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Research of chlorine in biogenic carbonate as an novel proxy of nutrient.

Research Project

Project/Area Number 16H02950
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionJapan Synchrotron Radiation Research Institute

Principal Investigator

TAMENORI Yusuke  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 主席研究員 (10360819)

Co-Investigator(Kenkyū-buntansha) 吉村 寿紘  国立研究開発法人海洋研究開発機構, 生物地球化学研究分野, 研究員 (90710070)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2018: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Keywords生物炭酸塩 / 二枚貝 / 微量元素 / 環境指標 / 塩素 / 放射光軟X線 / 顕微分光測定 / 古環境解析 / 放射光軟X線 / スペシエーション / 二枚貝殻 / 同位体分析 / 軟X線顕微分光 / 古環境分析 / 古環境 / 塩素同位体
Outline of Final Research Achievements

For the purpose of novel proxy development to the research of nutrient dynamics in the sea, we investigated the chlorine (Cl) distribution in the shell of bivalve (Pseudocardium sachalinense) by synchrotron microscopy. The distribution of Cl was associated with the formation of growth lines, and it was enhanced in the early stage. Time scale analysis suggested that the Cl in the shell of bivalve was not an appropriate paleological proxy but the record of bivalve growth.
High-throughput purification technique with an ion chromatograph coupled to an automated fraction collector has been developed for complete separation of dissolved elements in environmental samples for isotopic measurements. The purification method enables multi-isotope analysis of a sample using various mass spectrometry techniques, such as multiple-collector inductively coupled plasma and thermal ionization mass spectrometry.

Academic Significance and Societal Importance of the Research Achievements

生物が形成する代表的な炭酸塩鉱物である二枚貝の殻には、成長線と相関した微量元素濃度の変化として、貝の成長あるいは生育の履歴が記録されていることを見いだした。本成果を応用することにより、貝などの海産生物の成育記録を貝自身から読み解くことができる可能性が示唆され、今後、天然資源の管理や養殖などの水産業への応用が期待できる。
本研究の同位体分析研究で開発された高精度な元素単離法は、古気候・古環境分野にとどまらず、地球化学・海洋学・環境分析・惑星科学など、同位体組成を分析指標として利用している様々な研究分野に対して広く貢献するものと期待される

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (22 results)

All 2019 2018 2017 2016

All Journal Article (13 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 13 results,  Open Access: 1 results,  Acknowledgement Compliant: 4 results) Presentation (7 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results) Book (2 results)

  • [Journal Article] Sulfur speciation in growth layers of shell cross section of the long-lived bivalve Margaritifera laevis using synchrotron spectromicroscopy analysis2018

    • Author(s)
      Y. Tamenori、T. Yoshimura
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 237 Pages: 357-369

    • DOI

      10.1016/j.gca.2018.07.002

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] XANES spectra of forsterite in crystal, surface, and amorphous states2018

    • Author(s)
      O. Takahashi, Y. Tamenori, T. Suenaga, T. Ikeda- Fukazawa, J. Matsuno, and A. Tsuchiyama
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 2 Pages: 025107-025107

    • DOI

      10.1063/1.5017245

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reusable Immobilized Iron(II) Nanoparticle Pre-Catalysts for Ligand-Free Kumada Coupling2018

    • Author(s)
      Toshiki Akiyama, Yuki Wada, Kellie Jenkinson, Tetsuo Honma, Kazuki Tsuruta, Yusuke Tamenori, Hitoshi Haneoka, Tsunayoshi Takehara, Takeyuki Suzuki, Kenichi Murai, Hiromichi Fujioka, Yoshihiro Sato, Andrew E. H. Wheatley, Mitsuhiro Arisawa
    • Journal Title

      Acs Applied Nano Materials

      Volume: 1 Issue: 12 Pages: 6950-6958

    • DOI

      10.1021/acsanm.8b01742

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X-ray absorption near edge structure analysis of the charge-discharge mechanisms of dithiobiuret polymer used as a high-capacity cathode material for lithium-ion batteries2018

    • Author(s)
      H. Uemachi, Y. Tamenori, T. Itono, T. Masuda, T. Shimoda, A. Fujiwara
    • Journal Title

      Electrochimica Acta

      Volume: 281 Pages: 99-108

    • DOI

      10.1016/j.electacta.2018.05.137

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lithium, magnesium and sulfur purification from seawater using an ion chromatograph with a fraction collector system for stable isotope measurements2018

    • Author(s)
      Yoshimura Toshihiro、Araoka Daisuke、Tamenori Yusuke、Kuroda Junichiro、Kawahata Hodaka、Ohkouchi Naohiko
    • Journal Title

      Journal of Chromatography A

      Volume: 1531 Pages: 157-162

    • DOI

      10.1016/j.chroma.2017.11.052

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Altervalent substitution of sodium for calcium in biogenic calcite and aragonite2017

    • Author(s)
      Yoshimura, T., Tamenori, Y., Suzuki, A., Kawahata, H., Iwasaki, N., Hasegawa, H., Nguyen, L.T., Kuroyanagi, A., Yamazaki, T., Kuroda, J., Ohkouchi, N.,
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 202 Pages: 21-38

    • DOI

      10.1016/j.gca.2016.12.003

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ligand-free Suzuki?Miyaura coupling using ruthenium(0) nanoparticles and a continuously irradiating microwave system2017

