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Study on true congruent-melting LiNbO3 crystal growing with unity partition coefficients for any constituent species

Research Project

Project/Area Number 16H03855
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Crystal engineering
Research InstitutionTohoku University

Principal Investigator

UDA Satoshi  東北大学, 金属材料研究所, 教授 (90361170)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2018: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2017: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Keywordsニオブ酸リチウム / コングルエント / 化学量論 / 結晶化起電力 / イオン種 / 酸素 / 固液界面 / 熱力学自由度 / 熱力学的自由度 / 擬三元系
Outline of Final Research Achievements

Combining a conventional concept of “congruent” with the essentially new concept of “stoichiometry”; a material whose activities of its constituent elements can be unity is stoichiometric, we have developed cs-MgO:LiNbO3 (Li2O:Nb2O5:MgO = 45.30:50.00:4.70) by introducing Mg and vacancy, both of which are simultaneously congruent and stoichiometric. Activities of all constituent elements can be unity so that the equilibrium partition coefficient, k0 of every chemical species in the melt is unity. Thus, they yield no segregation of ionic species during growth so that there is no compositional change in growing crystals even if they experience the unexpected perturbation, which is not possible in the conventional congruent LiNbO3 (c-LiNbO3). They are easy to growth with extremely homogeneous composition and are effective to achieve excellent nonlinear optical properties.

Academic Significance and Societal Importance of the Research Achievements

酸化物融液からの結晶成長では最善の育成環境を整えても必ず非定常成長が起きる。結晶育成技術の限界である。この時、界面での局所平衡が損なわれイオン種偏析がある従来のコングルエント・ニオブ酸リチウム結晶(c-LN)では組成変動が起きる。しかし、「コングルエント+化学量論」のニオブ酸リチウム結晶が成長する融液(cs-MgO:LN)ではイオン種偏析はないので組成変動はない。真のコングルエント成長である。本研究では成長速度の擾乱が生じても組成が均質で屈折率変動の非常に小さく次世代光学デバイスの作製やOEICの微細加工に十分耐えうる均質結晶を作製する新しいニオブ酸リチウム結晶を開発した。

Report

(4 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (38 results)

All 2020 2019 2018 2017 2016 Other

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (33 results) (of which Int'l Joint Research: 13 results,  Invited: 15 results) Remarks (1 results)

  • [Journal Article] コングルエント組成と化学量論組成が一致するニオブ酸リチウムの開発2019

    • Author(s)
      宇田聡
    • Journal Title

      応用物理

      Volume: 88 Pages: 653-658

    • NAID

      130007725676

    • Related Report
      2018 Annual Research Report
  • [Journal Article] 界面電場制御による単結晶育成2018

    • Author(s)
      宇田聡, 黄新明, 坪田毅
    • Journal Title

      セラミックス

      Volume: 53 Pages: 853-856

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Effect of point defects on Curie temperature of lithium niobate2017

    • Author(s)
      Chihiro Koyama, Jun Nozawa, Kozo Fujiwara, Satoshi Uda
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 100 Issue: 3 Pages: 1118-1124

    • DOI

      10.1111/jace.14701

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 不純物添加したニオブ酸リチウムの点欠陥形態2016

    • Author(s)
      小山千尋、野澤純、藤原航三、宇田聡
    • Journal Title

      日本結晶成長学会誌

      Volume: 43 Pages: 131-138

    • NAID

      130005997179

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] Effect of interface electric field on ionic species segregation during the growth of LiNbO32020

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      東北大学大学院 理学・生命科学2研究科合同シンポジウム 2020
    • Related Report
      2018 Annual Research Report
  • [Presentation] 強い界面電場下において成長するCr:LiNbO3のCrイオンの固液間分配2020

    • Author(s)
      宇田聡, 佐藤慶弥
    • Organizer
      2020年第67回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Unsteady-state crystal growth in the presence of interface electric field2020

    • Author(s)
      Qilin Shi, Jun Nozawa, Satoshi Uda
    • Organizer
      2020年第67回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Study on the electrical relationship at the interface between LN melt and LN crystal2019

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      2019年第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Partitioning of Mg into Li Site and Nb Site in LiNbO3 Crystal during Growth from the Melt2019

    • Author(s)
      Satoshi Uda
    • Organizer
      2019 Collaborative Conference on Materials Research (CCMR)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bulk Growth of Oxide Materials2019

    • Author(s)
      Satoshi Uda
    • Organizer
      17th International Summer School on Crystal Growth (ISSCG-17)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Partitioning of Mg into Li and Nb site in LiNbO3 crystal during growth from the melt2019

    • Author(s)
      Satoshi Uda
    • Organizer
      19th International Conference on Crystal Growth and Epitaxy (ICCGE-19)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A New Growth Technology by Applying External Electric Fields2019

    • Author(s)
      Satoshi Uda
    • Organizer
      International Conference on Advanced Materials for Sustainable Energy and Sensors (INCAMSES-2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Extended concept of stoichiometry for new LiNbO3 and LiTaO3 crystals2019

    • Author(s)
      Satoshi Uda
    • Organizer
      Lecture: Anna University
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Extended concept of stoichiometry for new LiNbO3 and LiTaO3 crystals2019

