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Fabrication of high-quality atomic-layer heterostructures and novel photonic devices

Research Project

Project/Area Number 16H03825
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionNagoya University

Principal Investigator

Kitaura Ryo  名古屋大学, 理学研究科, 准教授 (50394903)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2018: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2016: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Keywords原子層 / バレー自由度 / 光学応答 / ヘテロ構造 / 結晶成長 / 発光分光 / 光電子機能 / 励起子 / 蛍光イメージング / 原子層物質 / 発光デバイス / 遷移金属ダイカルコゲナイド
Outline of Final Research Achievements

In this work, we have focused on development of a crystal growth method for high-quality atomic layers and atomic-layer heterostructures. We have investigated optical responses of atomic layers and heterostructures and found (1) small-fwhm excitonic emissions, (2) formation of biexcitons with small excitation power density, (3) formation of various interlayer excitons composed of electrons and holes locate at different valleys. In addition, we have observed valley-polarized photoluminescence from both atomic layers and heterostructures, which clearly demonstrates that present samples gives versatile playground for investigation of valley-oriented phenomena and valley-photonic devices.

Academic Significance and Societal Importance of the Research Achievements

原子層ではほぼ全てが表面に露出しているため、その物性は週環境に強く影響を受ける。また、バレー自由度をもつ原子層として注目を集めている遷移金属ダイカルコゲナイド(TMD)原子層は、欠陥生成エネルギーが小さく多くの欠陥を含む低品質の試料しか得られなかった。本研究では、独自設計の化学気相成長法装置と六方晶窒化ホウ素基板を用いることで上記二点を解決し、高品質TMD結晶を得ることに成功した。本研究で確立した手法を用いて生み出される試料は、バレー自由度に由来する新奇物性探索やフォトニックデバイス創製へ向けた基盤となる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (12 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 12 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (12 results) (of which Int'l Joint Research: 9 results,  Invited: 12 results) Book (3 results) Remarks (1 results)

  • [Int'l Joint Research] Rice大学(米国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] The Atomic and Electronic Structure of 0° and 60° Grain Boundaries in MoS22019

    • Author(s)
      Nakanishi Terunobu、Yoshida Shoji、Murase Kota、Takeuchi Osamu、Taniguchi Takashi、Watanabe Kenji、Shigekawa Hidemi、Kobayashi Yu、Miyata Yasumitsu、Shinohara Hisanori、Kitaura Ryo
    • Journal Title

      Frontiers in Physics

      Volume: 7 Pages: 1-7

    • DOI

      10.3389/fphy.2019.00059

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Systematic Study of Photoluminescence Enhancement in Monolayer Molybdenum Disulfide by Acid Treatment2018

    • Author(s)
      Kiriya Daisuke、Hijikata Yuh、Pirillo Jenny、Kitaura Ryo、Murai Akihiko、Ashida Atsushi、Yoshimura Takeshi、Fujimura Norifumi
    • Journal Title

      Langmuir

      Volume: 34 Issue: 35 Pages: 10243-10249

    • DOI

      10.1021/acs.langmuir.8b01425

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Blister-based-laser-induced-forward-transfer: a non-contact, dry laser-based transfer method for nanomaterials2018

    • Author(s)
      Goodfriend N T、Heng S Y、Nerushev O A、Gromov A V、Bulgakov A V、Okada M、Xu W、Kitaura R、Warner J、Shinohara H、Campbell E E B
    • Journal Title

      Nanotechnology

      Volume: 29 Issue: 38 Pages: 385301-385301

    • DOI

      10.1088/1361-6528/aaceda

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of a pick-and-drop process on optical properties of a CVD-grown monolayer tungsten disulfide2018

    • Author(s)
      Hoshi Yusuke、Okada Mitsuhiro、Moriya Rai、Masubuchi Satoru、Watanabe Kenji、Taniguchi Takashi、Kitaura Ryo、Machida Tomoki
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 6 Pages: 064003-064003

    • DOI

      10.1103/physrevmaterials.2.064003

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct and Indirect Interlayer Excitons in a van der Waals Heterostructure of hBN/WS2/MoS2/hBN2018

    • Author(s)
      Okada M, Kutana A, Kureishi Y, Kobayashi Y, Saito Y, Saito T, Watanabe K, Taniguchi T, Gupta S, Miyata Y, Yakobson BI, Shinohara H, Kitaura R
    • Journal Title

      ACS Nano

      Volume: 12 Issue: 3 Pages: 2498-2505

    • DOI

      10.1021/acsnano.7b08253

    • NAID

      120006496402

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Femtosecond Laser Filamentation in Gaseous Ethylene: Formation of Hydrogenated Amorphous Carbon2017

    • Author(s)
      Matsuda Akitaka、Hayashi Takahiro、Kitaura Ryo、Hishikawa Akiyoshi
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 9 Pages: 1426-1429

    • DOI

      10.1246/cl.170613

    • NAID

      130006067882

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of the Local Density of States of Carbon Nanotubes by Encapsulation of Europium Nanowires As Observed by Scanning Tunneling Microscopy and Spectroscopy2017

    • Author(s)
      Nakanishi Terunobu、Kitaura Ryo、Kawai Takazumi、Okada Susumu、Yoshida Shoji、Takeuchi Osamu、Shigekawa Hidemi、Shinohara Hisanori
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 33 Pages: 18195-18201

    • DOI

      10.1021/acs.jpcc.7b04047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppression of exciton-exciton annihilation in tungsten disulfide monolayers encapsulated by hexagonal boron nitrides2017

