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Creation of new two-dimensional materials composed with boron

Research Project

Project/Area Number 16H03823
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionUniversity of Tsukuba

Principal Investigator

Kondo Takahiro  筑波大学, 数理物質系, 准教授 (70373305)

Research Collaborator Fujita Takeshi  
Okada Susumu  
Nishibori Eiji  
Nakamura Junji  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2018: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2016: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywords二次元物質 / 硼素 / ホウ化水素 / ボロファン / ボロフェン / 水素貯蔵材料 / 水素吸蔵材料 / ナノマテリアル / 2次元シート / ボロン / ホウ化物 / MgB2 / ナノ材料 / 電子・電気材料
Outline of Final Research Achievements

In this study, we first investigated the reaction mechanism between MgB2 and water. It was found that ion exchange of magnesium cations of MgB2 with protons occurred followed by the hydrolysis reaction, where a sheet material composed by boron was formed during the process. Next, we attempted to form a new boron-based two-dimensional material consisting only of hydrogen and boron by ion-exchanging the magnesium cations of MgB2 with protons and simultaneously suppressing other reactions. The sheet material was successfully formed under mild conditions of room temperature and atmospheric pressure. The sheet material obtained was composed of only a negatively charged boron with two-dimensional sheet structure and protons, and it was found that the stoichiometric ratio was H: B = 1: 1, so it was named "hydrogen boride sheet".

Academic Significance and Societal Importance of the Research Achievements

ホウ化水素シートはプロトンを保持しており、150~1200℃の幅広い温度範囲で水素分子を放出するため、電子材料、水素吸蔵材料、固体燃料、固体酸触媒としての応用が期待できる。今後、既存材料との組み合わせにより資源・エネルギー・環境に関する様々な問題を解決する新材料としての利用が期待されるほか、他の二ホウ化金属やホウ化水素シートをスタート物質として用いることで、別の新しい二次元物質の生成も期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (42 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (27 results) (of which Int'l Joint Research: 12 results,  Invited: 8 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results)

  • [Int'l Joint Research] Universidad Autónoma de Madrid/IMDEA-Nanociencia(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University College London(英国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Alignment-resolved O2 scattering from highly oriented pyrolytic graphite and LiF(001) surfaces2019

    • Author(s)
      Mitsunori Kurahashi and Takahiro Kondo
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 4

    • DOI

      10.1103/physrevb.99.045439

    • NAID

      120007128242

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-energy methane scattering from Pt(111)2018

    • Author(s)
      Takahiro Kondo, Amjad Al Taleb, Gloria Anemone, Daniel Farias
    • Journal Title

      Journal of Chemical Physics

      Volume: 149 Issue: 8

    • DOI

      10.1063/1.5044744

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 水素とホウ素で構成される新しい二次元物質ボロファンの生成2018

    • Author(s)
      近藤剛弘
    • Journal Title

      JXTG Technical Review

      Volume: 60 Pages: 49-53

    • NAID

      40021643713

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 新しいシート状物質「ホウ化水素シート(ボロファン)」2018

    • Author(s)
      近藤剛弘
    • Journal Title

      クリーンエネルギー

      Volume: 27 Pages: 7-13

    • NAID

      40021533133

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Recent progress in boron nanomaterials2017

    • Author(s)
      Takahiro Kondo
    • Journal Title

      Sci. Technol. Adv. Mater.

      Volume: 18 Issue: 1 Pages: 780-804

    • DOI

      10.1080/14686996.2017.1379856

    • NAID

      120007134610

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Formation and characterization of hydrogen boride sheets derived from MgB2 by cation exchange2017

    • Author(s)
      Hiroaki Nishino, Takeshi Fujita, Nguyen Thanh Cuong, Satoshi Tominaka, Masahiro Miyauchi, SoshiIimura, Akihiko Hirata, Naoto Umezawa, Susumu Okada, Eiji Nishibori, Asahi Fujino, TomohiroFujimori, Shin-ichi Ito, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 139 Issue: 39 Pages: 13761-13769

    • DOI

      10.1021/jacs.7b06153

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation Mechanism of Boron-Based Nanosheet through the Reaction of MgB2 with Water2017

    • Author(s)
      Hiroaki Nishino, Takeshi Fujita, Akiyasu Yamamoto, Tomohiro Fujimori, Asahi Fujino, Shin-ichiIto, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Journal Title

      J. Phys. Chem. C

      Volume: 121 Issue: 19 Pages: 10587-10593

    • DOI

      10.1021/acs.jpcc.7b02348

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Hydrogen boride and boron monosulfide2019

    • Author(s)
      Takahiro Kondo
    • Organizer
      First annual symposium of Tokyo Tech- UCL- McGill core-to-core collaboration, Defect Functionalized Sustainable Energy Materials: From Design to Devices Application
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Semi-metallicity of free-standing hydrogenated monolayer boron from MgB22019

