• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Ion Conductivity in All-Solid-State Thin-Film Lithium Batteries

Research Project

Project/Area Number 16H03864
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNippon Institute of Technology (2017-2018)
Tohoku University (2016)

Principal Investigator

Shiraki Susumu  日本工業大学, 基幹工学部, 教授 (80342799)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2018: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2017: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2016: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords界面 / 表面 / 薄膜 / 全固体電池 / リチウム2次電池 / エピタキシャル薄膜 / パルスレーザー堆積法 / 表面界面物性 / リチウム電池 / 表面・界面物性
Outline of Final Research Achievements

All-solid-state Li batteries show great promise as a next-generation energy-storage devices because of their high energy density and good safety. However, practical applications of such batteries are hampered by the high resistance at their solid electrolyte/electrode interfaces. In this study, we fabricatetd all-solid-state thin-film batteries, and achieved an extremely low electrolyte/electrode interface resistance. Using synchrotron surface X-ray diffraction, we found the low-resistance interface exhibited a flat and well-ordered atomic arrangement at the electrode surface, whereas the high resistance interface showed a disordered interface.

Academic Significance and Societal Importance of the Research Achievements

今回の成果により、全固体電池を実用化するための道筋が見えてきました。高出力型全固体電池における界面抵抗の低減や高速充放電の実証は、全固体リチウム電池の実用化の鍵であり、実用化を目指す上で、大きな一歩です。今回の研究で得られた知見が全固体電池の作製プロセスの改良に活用され、高性能全固体電池の開発につながることが期待されます。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (43 results)

All 2018 2017 2016 Other

All Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 17 results,  Open Access: 8 results,  Acknowledgement Compliant: 4 results) Presentation (20 results) (of which Int'l Joint Research: 7 results,  Invited: 5 results) Book (2 results) Remarks (4 results)

  • [Journal Article] Atomically Well-Ordered Structure at Solid Electrolyte and Electrode Interface Reduces the Interfacial Resistance2018

    • Author(s)
      Shiraki Susumu、Shirasawa Tetsuroh、Suzuki Tohru、Kawasoko Hideyuki、Shimizu Ryota、Hitosugi Taro
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 48 Pages: 41732-41737

    • DOI

      10.1021/acsami.8b08926

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Impact of a surface TiO2 atomic sheet on the electronic transport properties of LaAlO3/SrTiO3 heterointerfaces2018

    • Author(s)
      T. Ohsawa, M. Saito, R. Shimizu, K. Iwaya, S. Shiraki, Y. Ikuhara, and T. Hitosugi
    • Journal Title

      Applied Physics Letters

      Volume: 113 Issue: 14 Pages: 141602-141602

    • DOI

      10.1063/1.5046876

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extremely low resistance of Li3PO4 electrolyte/Li(Ni0.5Mn1.5)O4 electrode interfaces2018

    • Author(s)
      Hideyuki Kawasoko, Susumu Shiraki, Toru Suzuki, Ryota Shimizu, and Taro Hitosugi
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 10 (32) Issue: 32 Pages: 27498-27502

    • DOI

      10.1021/acsami.8b08506

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On the Use of 31Mg for b-Detected NMR Studies of Solids2018

    • Author(s)
      R. M. L. McFadden, A. Chatzichristos, M. H. Dehn, D. Fujimoto, H. Funakubo, A. Gottberg, T. Hitosugi, V. L. Karner, R. F. Kiefl, M. Kurokawa, J. Lassen, C. D. Philip Levy, R. Li, G. D. Morris, M. R. Pearson, S. Shiraki, M. Stachura, J. Sugiyama, D. M. Szunyogh, W. A. MacFarlane
    • Journal Title

      JPS Conference Proceedings

      Volume: 21

    • DOI

      10.7566/jpscp.21.011047

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Challenge for Detecting the Interface between Electrode and Electrolyte with β-NMR2018

