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Synthesis of Novel Metallic Phase Nanoparticles and Development of Their Catalysis

Research Project

Project/Area Number 16H03826
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials chemistry
Research InstitutionKyoto University

Principal Investigator

Teranishi Toshiharu  京都大学, 化学研究所, 教授 (50262598)

Research Collaborator SAKAMOTO masanori  
SATO ryota  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2018: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywordsナノ粒子 / 電子構造 / パラジウム / リン / 合金 / 局在表面プラズモン共鳴 / ナノ材料 / 金属化合物 / 触媒
Outline of Final Research Achievements

This research aims at the synthesis of novel metallic phase nanoparticles with excellent properties, compared with the noble metal nanoparticles, by tuning the electronic structures. The Pd-P metal compound nanoparticles were successfully synthesized by introducing the element P, which has the similar electron negativity with the element Pd, into the Pd nanoparticles. Then, the Pd-base metal alloy nanoparticles was synthesized by the pseudo-galvanic replacement reaction of the Pd-P nanoparticles with various base metal ions. Furthermore, it was demonstrated that the B2-Pd-base metal alloy nanoparticles (e.g., B2-PdIn) possessing the similar band structures with group 11 elements showed the localized surface plasmon resonance in the visible region.

Academic Significance and Societal Importance of the Research Achievements

これまでに得ることができなかった貴金属と卑金属からなる新たな合金ナノ粒子の合成法を開発した。また、これまでに可視領域に局在表面プラズモン共鳴吸収を示す球状無機ナノ粒子として、金・銀・銅ナノ粒子以外の金属ナノ粒子があることを発見し、そのメカニズムを明らかにした。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 9 results,  Invited: 19 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Phase-segregated NiPx@FePyOz core@shell nanoparticles: ready-to-use nanocatalysts for electro- and photo-catalytic water oxidation through in situ activation by structural transformation and spontaneous ligand removal2018

    • Author(s)
      Saruyama Masaki、Kim Sunwon、Nishino Toshio、Sakamoto Masanori、Haruta Mitsutaka、Kurata Hiroki、Akiyama Seiji、Yamada Taro、Domen Kazunari、Teranishi Toshiharu
    • Journal Title

      Chemical Science

      Volume: 印刷中 Issue: 21 Pages: 4830-4836

    • DOI

      10.1039/c8sc00420j

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Plasmonic p-n Junction for Infrared Light to Chemical Energy Conversion2018

    • Author(s)
      Lian Zichao, Sakamoto Masanori, Vequizo Junie J. M., Ranasinghe C. S. Kumara, Yamakata Akira, Nagai Takuro, Kimoto Koji, Kobayashi Yoichi, Tamai Naoto, Teranishi Toshiharu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 141 Issue: 6 Pages: 2446-2450

    • DOI

      10.1021/jacs.8b11544

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ligand Effect on the Catalytic Activity of Gold Clusters in the Electrochemical Hydrogen Evolution Reaction2018

    • Author(s)
      D. Eguchi, M. Sakamoto, and T. Teranishi
    • Journal Title

      Chem. Sci.

      Volume: 9 Pages: 261-265

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Boosting photocatalytic overall water splitting by Co doping into Mn3O4 nanoparticles as oxygen evolution cocatalysts2018

    • Author(s)
      Yoshinaga Taizo、Saruyama Masaki、Xiong Anke、Ham Yeilin、Kuang Yongbo、Niishiro Ryo、Akiyama Seiji、Sakamoto Masanori、Hisatomi Takashi、Domen Kazunari、Teranishi Toshiharu
    • Journal Title

      Nanoscale

      Volume: 印刷中 Issue: 22 Pages: 10420-10427

    • DOI

      10.1039/c8nr00377g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Layer-by-Layer Assembled Cocatalyst Films of S2?-Stabilized Ni3S4 Nanoparticles for Hydrogen Evolution Reaction2017

    • Author(s)
      Kim Sungwon、Nishino Toshio、Saruyama Masaki、Sakamoto Masanori、Kobayashi Hiroyuki、Akiyama Seiji、Yamada Taro、Domen Kazunari、Teranishi Toshiharu
    • Journal Title

      ChemNanoMat

      Volume: 3 Issue: 10 Pages: 764-771

    • DOI

      10.1002/cnma.201700220

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] ヘテロ構造ナノ粒子の近赤外プラズモン励起キャリアダイナミクス計測2019

    • Author(s)
      寺西利治
    • Organizer
      2019 OCUシンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Near Infrared Plasmon-Induced Charge Separation in Heterostructured Nanoparticles2018