    • Author(s)
      Akiyama Toshiki、Taniguchi Takahisa、Saito Nozomi、Doi Ryohei、Honma Tetsuo、Tamenori Yusuke、Ohki Yuuta、Takahashi Naoyuki、Fujioka Hiromichi、Sato Yoshihiro、Arisawa Mitsuhiro
    • Journal Title

      Green Chemistry

      Volume: 19 Issue: 14 Pages: 3357-3369

    • DOI

      10.1039/c7gc01166k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Evaluation of oxygen isotope and Mg/Ca ratios in high-magnesium calcite from benthic foraminifera as a proxy for water temperature.2016

    • Author(s)
      Maeda, A., Fujita, K., Horikawa, K., Suzuki, A., Yoshimura, T., Tamenori, Y., and Kawahata, H.
    • Journal Title

      Journal of Geophysical Research

      Volume: 122 Issue: 1 Pages: 185-199

    • DOI

      10.1002/2016jg003587

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] An X-ray spectroscopic perspective on Messinian evaporite from Sicily: sedimentary fabrics, element distributions, and chemical environments of S and Mg2016

    • Author(s)
      Toshihiro Yoshimura, Junichiro Kuroda, Stefano Lugli, Yusuke Tamenori, Nanako O. Ogawa, Francisco J. Jiménez-Espejo, Yuta Isaji, Marco Roveri, Vinicio Manzi, Hodaka Kawahata, Naohiko Ohkouchi
    • Journal Title

      Geochemistry Geophysics Geosystems

      Volume: 17 Issue: 4 Pages: 1-18

    • DOI

      10.1002/2015gc006233

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Self-assembled Multi-layer Stabilized Nickel Nanoparticle Catalyst for Ligand-free Cross-coupling Reactions: in situ Metal Nanoparticle and Nanospace Simultaneous Organization2016

    • Author(s)
      Naoyuki Hoshiya, Katsumasa Fujiki, Takahisa Taniguchi, Tetsuo Honma, Yusuke Tamenori, Mincen Xiao, Nozomi Saito, Mami Yokoyama, Akira Ishii, Hiromichi Fujioka, Satoshi Shuto, Yoshihiro Sato, Mitsuhiro Arisawa
    • Journal Title

      Adv. Synth. Catal.

      Volume: 358 Issue: 15 Pages: 2449-2459

    • DOI

      10.1002/adsc.201600024

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] The determining factor for interstitial oxygen formation in Ruddlesden-Popper type La2NiO4-based oxides2016

    • Author(s)
      Takashi Nakamura, Ryo Oike, Yihan Ling, Yusuke Tamenori, and Koji Amezawa
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 18 Issue: 3 Pages: 1564-1569

    • DOI

      10.1039/c5cp05993c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Distribution of sulfur in styrene-butadiene rubber studied with anomalous small-angle X-ray scattering at sulfur K-edge2016

    • Author(s)
      Y. Shinohara, H. Seike, H. Kishimoto, Y. Tamenori, and Y. Amemiya
    • Journal Title

      Polymer

      Volume: 105 Pages: 368-377

    • DOI

      10.1016/j.polymer.2016.06.016

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Realization of two-dimensional anomalous small-angle scattering of Al alloys at theKabsorption edge of Al2016

    • Author(s)
      Okuda Hiroshi、Sakohata Rei、Kitajima Yoshinori、Tamenori Yusuke
    • Journal Title

      Journal of Applied Crystallography

      Volume: 49 Issue: 5 Pages: 1803-1805

    • DOI

      10.1107/s1600576716010669

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大型底生有孔虫のMg同位体比と代替指標としての可能性2019

    • Author(s)
      前田歩,吉村寿紘,荒岡大輔,鈴木淳,為則雄祐,藤田和彦,豊福高志,大河内直彦,川幡穂高
    • Organizer
      日本古生物学会第168回例会
    • Related Report
      2018 Annual Research Report
  • [Presentation] シンチレータと可視光学系を利用した密着型軟X線顕微XAFS装置の開発2018

    • Author(s)
      為則雄祐
    • Organizer
      第21回XAFS討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Recent progress in the application of in-situ and operando soft x-ray spectromicroscopy2018

    • Author(s)
      Y.Tamenori
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 軟X線計測の到達点と次世代光源への展望2018

    • Author(s)
      為則雄祐
    • Organizer
      物性研究所短期研究会「軟X線放射光科学のアップシフト」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 次世代放射光で期待される光源性能とその活用2018

    • Author(s)
      為則雄祐
    • Organizer
      多元物質科学研究所 放射光産学連携準備室 第1回 ワークショップ
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Li, Mg, and S Purification from Seawater Using an Ion Chromatograph with a Fraction Collector System for Stable Isotope Measurements2018

    • Author(s)
      T. Yoshimura, D. Araoka, Y. Tamenori, J. Kuroda H. Kawahata and N. Ohkouchi
    • Organizer
      15th Annual Meeting of Aisa Oceania Geosciences Society
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高輝度軟X線を光源とした散乱・顕微分光観測技術の進展2017

    • Author(s)
      為則雄祐
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Book] 真空科学ハンドブック2018

    • Author(s)
      日本真空学会
    • Total Pages
      590
    • Publisher
      コロナ社
    • ISBN
      9784339009088
    • Related Report
      2017 Annual Research Report
  • [Book] XAFSの基礎と応用2017

    • Author(s)
      日本XAFS研究会
    • Total Pages
      352
    • Publisher
      講談社
    • ISBN
      9784061532953
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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