    • Author(s)
      Sugiyama Jun、Umegaki Izumi、Shiraki Susumu、Hitosugi Taro、McFadden Ryan M. L.、Wang Dongsheng、Karner Victoria、Morris Gerald D.、MacFarlane W. Andrew、Kiefl Robert F.
    • Journal Title

      JPS Conference Proceedings

      Volume: 21 Pages: 011021-011021

    • DOI

      10.7566/jpscp.21.011021

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] LE-μ+SR Study of Superconductivity in the Thin Film Battery Material LiTi2O42018

    • Author(s)
      Mansson M.、Forslund O. K.、Nozaki H.、Umegaki I.、Shiraki S.、Hitosugi T.、Prokscha T.、Salman Z.、Suter A.、Sassa Y.、Sugiyama J.
    • Journal Title

      JPS Conference Proceedings

      Volume: 21 Pages: 011025-011025

    • DOI

      10.7566/jpscp.21.011025

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Li-Diffusion in Spinel Li[Ni1/2Mn3/2]O4 Powder and Film Studied with μ+SR2018

    • Author(s)
      Sugiyama Jun、Nozaki Hiroshi、Umegaki Izumi、Mukai Kazuhiko、Cottrell Stephen P.、Shiraki Susumu、Hitosugi Taro、Sassa Yasmine、Suter Andreas、Salman Zaher、Prokscha Thomas、Mansson Martin
    • Journal Title

      JPS Conference Proceedings

      Volume: 21 Pages: 011015-011015

    • DOI

      10.7566/jpscp.21.011015

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Lithium diffusion in spinel Li4Ti5O12 and LiTi2O4 films detected with Li8β-NMR2017

    • Author(s)
      Sugiyama Jun、Umegaki Izumi、Uyama Takeshi、McFadden Ryan M. L.、Shiraki Susumu、Hitosugi Taro、Salman Zaher、Saadaoui Hassan、Morris Gerald D.、MacFarlane W. Andrew、Kiefl Robert F.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 9 Pages: 094402-094402

    • DOI

      10.1103/physrevb.96.094402

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Fabrication of atomically abrupt interfaces of single-phase TiH2 and Al2O32017

    • Author(s)
      Ryota Shimizu, Yuki Sasahara, Hiroyuki Oguchi, Kuniko Yamamoto, Issei Sugiyama, Susumu Shiraki, Shin-ichi Orimo, and Taro Hitosugi
    • Journal Title

      APL Materials

      Volume: 5 Issue: 8 Pages: 086102-086102

    • DOI

      10.1063/1.4996984

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Scanning tunneling spectroscopy of superconductivity on surfaces of LiTi2O4(111) thin films2017

    • Author(s)
      Yoshinori Okada, Yasunobu Ando, Ryota Shimizu, Emi Minamitani, Susumu Shiraki, Satoshi Watanabe, and Taro Hitosugi
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1 Pages: 15975-15975

    • DOI

      10.1038/ncomms15975

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quasiparticle interference on cubic perovskite oxide surfaces2017

    • Author(s)
      Y. Okada, S.-Y. Shiau, T.-R. Chang, G. Chang, M. Kobayashi, R. Shimizu, H.-T. Jeng, S. Shiraki, H. Kumigashira, A. Bansil, H. Lin, T. Hitosugi
    • Journal Title

      Phys. Rev. Lett.

      Volume: VOL. 119 Issue: 8 Pages: 086801-086801

    • DOI

      10.1103/physrevlett.119.086801

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Nonvolatile Memory Device with Very Low Power Consumption Based on the Switching of a Standard Electrode Potential2017

    • Author(s)
      Issei Sugiyama, Ryota Shimizu, Tohru Suzuki, Kuniko Yamamoto, Hideyuki Kawasoko, Susumu Shiraki, and Taro Hitosugi
    • Journal Title

      APL Materials

      Volume: 5 Issue: 4 Pages: 046105-046105

    • DOI

      10.1063/1.4980031

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Self-assembly of very-low height/width aspect-ratio Li3Ni2NbO6 disks embedded in Li3NbO4 epitaxial films.2017