    • Author(s)
      T. Teranishi
    • Organizer
      233rd ECS Meeting
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノプラズモニクスの新展開2018

    • Author(s)
      寺西利治
    • Organizer
      第3回固体化学フォーラム研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Pseudomorphic Transformation of Nanocrystals by Element Replacement2018

    • Author(s)
      T. Teranishi
    • Organizer
      ISMANAM2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Plasmonic Chemistry of Nanocrystals toward Photoenergy Conversion2018

    • Author(s)
      T. Teranishi
    • Organizer
      北京大学セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ナノ仮晶化学:元素置換による新しいナノ粒子の創り方 -プラズモニクスにおける錬金術-2018

    • Author(s)
      寺西利治
    • Organizer
      日本セラミックス協会第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Novel Plasmonic Alloy Nanocrystals formed by Pseudomorphic Reaction2018

    • Author(s)
      T. Teranishi
    • Organizer
      KJF International Conference on Organic Materials for Electronics and Photonics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ仮晶化学の開拓と近赤外プラズモニクスへの展開2018

    • Author(s)
      寺西利治
    • Organizer
      錯体化学若手の会夏の学校
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ナノ仮晶化学:元素置換による新しいナノ粒子の創り方 -プラズモニクスにおける錬金術-2018

    • Author(s)
      寺西利治
    • Organizer
      第3回精密無機有機合成化学研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ナノ結晶の特異構造がもたらす高効率光エネルギー変換特性2018

    • Author(s)
      寺西利治
    • Organizer
      第22回名古屋大学VBLシンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ナノ仮晶化学:新しいナノ結晶の作り方2017

    • Author(s)
      寺西利治
    • Organizer
      第3回OCU物質科学フロンティアシンポジウム
    • Place of Presentation
      大阪市立大学(大阪)
    • Year and Date
      2017-01-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Pseudomorphic Transformation of Nanocrystals by Element Replacement2017

    • Author(s)
      T. Teranishi
    • Organizer
      231st ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 原子を集めて入れ替える ~新しいナノ粒子の創り方と使い方~2017

    • Author(s)
      寺西利治
    • Organizer
      第7回CSJフェスタ
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Efficient Charge Separation in Heterostructured Nanoparticles2017

    • Author(s)
      T. Teranishi
    • Organizer
      5th CMS International Symposium on Photofunctional Chemistry and Molecular Systems
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pseudomorphic Transformation of Nanocrystals by Element Replacement2016

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      France-Japan Workshop
    • Place of Presentation
      Strasbourg (France)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nano-pseudomorphic Chemistry: Novel Structural Transformation of Nanocrystals by Element Replacement2016

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      Applied Nanotechnology & Nanomaterials
    • Place of Presentation
      Ho Chi Minh (Vietnam)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 無機ナノ粒子:設計の重要性と偶発の面白さ2016

    • Author(s)
      寺西利治
    • Organizer
      日本セラミックス協会資源・環境関連材料部会講演会
    • Place of Presentation
      東京都立産業技術センター(東京)
    • Year and Date
      2016-10-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Nano-pseudomorphic Chemistry: Epochal Structural Transformation of Nanocrystals by Element Replacement2016

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      ISSPIC-18
    • Place of Presentation
      ユバスキュラ (Finland)
    • Year and Date
      2016-08-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Formation of Novel Nanocrystals by Element Replacement2016

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      ISCA Japan Workshop
    • Place of Presentation
      アイルランド大使館(東京)
    • Year and Date
      2016-06-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Book] CSJ Current Review 32 プラズモンと光圧が導く物質科学2019

    • Author(s)
      寺西利治 他
    • Total Pages
      196
    • Publisher
      化学同人
    • ISBN
      9784759813920
    • Related Report
      2018 Annual Research Report
  • [Remarks] Teranishi Laboratory

    • URL

      https://www.scl.kyoto-u.ac.jp/~teranisi/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 研究室webページ

    • URL

      http://www.scl.kyoto-u.ac.jp/~teranisi/

    • Related Report
      2017 Annual Research Report
  • [Remarks] Teranishi Laboratory

    • URL

      http://www.scl.kyoto-u.ac.jp/~teranisi/

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 可視光プラズモニック合金ナノ粒子、その製造方法、及びその用途2017

    • Inventor(s)
      佐藤良太、寺西利治、川脇徳久、信定克幸、飯田健二
    • Industrial Property Rights Holder
      佐藤良太、寺西利治、川脇徳久、信定克幸、飯田健二
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-159786
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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