Budget Amount *help |
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2018: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2016: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
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Outline of Final Research Achievements |
This research aims at the synthesis of novel metallic phase nanoparticles with excellent properties, compared with the noble metal nanoparticles, by tuning the electronic structures. The Pd-P metal compound nanoparticles were successfully synthesized by introducing the element P, which has the similar electron negativity with the element Pd, into the Pd nanoparticles. Then, the Pd-base metal alloy nanoparticles was synthesized by the pseudo-galvanic replacement reaction of the Pd-P nanoparticles with various base metal ions. Furthermore, it was demonstrated that the B2-Pd-base metal alloy nanoparticles (e.g., B2-PdIn) possessing the similar band structures with group 11 elements showed the localized surface plasmon resonance in the visible region.
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