    • Author(s)
      H. Kawasoko, R. Shimizu, Y. Takagi, K. Yamamoto, I. Sugiyama, S. Shiraki, T. Hitosugi
    • Journal Title

      Thin Solid Films

      Volume: 621 Pages: 202-206

    • DOI

      10.1016/j.tsf.2016.12.006

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transparent conducting properties of Re-doped β-MoO3 films2016

    • Author(s)
      Kuniko Yamamoto, Ryota Shimizu, Susumu Shiraki, and Taro Hitosugi
    • Journal Title

      APL Materials

      Volume: 4 Issue: 9 Pages: 096104-096104

    • DOI

      10.1063/1.4963154

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Li diffusion in (110)-oriented LiCoO2 thin films grown on Au and Pt (110) substrates2016

    • Author(s)
      S. Shiraki, H. Oki, T. Hitosugi
    • Journal Title

      Surface and Interface Analysis

      Volume: 48 Issue: 11 Pages: 1240-1243

    • DOI

      10.1002/sia.6108

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Negligible Sr segregation on SrTiO3 (001) √13 x √13 reconstructed surfaces2016

    • Author(s)
      Takeo Ohsawa, Ryota Shimizu, Katsuya Iwaya, Susumu Shiraki and Taro Hitosugi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 108 Issue: 16 Pages: 161603-161603

    • DOI

      10.1063/1.4947441

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation and in-situ characterization of well-defined solid electrolyte/electrode interfaces in thin-film lithium batteries2016

    • Author(s)
      Masakazu Haruta, Susumu Shiraki, Takeo Ohsawa, Tohru Suzuki, Akichika Kumatani, Yoshitaka Takagi, Ryota Shimizu, and Taro Hitosugi
    • Journal Title

      Solid State Ionics

      Volume: 285 Pages: 118-121

    • DOI

      10.1016/j.ssi.2015.06.007

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 全固体電池実用化に向けた大学での取組み2018

    • Author(s)
      白木将
    • Organizer
      とちぎ環境産業振興協議会・環境負荷低減技術研究部会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 薄膜型全固体電池の作製とそのin-situ電気化学特性評価2018

    • Author(s)
      白木将
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fabrication and In-Situ Characterization of All-Solid-State Thin-Film Batteries2018

    • Author(s)
      S. Shiraki
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全固体薄膜電池作製・in-situ評価装置の構築2018

    • Author(s)
      白木将
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Electrochemical Properties of Li4Ti5O12 and LiTi2O4 Epitaxial Thin Films2018

    • Author(s)
      S. Shiraki, Y. Takagi, R. Shimizu, T. Hitosugi
    • Organizer
      2018 International Conference on Solid State Devices and Materials (SSDM2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 真空・薄膜技術を活用した全固体リチウム電池研究2018

    • Author(s)
      白木将
    • Organizer
      表面技術協会・表面技術とものづくり研究部会例会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Fabrication and in-situ characterization of well-defined solid electrolyte/electrode interfaces in thin-film lithium batteries2018

    • Author(s)
      S. Shiraki
    • Organizer
      The 3rd International Symposium on "Recent Trends in the Elucidation and Function Discovery of Next Generation Functional Materials of Surface / Interface Properties"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 薄膜型全固体電池作製・in-situ評価装置の構築2018

    • Author(s)
      白木将
    • Organizer
      平成30年度日本表面真空学会 九州支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 薄膜型全固体リチウム電池の作製と表面界面研究2017

    • Author(s)
      白木将
    • Organizer
      表面技術協会第135回講演大会
    • Place of Presentation
      東洋大学(埼玉)
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Ion conductivity at solid-electrolyte/electrode interface in all-solid-state Li batteries2017

    • Author(s)
      S. Shiraki
    • Organizer
      The 2nd international symposium on “Recent Trends in Analysis Techniques for Functional Materials and Devices
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2017-01-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 5V級正極LiNi0.5Mn1.5O4を用いた全固体薄膜電池の作製とその高速充放電特性2017

