kei Hasegawa, and Manabu Ihara
    • Organizer
      The Sixth International Education Forum on Environment and Energy Science
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポーラスシリコン太陽電池におけるナノ構造の役割の検討2017

    • Author(s)
      用貝 亮二、村上 和生、張 暁梅、長谷川 馨、伊原 学
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 単結晶薄膜 Si 太陽電池作製に向けた2層多孔質Si基板のナノ表面制御と超高速成膜により得られたSi 薄膜特性の評価2017

    • Author(s)
      松浦 明、柴原 竜太朗、藤田 誠、高澤 千明、長谷川 馨、野田 優、伊原 学
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高速成膜法による単結晶薄膜Si太陽電池の作製とSi薄膜の電気特性評価2017

    • Author(s)
      柴原 竜太朗、松浦 明、高澤 千明、藤田 誠、長谷川 馨、野田 優、伊原 学
    • Organizer
      化学工学会第83年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ペロブスカイト/Siタンデム太陽電池に向けたトップセル光吸収層薄膜の二次元結晶成長手法の検討2017

    • Author(s)
      鈴木 一馬、Nukunudompanich Methawee、長谷川 馨、伊原 学
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] タンデム太陽電池への応用に向けたスプレー法によるTiO2緻密層の検討と界面への影響2017

    • Author(s)
      Nukunudompanich Methawee、鈴木 一馬、長谷川 馨、FOURMOND Erwann、FAVE Alain、伊原 学
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Shape and size control of indium nanoparticles intended for silicon solar cells application2016

    • Author(s)
      X. M. Zhang, R. Yogai, and M. Ihara
    • Organizer
      MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, U.S.A
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] One-pot solution synthesis of indium nanoparticles and their application in solar cell devices2016

    • Author(s)
      X. M. Zhang, R. Yogai, and M. Ihara
    • Organizer
      Nano S&T
    • Place of Presentation
      Singapore
    • Year and Date
      2016-10-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Epitaxial growth of silicon nanowire arrays at wafer-scale using high-speed rotating-disk CVD for improved light-trapping2016

    • Author(s)
      X. M. Zhang and M. Ihara
    • Organizer
      Asia NANO
    • Place of Presentation
      札幌
    • Year and Date
      2016-10-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nano-Scale Smoothing of Double Layer Porous Si Substrates for Detaching and Fabricating Low Cost, High Efficiency Monocrystalline Thin Film Si Solar Cell By Zone Scanning Annealing2016

    • Author(s)
      C. Takazawa, K. Hasegawa, A. Lukianov, X. Zhang, and M. Ihara
    • Organizer
      230th ECS Meeting Honolulu
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] タンデム化に向けた長波長側で光透過な薄膜ペロブスカイト太陽電池の検討2016

    • Author(s)
      鈴木一馬, トーベンジャミン, 長谷川馨, 伊原学
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] プラズモニックポーラスSi太陽電池に向けたナノ細孔中への金属ナノ粒子と酸化膜の導入2016

    • Author(s)
      村上和生, 長谷川馨, 伊原学
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単結晶薄膜 Si 太陽電池作製に向けたエピタキシャル成長用ポーラス Si のナノ表面平滑化2016

    • Author(s)
      高澤千明, 藤田誠(早大先進理工), 長谷川馨, A. Lukianov, 野田優(早大先進理工), 伊原学
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Remarks] 伊原・Manzhos研究室ホームページ

    • URL

      http://www.chemeng.titech.ac.jp/~iharalab/index.html

    • Related Report
      2020 Annual Research Report

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Published: 2016-04-21   Modified: 2022-01-27  

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