    • Author(s)
      Yusuke Hoshi, Takashi Kuroda, Mitsuhiro Okada, Rai Moriya, Satoru Masubuchi, Kenji Watanabe, Takashi Taniguchi, Ryo Kitaura, and Tomoki Machida
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 24 Pages: 241403-241403

    • DOI

      10.1103/physrevb.95.241403

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of biexcitonic emission at extremely low power density in tungsten disulfide atomic layers grown on hexagonal boron nitride2017

    • Author(s)
      M. Okada, Y. Miyauchi, K. Matsuda, T. Taniguchi, K. Watanabe, H. Shinohara, and R. Kitaura
    • Journal Title

      Scientific Report

      Volume: 7 Issue: 1 Pages: 322-322

    • DOI

      10.1038/s41598-017-00068-0

    • NAID

      120006305891

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Molecular beam epitaxy growth of monolayer niobium diselenide flakes2016

    • Author(s)
      T. Hotta, T. Tokuda, S. Zhao, K. Watanabe, T. Taniguchi, H. Shinohara, R. Kitaura
    • Journal Title

      Applied Physics Letters

      Volume: 109 Issue: 13 Pages: 133101-133101

    • DOI

      10.1063/1.4963178

    • NAID

      120005895205

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Simple fabrication of air-stable black phosphorus heterostructures with large-area hBN sheets grown by chemical vapor deposition method2016

    • Author(s)
      S. Sinha, Y. Takabayashi, H. Shinohara, R. Kitaura
    • Journal Title

      2D Materials

      Volume: 3 Issue: 3 Pages: 035010-035010

    • DOI

      10.1088/2053-1583/3/3/035010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Two-dimensional metallic NbS2: growth, optical identification and transport properties2016

    • Author(s)
      Sihan Zhao, Takato Hotta, Takashi Koretsune, Kenji Watanabe, Takashi Taniguchi, Katsuaki Sugawara, Takashi Takahashi, Hisanori Shinohara & Ryo Kitaura
    • Journal Title

      2D Materials

      Volume: 3 Issue: 2 Pages: 025027-025027

    • DOI

      10.1088/2053-1583/3/2/025027

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Properties of van der Waals heterostructures of Transition metal dichalcogenide and hexagonal boron nitrides2018

    • Author(s)
      Ryo Kitaura
    • Organizer
      The 9th A3 Symposium on Emerging Materiaks
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transition metal dichalcogenide based van der Waals heterostructures: fabrication and properties2018

    • Author(s)
      Ryo Kitaura
    • Organizer
      The 9th Graphene and 2D Materials Symposium of NT18 conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MBE法による2次元層状物質の結晶成長2018

    • Author(s)
      北浦良
    • Organizer
      日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 遷移金属ダイカルコゲナイド原子層をベースとしたファンデルワールス積層構造の作製と光学応答2018

    • Author(s)
      北浦良
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 原子層の結晶成長と液体セルへの応用2018

    • Author(s)
      北浦良
    • Organizer
      日本セラミックス協会第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Transition metal dichalcogenides based van der Waals heterostacks: fabrication and properties2017

    • Author(s)
      Kitaura, R.
    • Organizer
      Japan-India Meeting on Applications of Layered Materials: Advances and Perspectives
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transition metal dichalcogenides based van der Waals heterostacks: fabrication and properties2017

    • Author(s)
      Kitaura, R.
    • Organizer
      The 8th A3 Symposium on Emerging Materials
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transition metal dichalcogenides based van der Waals heterostacks: fabrication and properties2017

    • Author(s)
      Kitaura, R.
    • Organizer
      ICMass 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transition metal dichalcogenides based van der Waals heterostacks: fabrication and properties2017

    • Author(s)
      Kitaura, R.
    • Organizer
      18th International Conference on the Science and Application of Nanotubes and Low-dimensional Materials (NT17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bottom-up fabrication and optical properties of high-quality two-dimensional atomic layers2016

    • Author(s)
      Ryo Kitaura
    • Organizer
      A3 conference on emerging materials
    • Place of Presentation
      Korea, Buyeo
    • Year and Date
      2016-10-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bottom-up fabrication and optical properties of high-quality two-dimensional atomic layers2016

    • Author(s)
      Ryo Kitaura
    • Organizer
      ナノカーボン研究会 ZAO16
    • Place of Presentation
      たかみや瑠璃クラリゾート
    • Year and Date
      2016-08-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bottom-up fabrication and optical properties of high-quality two-dimensional atomic layers2016

    • Author(s)
      Ryo Kitaura
    • Organizer
      7th UK-Japan Symposium on Fundamental Research Advances in carbon nanomaterials
    • Place of Presentation
      London, UK
    • Year and Date
      2016-06-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] CSJカレントレビュー「二次元物質の科学」2017

    • Author(s)
      北浦良
    • Total Pages
      208
    • Publisher
      日本化学会
    • Related Report
      2016 Annual Research Report
  • [Book] 応用物理2017

    • Author(s)
      北浦良
    • Total Pages
      266
    • Publisher
      応用物理学会
    • Related Report
      2016 Annual Research Report
  • [Book] 『カルコゲナイド系層状物質の最新研究』2016

    • Author(s)
      北浦良
    • Total Pages
      286
    • Publisher
      CMC
    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://nano.chem.nagoya-u.ac.jp/japanese/people/kitaura/index.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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