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Development of advanced separation and removal technology of harmful trace elements contained in solid waste by halogenation volatilization method

Research Project

Project/Area Number 16H02983
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Modeling and technologies for environmental conservation and remediation
Research InstitutionChubu University

Principal Investigator

NINOMIYA Yoshihiko  中部大学, 工学部, 教授 (10164633)

Co-Investigator(Kenkyū-buntansha) 末木 啓介  筑波大学, 数理物質系, 教授 (90187609)
Research Collaborator KINOSHITA Norikazu  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2018: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywordsハロゲン化揮発法 / 放射性セシウム / 希土類元素 / アルカリ金属 / 遷移金属 / 塩化カルシウム / 臭化カルシウム / 分離除去技術 / ハロゲン化揮発 / 分離除去 / 固体廃棄物 / 有害微量元素 / 平衡計算 / 放射性同位体 / 焼却灰 / ホット実験 / Cs-137 / 微量有害元素 / 放射光XAFS
Outline of Final Research Achievements

The purpose of this study was to develop advanced separation and removal technology of harmful trace elements contained in solid waste by halogenation volatilization method. Removal by chlorine or bromide volatilization was examined for about 30 elements such as Cs, Co and Eu contained in combustion ash. Chlorinated volatilization was applied to the contained radioactive cesium (137-Cs) soil samples and clinker collected in Fukushima Prefecture. As a result, it was shown that the value of 137-Cs contained in the sample decreased to about 10% of the original value when treated at a temperature above 1100℃.

Academic Significance and Societal Importance of the Research Achievements

東日本大震災に伴う原子力発電所の事故以降、放射性同位体を持つ半減期が比較的長い有害元素類を含む放射性物質に汚染された可燃性廃棄物から、これらの元素を分離除去する技術の開発が急務になっている。さらに、近年、福島原発の事故を契機に築40年以上の福島原発以外の原子力発電所の廃炉決定が相次いでなされ、廃炉にあたって放射性廃棄物や放射化したコンクリートの処理が大きな課題になっている。Ppbからppmレベルの有害元素を含む廃棄物を塩化・臭素化揮発法によって分離除去し、有害元素含有率を環境許容レベルまで低減できる手法を開発することが求められている。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (9 results)

All 2018 2017 2016

All Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Enhancement of Cs vaporization from simulated granular ash through thermal treatment in N2 atmosphere with the addition of a mixture of CaCl2 and CaO2018

    • Author(s)
      Jiao Facun、Kinoshita Norikazu、Kawaguchi Masato、Asada Motoyuki、Honda Maki、Sueki Keisuke、Ninomiya Yoshihiko
    • Journal Title

      Fuel

      Volume: 214 Pages: 409-415

    • DOI

      10.1016/j.fuel.2017.11.018

    • Related Report
      2018 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synergistic Mechanisms of CaCl2 and CaO on the Vaporization of Cs from Cs-Doped Ash during Thermal Treatment2018

    • Author(s)
      Jiao Facun、Kinoshita Norikazu、Kawaguchi Masato、Asada Motoyuki、Honda Maki、Sueki Keisuke、Ninomiya Yoshihiko、Sergeev Dmitry、Blasing Marc、Muller Michael
    • Journal Title

      Energy & Fuels

      Volume: 32 Issue: 4 Pages: 5433-5442

    • DOI

      10.1021/acs.energyfuels.8b00620

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vaporization Behavior of Cs, K, and Na in Cs-Containing Incineration Bottom Ash during Thermal Treatment with CaCl2 and CaO2017

    • Author(s)
      Jiao Facun、Kinoshita Norikazu、Kawaguchi Masato、Asada Motoyuki、Honda Maki、Sueki Keisuke、Ninomiya Yoshihiko、Sergeev Dmitry、Blasing Marc、Muller Michael
    • Journal Title

      Energy & Fuels

      Volume: 31 Issue: 12 Pages: 14045-14052

    • DOI

      10.1021/acs.energyfuels.7b02930

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Role of CaCl2 and MgCl2 addition in the vaporization of water-insoluble cesium from incineration ash during thermal treatment2017

    • Author(s)
      Facun Jiao, Norikazu Kinoshita, Masato Kawaguchi, Motoyuki Asada, Maki Honda, Keisuke Sueki, Yoshihiko Ninomiya
    • Journal Title

      Chemical Engineering Journal

      Volume: 323 Pages: 114-123

    • DOI

      10.1016/j.cej.2017.04.086

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Vaporization Mechanisms of Water-Insoluble Cs in Ash During Thermal Treatment with Calcium Chloride Addition2016

    • Author(s)
      Facun Jiao, Norie Iwata, Norikazu Kinoshita, Masato Kawaguchi, Motoyuki Asada, Maki Honda, Keisuke Sueki, Yoshihiko Ninomiya
    • Journal Title

      Environmental Science & Technology

      Volume: 50 Issue: 24 Pages: 13328-13334

    • DOI

      10.1021/acs.est.6b03635

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 塩化揮発法を用いた土壌および焼却灰からの放射性セシウム濃度低減2018

    • Author(s)
      木下哲一、焦発存、浅田素之、川口正人、本多真紀、末木啓介、二宮善彦
    • Organizer
      2018日本放射化学会年会・第62回放射化学討論、2B03
    • Related Report
      2018 Annual Research Report
  • [Presentation] Vaporization of alkali metals (Cs, K, Na) in incineration ash during thermal treatment with additives2018

    • Author(s)
      Facun Jiao, Norikazu Kinoshita, Masato Kawaguchi, Motoyuki Asada, Maki Honda, Keisuke Sueki, Yoshihiko Ninomiya, Dmitry Sergeev, Marc Blasing, Michael Muller
    • Organizer
      Impacts of Fuel Quality on Power Production and the Environment, Canada
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 焼却灰中に含まれるセシウムのCa系添加剤による塩化揮発2017

    • Author(s)
      焦発存、二宮善彦、木下哲一、浅田素之、本多 真紀、末木啓介
    • Organizer
      化学工学会第82年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Comparison of the effects of CaCl2 and MgCl2 on the vaporization of Cs in ashes during thermal treatment2016

    • Author(s)
      Facun Jiao, Norie Iwata, Yoshihiko Ninomiya, Norikazu Kinoshita, Motoyuki Asada, Maki Honda
    • Organizer
      化学工学会第48回秋季大会
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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