    • Author(s)
      I. Tateishi, N. T. Cuong, C.A.S. Moura, M. Cameau, R. Ishibiki, A.Fujino, S. Okada, A. Yamamoto, M. Araki, S. Ito, S. Yamamoto, M. Niibe, T. Tokushima, D.E. Weibel, T. Kondo, M. Ogata and I. Matsuda
    • Organizer
      第13回 日本ホウ素ホウ化物研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホウ化水素シートの熱的安定性2019

    • Author(s)
      石引涼太, 松田巌, 藤野朝日, 伊藤伸一, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      第13回 日本ホウ素ホウ化物研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ~優れた水素吸蔵性能を有する新材料~新規二次元物質ボロファンの合成を実現2019

    • Author(s)
      近藤剛弘
    • Organizer
      第1回筑波大学産学連携シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Catalytic property of hydrogen boride sheets2018

    • Author(s)
      Asahi FUJINO, Hiroaki NISHINO, Ryota ISHIBIKI, Shin-ichi ITO, Tadahiro FUJITANI, Junji NAKAMURA, Hideo HOSONO, Takahiro KONDO
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ホウ化水素シートの触媒特性2018

    • Author(s)
      藤野朝日, 石引涼太, 西野弘晃, 伊藤伸一, 藤谷忠博, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホウ化水素シート上に担持した銅ナノ粒子触媒の調製2018

    • Author(s)
      石引涼太, 藤田武志, 藤野朝日, 伊藤伸一, 宮内雅浩, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Hydrogen Boride Sheets Derived from MgB2 by Cation Exchange2018

    • Author(s)
      Takahiro Kondo
    • Organizer
      Materials Science & Technology 2018 Conference & Exhibition (MS&T'18)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ホウ素を含む新規二次元物質群の創出と機能評価2018

    • Author(s)
      近藤剛弘
    • Organizer
      量子物理学・ナノサイエンス第57回特別セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Boride Sheets Showing Catalytic Activity As Solid Acid Catalyst2018

    • Author(s)
      A. Fujino, H. Nisino, R. Ishibiki, S. Ito, T. Fujitani J. Nakamura, H. Hosono, T. Kondo
    • Organizer
      31st International Microprocesses and Nanotechnology Conference (MNC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Thermal Stability and Chemical Stability of Hydrogen Boride Sheets2018

    • Author(s)
      R. Ishibiki, A. Fujino, T. Goto, H. Nishino, S. Ito, N.T. Cuong, M. Miyauchi, J. Nakamura, H. Hosono, and T. Kondo
    • Organizer
      31st International Microprocesses and Nanotechnology Conference (MNC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ホウ化水素シート上に担持した銅ナノ粒子触媒の調製2018

    • Author(s)
      石引涼太, 藤田武志, 藤野朝日, 伊藤伸一, 宮内雅浩, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      表面界面スペクトロスコピー2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ホウ化水素シートの触媒特性解明2018

    • Author(s)
      藤野朝日, 伊藤伸一, 西野弘晃, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      表面界面スペクトロスコピー2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] ボロファンシートの生成と機能2018

    • Author(s)
      近藤剛弘
    • Organizer
      第16回 Pring-8ユーザー協同体 顕微ナノ材料科学研究会,第13回 日本表面科学会 放射光表面科学研究部会,第2回 日本表面科学会 プローブ顕微鏡研究部会,合同シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ホウ化水素シートの生成と機能2018

    • Author(s)
      西野弘晃, 藤田武志, Nguyen Thanh Cuong, 冨中悟史, 宮内雅浩, 飯村壮史, 平田秋彦, 梅澤直人, 岡田晋, 西堀英治, 藤野朝日, 藤森智博, 伊藤伸一, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      第12回 日本ホウ素・ホウ化物研究会(JSBB2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] ホウ化水素(ボロファン)シートの生成と機能2018

    • Author(s)
      近藤剛弘
    • Organizer
      第63回 GREENオープンセミナー, 物質・材料研究機構
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Hydrogen boride sheets derived from MgB2 by cation exchange2018

    • Author(s)
      Takahiro Kondo
    • Organizer
      2018 Joint Symposium on Energy Materials Science and Technology (Workshop of Pre-Strategic Initiatives)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 白金代替窒素ドープ炭素触媒と新規ホウ素触媒2017

    • Author(s)
      近藤剛弘
    • Organizer
      2017年度触媒学会北海道支部札幌講演会「~固体表面反応場の新しい描像~」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Hydrogen Boride Sheets Derived from MgB2 by Cation Exchange2017