    • Author(s)
      白木将
    • Organizer
      第6回酸化物研究の新機軸に向けた学際討論会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 5V級正極Li(Ni0.5Mn1.5)O4と固体電解質Li3PO4界面におけるイオン伝導特性2017

    • Author(s)
      白木将、河底秀幸、鈴木竜、清水亮太、一杉太郎
    • Organizer
      九州表面・真空研究会2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 5V級正極LiNi0.5Mn1.5O4と固体電解質Li3PO4が形成する超低抵抗界面2017

    • Author(s)
      白木将、河底秀幸、鈴木竜、清水亮太、一杉太郎
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Very-Low Solid-Electrolyte/Electrode Interface Resistance in Li(Ni0.5Mn1.5)O4-Based Thin-Film Battery2017

    • Author(s)
      Susumu Shiraki, Hideyuki Kawasoko, Toru Suzuki, Ryota Shimizu, and Taro Hitosugi
    • Organizer
      The 5th Ito International Research Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Properties of Li4Ti5O12 and LiTi2O4 epitaxial thin films synthesized with pulsed laser deposition2017

    • Author(s)
      Susumu Shiraki, Yoshitaka Takagi, Ryota Shimizu, Taro Hitosugi
    • Organizer
      11th International Symposium on Atomic Level Characterizations for New Materials and Devices ’17 (ALC'17)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体電解質/電極界面の界面抵抗発生起源の解明2016

    • Author(s)
      白木将、白澤徹郎、鈴木竜、河底秀幸、清水亮太、一杉太郎
    • Organizer
      第42回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2016-12-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] Very-low solid-electrolyte/electrode interface resistance in Li(Ni0.5Mn1.5)O4-based thin-film Lithium Battery2016

    • Author(s)
      S. Shiraki, H. Kawasoko, T. Suzuki, R. Shimizu, T. Hitosugi
    • Organizer
      Prime2016
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体電解質/電極界面の界面抵抗発生起源の解明2016

    • Author(s)
      白木将、白澤徹郎、鈴木竜、河底秀幸、清水亮太、一杉太郎
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] PLDで成膜したLi3PO4固体電解質/LiCoO2電極界面のイオン伝導2016

    • Author(s)
      白木将、鈴木竜、河底秀幸,一杉太郎
    • Organizer
      学術振興会マイクロビームアナリシス第141委員会第164回研究会
    • Place of Presentation
      堀場製作所(東京)
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] PLDで成膜したLi3PO4固体電解質/LiCoO2電極界面のイオン伝導2016

    • Author(s)
      (5)白木将、鈴木竜、河底秀幸、清水亮太、白澤徹郎、一杉太郎
    • Organizer
      九州薄膜表面研究会
    • Place of Presentation
      九州大学(福岡)
    • Related Report
      2016 Annual Research Report
  • [Book] 全固体電池の基礎理論と開発最前線2018

    • Author(s)
      白木将、一杉太郎
    • Total Pages
      271
    • Publisher
      シーエムシー・リサーチ
    • ISBN
      9784904482513
    • Related Report
      2018 Annual Research Report
  • [Book] 全固体電池のイオン伝導性向上技術と材料、製造プロセスの開発2017

    • Author(s)
      白木将、白澤徹郎、河底秀幸、一杉太郎
    • Total Pages
      475
    • Publisher
      技術情報協会
    • ISBN
      9784861046476
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 日本工業大学応用化学科固体電気化学研究室

    • URL

      http://enjoy1.bb-east.ne.jp/~shiraki/

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 日本工業大学ブランディング事業「次世代動力源としての全固体電池技術の開発と応用」

    • URL

      https://www.nit.ac.jp/education-research/branding.html

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 東工大、産業技術総合研究所、科学技術振興機構との共同研究により、全固体電池実現のネックを解明

    • URL

      https://www.nit.ac.jp/topics/link/pdf_452.pdf

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東工大、東北大との共同研究により、全固体電池で超高速充放電を実現

    • URL

      https://www.nit.ac.jp/topics/link/pdf_407.pdf

    • Related Report
      2018 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2021-12-27  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi