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Development of high energy state-selected O2 beam and the method for a high sensitivity measurement

Research Project

Project/Area Number 16H03874
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

Kurahashi Mitsunori  国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点, 主席研究員 (10354359)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2016: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywords酸素分子 / 配向効果 / 白金 / 分子線 / 表面反応 / 量子状態選別分子ビーム / 配向 / スピン / 分子ビーム / 立体効果
Outline of Final Research Achievements

The single spin-rotational state-selected O2 beam enables us to conduct spin and alignment- controlled surface oxidation experiments. But, because of the limitation of its beam energy range and sensitivity, only reactive surfaces were investigated with this method. In this project, the beam energy range was expanded to 0.1-0.9 eV by increasing the number of movable hexapole elements used and implementing the nozzle temperature control. The apparatus has been used for clarifying (1)the origin of the unusual behavior in O2 chemisorption on Pt(111) surface, and (2)the steric effect in Pt steps by utilizing the Pt(553) and (533) surfaces. Another apparatus combining the aligned O2 beam with laboratory XPS machine that allows us to measure the accumulated oxygen during the prolonged O2 beam irradiation was developed for investigating the alignment effect in O2 adsorption on inert surfaces.

Academic Significance and Societal Importance of the Research Achievements

貴金属表面へのO2吸着は燃料電池や排ガス処理等において応用上重要な過程であり、原子レベルでの反応機構理解に向けた研究が長年行われてきたが、表面に飛来するO2分子の配向の影響は不明であった。本計画で開発した高エネルギー状態選別O2ビームによって初めて示された白金平坦表面、ステップ表面でのO2配向効果観測はこれを示す最初の観測であり、反応機構の理解に大きく貢献するものである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (16 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] Leiden University/DIFER(オランダ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] CAEP(中国)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Alignment-resolved O2 scattering from highly oriented pyrolytic graphite and LiF(001) surfaces2019

    • Author(s)
      Mitsunori Kurahashi and Takahiro Kondo
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 4

    • DOI

      10.1103/physrevb.99.045439

    • NAID

      120007128242

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Steps on Pt stereodynamically filter sticking of O22019

    • Author(s)
      Kun Cao, Richard van Lent, Aart W. Kleyn, Mitsunori Kurahashi, and Ludo B.F. Juurlink
    • Journal Title

      Proceedings of the National Academy of Sciences of the United States of America

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Steric effect in CO oxidation on Pt(111)2017

    • Author(s)
      Hirokazu Ueta and Mitsunori Kurahashi
    • Journal Title

      The Journal of Chemical Physics

      Volume: 147 Issue: 19

    • DOI

      10.1063/1.5001683

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 量子状態を制御した分子による表面反応2017

    • Author(s)
      倉橋光紀
    • Journal Title

      月刊「化学」

      Volume: 72 Pages: 68-71

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Development of a Hyperthermal State-selected Molecular Oxygen Beam and Its Application to the Study of O<sub>2</sub> Adsorption on Pt(111)2017

    • Author(s)
      倉橋光紀,植田寛和
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 60 Issue: 8 Pages: 307-312

    • DOI

      10.3131/jvsj2.60.307

    • NAID

      130005995508

    • ISSN
      1882-2398, 1882-4749
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dynamics of O2 Chemisorption on a Flat Platinum Surface Probed by an Alignment Controlled O2 beam (selected as a Very Important Paper)2017

    • Author(s)
      Hirokazu Ueta and Mitsunori Kurahashi
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 15 Pages: 4174-4177

    • DOI

      10.1002/anie.201612281

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 酸素分子のスピン・回転状態制御と表面反応計測への応用2017

    • Author(s)
      倉橋光紀
    • Journal Title

      固体物理

      Volume: 52 Pages: 57-66

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Oxygen adsorption on surfaces studied by a spin- and alignment-controlled O2 beam2016

    • Author(s)
      Mitsunori Kurahashi
    • Journal Title

      Prog. Surf. Sci.