    • Author(s)
      Satoshi Uda
    • Organizer
      3rd International Conference on Recent Trends in Applied Science and Technology (ICRTAST-2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マイクロPD法による単結晶育成の基礎2019

    • Author(s)
      宇田聡
    • Organizer
      講演: 東京工業大学物質理工学院
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Effect of interface electric field on ionic species segregation during the growth of LiNbO32019

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      第48回結晶成長国内会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] バルク結晶成長から見た固液界面の存在とは?2019

    • Author(s)
      宇田聡
    • Organizer
      大阪電気通信大学エレクトロニクス基礎研究所ワークショップ「固液を区別するパラメタ-長距離秩序か配向秩序か-」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] А New Growth Method by Applying External Electric Fields2019

    • Author(s)
      Satoshi Uda
    • Organizer
      26th CIRFE Seminar
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Growth of Mg-Doped Lithium Niobate Crystal with Stoichiometric Composition Coincident with Congruent Point2018

    • Author(s)
      Satoshi Uda, Hiromitsu Kimura
    • Organizer
      2018 ISAF-FMA-AMF-AMEC-PFM Joint Conference (IFAAP2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 固液成長界面における酸化物融液の構造2018

    • Author(s)
      宇田聡
    • Organizer
      第35回無機・分析化学コロキウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 無機機能材料の結晶成長2018

    • Author(s)
      宇田聡
    • Organizer
      第2回結晶成長基礎セミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 融液成長における結晶への不純物分配2018

    • Author(s)
      宇田聡
    • Organizer
      第41回結晶成長討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Oxygen-metal non-stoichiometry in the diffusion boundary layer during growth of congruent-melting LiNbO32018

    • Author(s)
      Satoshi Uda, Chihiro Koyama, Jun Nozawa, Hiromasa Niinomi, Junpei Okada
    • Organizer
      6th European Conference on Crystal Growth (ECCG-6)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the interface potential distribution during growth of MgO-doped lithium niobate under an external electric field2018

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      Summit of Materials Science 2018: SMS2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the interface potential distribution during growth of MgO-doped lithium niobate under an external electric field2018

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      第47回結晶成長国内会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] Growth of new congruent oxide crystals with extended stoichiometric compositions2018

    • Author(s)
      Satoshi Uda
    • Organizer
      International Symposium & School on Crystal Growth Fundamentals (ISSCGF2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ニオブ酸リチウム結晶成長におけるLiサイトおよびNbサイトへのMgの分配2018

    • Author(s)
      宇田聡、堀江勇介
    • Organizer
      2018年第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Compositional uniformity in the MgO-doped LiNbO3 crystal that is concurrently congruent and stoichiometric2018

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      2018年第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 不純物添加したニオブ酸リチウムの融点およびキュリー温度に与える酸素欠陥の影響2017

    • Author(s)
      小山千尋、野澤純、岡田純平、宇田聡
    • Organizer
      2017年第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県・横浜市)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 固液近傍の酸化物融液の構造についての一考察2017

    • Author(s)
      宇田聡、岡田純平
    • Organizer
      日本学術振興会第161委員会第99回研究会
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2017-03-10
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Thermodynamic view on the oxide melt structure near the growth interface2017

    • Author(s)
      Satoshi Uda, Y. Tsuboi, S. Sakano, C. Koyama, J. Okada
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Possible presence of Al-Ga complex in the Ca3Ta(Ga,Al)3Si2O14 melt and its partitioning during growth from the melt2017

    • Author(s)
      Satoshi Uda, Shuhei Sakano, Chihiro Koyama, Junpei Okada
    • Organizer
      21st American Conference on Crystal Growth and Epitaxy (ACCGE-21)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 熱力学的自由度を増やして拡がる結晶づくりの新世界2017

    • Author(s)
      宇田聡
    • Organizer
      2017年第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Al-Gaの固液分配現象から見るCa3Ta(Ga,Al)3Si2O14単結晶の成長界面融液構造2017

    • Author(s)
      宇田聡、坂野修平、小山千尋、野澤純
    • Organizer
      第46回結晶成長国内会議(JCCG-46)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Compositional uniformity in the MgO-doped LiNbO3 crystal that is concurrently congruent and stoichiometric2017

    • Author(s)
      Qilin Shi, Chihiro Koyama, Jun Nozawa, Satoshi Uda
    • Organizer
      第46回結晶成長国内会議(JCCG-46)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸化物結晶成長において界面融液で起きていること -界面融液構造の熱力学的解析-2017

    • Author(s)
      宇田聡
    • Organizer
      第134回東北大学金属材料研究所講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 不純物添加したニオブ酸リチウムの融点およびキュリー温度に与える酸素欠陥の影響2016

    • Author(s)
      小山千尋、野澤純、岡田純平、宇田聡
    • Organizer
      第132回東北大学金属材料研究所講演会
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2016-11-24
    • Related Report
      2016 Annual Research Report
  • [Remarks] 東北大学金属材料研究所結晶材料化学研究部門 宇田研究室ホームページ

    • URL

      http://www.uda-lab.imr.tohoku.ac.jp/

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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