    • Author(s)
      Hiroaki Nishino, Takeshi Fujita, Nguyen Thanh Cuong, Satoshi Tominaka, Masahiro Miyauchi, Soshi Iimura, Akihiko Hirata, Naoto Umezawa, Susumu Okada, Eiji Nishibori, Asahi Fujino, Tomohiro Fujimori, Shin-ichi Ito, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Organizer
      2017 Materials Research Society (MRS) Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen Boride Sheets Derived from MgB2 by Cation Exchange2017

    • Author(s)
      Hiroaki Nishino, Takeshi Fujita, Nguyen Thanh Cuong, Satoshi Tominaka, Masahiro Miyauchi, Soshi Iimura, Akihiko Hirata, Naoto Umezawa, Susumu Okada, Eiji Nishibori, Asahi Fujino, Tomohiro Fujimori, Shin-ichi Ito, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Organizer
      5th Ito International Research Center Conference "Forefront of Molecular Dynamics at Surfaces and Interfaces: from a single molecule to catalytic reaction"
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Catalytic property of boron hydride sheets2017

    • Author(s)
      Asahi Fujino, Hiroaki Nishino, Shin-ichi Ito, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Boron-Based Sheets Derived From MgB22017

    • Author(s)
      Hiroaki Nishino, Takeshi Fujita, Nguyen Thanh Cuong, Satoshi Tominaka, Masahiro Miyauchi, Akiyasu Yamamoto, Soshi Iimura, Akihiko Hirata, Naoto Umezawa, Susumu Okada, Eiji Nishibori, Asahi Fujino, Tomohiro Fujimori, Shin-ichi Ito, Junji Nakamura, Hideo Hosono, Takahiro Kondo
    • Organizer
      The Tenth International Conference on the Science and Technology for Advanced Ceramics (STAC-10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イオン交換法による水素化ホウ素シートの大量生成2017

    • Author(s)
      西野弘晃, 藤田武志, Nguyen Thanh Cuong, 宮内雅浩, 飯村壮史, 梅澤直人, 岡田晋, 西堀英治, 藤森智博, 藤野朝日, 伊藤伸一, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      日本化学会 第97春季年会 (2017)
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素化ホウ素シートの触媒特性の解明2017

    • Author(s)
      藤野朝日, 伊藤伸一, 西野弘晃, 藤森智博, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      日本化学会 第97春季年会 (2017)
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 窒素で機能化された新規二次元ホウ素シートの生成2017

    • Author(s)
      藤森智博, 藤田武志, 西野弘晃, 藤野朝日, 中村潤児, 細野秀雄, 近藤剛弘
    • Organizer
      日本化学会 第97春季年会 (2017)
    • Place of Presentation
      慶應義塾大学 日吉キャンパス(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fundamental Properties and Applications of Two-Dimensional Materials2016

    • Author(s)
      Takahiro Kondo
    • Organizer
      29th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      ANA Crowne Plaza Kyoto, Kyoto (Japan)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Room Temperature Synthesis of Two-Dimensional Boron Sheets2016

    • Author(s)
      H. Nishino, T. Fujimori, A.Fujino, T. Fujita, N. Umezawa, S. Okada, E. Nishibori, S.Ito, J. Nakamura, H. Hosono and T. Kondo
    • Organizer
      29th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      ANA Crowne Plaza Kyoto, Kyoto (Japan)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] Helium Atom Scattering, Compendium of Surface and Interface Analysis2018

    • Author(s)
      Takahiro Kondo (Editors:The Surface Science Society of Japan)
    • Total Pages
      7
    • Publisher
      Springer
    • ISBN
      9789811061554
    • Related Report
      2018 Annual Research Report
  • [Remarks] プレスリリース(筑波大学 注目の研究)

    • URL

      https://www.tsukuba.ac.jp/attention-research/p201709261400.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] TSUKUBA FUTURE:#085:平面に広がる新しい材料の世界

    • URL

      http://www.tsukuba.ac.jp/notes/085/index.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 還元材料、複合体、還元方法2019

    • Inventor(s)
      近藤剛弘, 藤野朝日, 石引涼太, 後藤大河, 宮内雅浩 他3名
    • Industrial Property Rights Holder
      近藤剛弘, 藤野朝日, 石引涼太, 後藤大河, 宮内雅浩 他3名
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-042011
    • Filing Date
      2019
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素貯蔵ならびに放出材料2018

    • Inventor(s)
      宮内雅浩, 河村玲哉, 近藤剛弘
    • Industrial Property Rights Holder
      宮内雅浩, 河村玲哉, 近藤剛弘
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-118560
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 二酸化炭素貯蔵ならびに放出材料2018

    • Inventor(s)
      近藤剛弘, 藤野朝日, 石引涼太, 後藤大河, 伊藤伸一
    • Industrial Property Rights Holder
      近藤剛弘, 藤野朝日, 石引涼太, 後藤大河, 伊藤伸一
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-204785
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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