      Volume: 91 Issue: 1 Pages: 29-55

    • DOI

      10.1016/j.progsurf.2016.03.001

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 六極磁子による核スピン偏極オルトH2分子ビームの生成2019

    • Author(s)
      倉橋光紀
    • Organizer
      日本物理学会2019年年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 配向制御した酸素分子ビームによる吸着・触媒酸化反応計測2018

    • Author(s)
      倉橋光紀
    • Organizer
      第35回 プラズマ・核融合学会 年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Two-faced steps: how molecular alignment impacts O2 sticking dynamics on nanostructured Pt2018

    • Author(s)
      Kun Cao, Richard van Lent, Aart W. Kleyn, Mitsunori Kurahashi, and Ludo B.F. Juurlink
    • Organizer
      THE AVS 65th INTERNATIONAL SYMPOSIUM
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pt(553), Pt(533)ステップ表面へのO2吸着立体効果2018

    • Author(s)
      倉橋光紀, Ludo Juurlink
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 量子状態選別O2分子ビーム-XPS複合装置の開発2018

    • Author(s)
      倉橋光紀
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fully alignment specified O2 scattering and adsorption at corrugated surfaces2018

    • Author(s)
      Mitsunori Kurahashi
    • Organizer
      Stereodynamics2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Pt(111)表面へのO2 吸着: 状態選別O2 ビームによる解析2017

    • Author(s)
      植田寛和, 倉橋光紀
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(横浜市西区)
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Oxygen chemisorption and scattering studied with a single spin-rotational state-selected O2 beam2017

    • Author(s)
      Mitsunori Kurahashi
    • Organizer
      The 22nd International Workshop on Inelastic Ion-surface Collisions.
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ni(111)表面へのO2吸着スピン・立体効果: 量子状態選別酸素分子ビームによる解析2017

    • Author(s)
      倉橋光紀
    • Organizer
      2017年真空・表面科学合同講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] O2 chemisorption and CO oxidation on a Pt model catalyst surface studied by an alignment-controlled O2 beam2017

    • Author(s)
      Mitsunori Kurahashi
    • Organizer
      The 4th NIMS-Taiwan MOST Workshop
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Oxygen adsorption dynamics probed by a spin- and alignment-controlled O2 beam2017

    • Author(s)
      Mitsunori Kurahashi
    • Organizer
      2017 Gordon Research Conference on Dynamics at Surfaces
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Observation of Graphene on Ni(110) with SPLEEM2017

    • Author(s)
      M. Suzuki, M. Kurahashi. Y. Yamauchi, N. Ishida, D. Fujita. T. Yasue, T. Koshikawa
    • Organizer
      The 8th international symposium on surface science (ISSS8)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Spin-dependent O2 chemisorption on Fe/W(110)2017

    • Author(s)
      M. Kurahashi
    • Organizer
      The 8th international symposium on surface science (ISSS8)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高エネルギー状態選別O2 分子線による白金表面上での 酸素分子吸着反応過程の解析2016

    • Author(s)
      植田寛和, 倉橋光紀
    • Organizer
      第36回表面科学学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市熱田区)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Alignment resolved O2 chemisorption and CO oxidation on Pt(111)2016

    • Author(s)
      M. Kurahashi, H. Ueta
    • Organizer
      Stereodynamics2016
    • Place of Presentation
      National Taiwan University(Taipei, Taiwan))
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 量子状態選別O2ビームによる酸素吸着 スピン・立体効果の解析2016

    • Author(s)
      倉橋光紀
    • Organizer
      マイクロビームアナリシス第141委員会第165回研究会
    • Place of Presentation
      名古屋大学(名古屋市千種区)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Book] 最新 実用真空技術総覧2019

    • Author(s)
      倉橋光紀 (分担執筆)
    • Publisher
      エヌ・ティー・エス
    • ISBN
      9784860435592
    • Related Report
      2018 Annual Research Report
  • [Remarks]

    • URL

      https://samurai.nims.go.jp/profiles/kurahashi_mitsunori/publications

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/KURAHASHI_Mitsunori-j.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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