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Magnetic proximity effect and spin-current control in graphene/magnetic oxide junctions

Research Project

Project/Area Number 16H03875
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institutes for Quantum and Radiological Science and Technology

Principal Investigator

Sakai Seiji  国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 上席研究員(定常) (10354929)

Co-Investigator(Kenkyū-buntansha) 圓谷 志郎  国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 主幹研究員(定常) (40549664)
李 松田  国立研究開発法人量子科学技術研究開発機構, 高崎量子応用研究所 先端機能材料研究部, 博士研究員(任常) (90805649)
Research Collaborator Yamauchi Yasushi  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥10,000,000、Indirect Cost: ¥3,000,000)
Fiscal Year 2018: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywordsグラフェン / 二次元物質 / スピントロニクス / 界面 / 電子・スピン物性 / ヘテロ構造 / 量子ビーム / スピンエレクトロニクス / ナノ材料 / マイクロ・ナノデバイス / 原子層物質 / 界面物性 / 酸化物磁性体 / 近接効果 / スピン流 / 磁気物性 / 表面・界面物性
Outline of Final Research Achievements

Graphene is receiving great attention as one of the most promising materials for future spintronics due to their outstanding transport properties of spin-polarized charge carriers and two-dimensionality. The key research issue in developing graphene-based spintronic devices is to realize effective injection and modulation of spin-polarized carriers in graphene. However, the graphene-based devices consisting of ferromagnetic metal electrodes studied so far revealed the low spin injection efficiency and difficulty in effective spin manipulation. We for the first time demonstrated that highly-effective spin injection can be realized by utilizing the heterostructures of graphene and half-metallic magnetic oxide (LSMO) in the study of spin-polarized metastable He atom deexcitation spectroscopy. Furthermore, we also revealed that the carrier spin polarization in graphene can be controlled by the magnetic proximity effect in the graphene/insulating magnetic oxide (YIG) heterostructure.

Academic Significance and Societal Importance of the Research Achievements

本研究で得られたグラフェン/酸化物磁性体の磁気近接効果に関する研究成果は、グラフェンを用いた次世代スピントロニクスデバイスの実現に繋がるものであり、それによる情報デバイスの省エネ化など電子情報技術の発展に貢献することが期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (40 results)

All 2019 2018 2017 2016 Other

All Journal Article (19 results) (of which Int'l Joint Research: 10 results,  Peer Reviewed: 18 results,  Open Access: 6 results,  Acknowledgement Compliant: 6 results) Presentation (15 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results) (of which Overseas: 1 results)

  • [Journal Article] Growth of graphene on SiO2 with hexagonal boron nitride buffer layer2019

    • Author(s)
      Entani Shiro、Takizawa Masaru、Li Songtian、Naramoto Hiroshi、Sakai Seiji
    • Journal Title

      Applied Surface Science

      Volume: 475 Pages: 6-11

    • DOI

      10.1016/j.apsusc.2018.12.186

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-Polarized Positron Annihilation Measurement on Ga Vacancies in p-type GaN2018

    • Author(s)
      Maekawa Masaki、Sakai Seiji、Miyashita Atsumi、Kawasuso Atsuo
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 16 Issue: 0 Pages: 347-350

    • DOI

      10.1380/ejssnt.2018.347

    • NAID

      130007420683

    • ISSN
      1348-0391
    • Year and Date
      2018-07-28
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical and Electronic State Analyses of Oxidizing Graphene2018

    • Author(s)
      Takaoka Kota、Mitsuhara Kei、Takizawa Masaru、Entani Shiro、Sakai Seiji
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 16 Issue: 0 Pages: 320-323

    • DOI

      10.1380/ejssnt.2018.320

    • NAID

      130007402872

    • ISSN
      1348-0391
    • Year and Date
      2018-07-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dirac Cone Spin Polarization of Graphene by Magnetic Insulator Proximity Effect Probed with Outermost Surface Spin Spectroscopy2018

    • Author(s)
      Sakai Seiji、Erohin Sergei V.、Popov Zakhar I.、Haku Satoshi、Watanabe Takahiro、Yamada Yoichi、Entani Shiro、Li Songtian、Avramov Pavel V.、Naramoto Hiroshi、Ando Kazuya、Sorokin Pavel B.、Yamauchi Yasushi
    • Journal Title

      Advanced Functional Materials

      Volume: 28 Issue: 20 Pages: 1800462-1800462

    • DOI

      10.1002/adfm.201800462

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Spin polarization of graphene and h-BN on Co(0001) and Ni(111) observed by spin-polarized surface positronium spectroscopy2018

    • Author(s)
      A. Miyashita, M. Maekawa, K. Wada, A. Kawasuso, S. Entani, T. Watanabe, S. Sakai
    • Journal Title

      Physical Review B

      Volume: 97 Issue: 19 Pages: 195405-195405

    • DOI

      10.1103/physrevb.97.195405

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-polarized positron beams with 22Na and 68Ge and their applications to materials research2018

    • Author(s)
      Wada K.、Miyashita A.、Maekawa M.、Sakai S.、Kawasuso A.
    • Journal Title

      AIP Conference Proceedings

      Volume: 1970 Pages: 040001-040001

    • DOI

      10.1063/1.5040213

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] X-ray magnetic circular dichroism spectroscopy analysis of graphene/YIG heterostrcuture with Dirac cone spin polarization2018

    • Author(s)
      S. Sakai, T. Watanabe, Y. Yamada, S. Li, S. Entani, H. Naramoto, K. Amemiya
    • Journal Title

      Photon Factory Activity Report 2017

      Volume: #35 Pages: 1-2

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Electronic structure of Li + @C 60 : Photoelectron spectroscopy of the Li + @C 60 [PF 6 ? ] salt and STM of the single Li + @C 60 molecules on Cu(111)2018

    • Author(s)
      Yamada Yoichi、Kuklin Artem V.、Sato Sho、Esaka Fumitaka、Sumi Naoto、Zhang Chunyang、Sasaki Masahiro、Kwon Eunsung、Kasama Yukihiko、Avramov Pavel V.、Sakai Seiji
    • Journal Title

      Carbon

      Volume: 133 Pages: 23-30

    • DOI

      10.1016/j.carbon.2018.02.106

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interface-induced perpendicular magnetic anisotropy of Co nanoparticles on single-layer h-BN/Pt(111)2018

    • Author(s)
      Watanabe Takahiro、Yamada Yoichi、Koide Akihiro、Entani Shiro、Li Songtian、Popov Zakhar I.、Sorokin Pavel B.、Naramoto Hiroshi、Sasaki Masahiro、Amemiya Kenta、Sakai Seiji
    • Journal Title

      Applied Physics Letters

      Volume: 112 Issue: 2 Pages: 022407-022407

    • DOI

      10.1063/1.5010836

    • NAID

      120007133813

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effective adsorption and collection of cesium from aqueous solution using graphene oxide grown on porous alumina2018

    • Author(s)
      Shiro Entani, Mitsunori Honda, Iwao Shimoyama, Songtian Li, Hiroshi Naramoto, Tsuyoshi Yaita, and Seiji Sakai
    • Journal Title

      japanese Journal of Applied Physics

      Volume: 57 Issue: 4S Pages: 04FP04-04FP04

    • DOI

      10.7567/jjap.57.04fp04

    • NAID

      210000148997

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Vacancy-induced ferromagnetism in ZnO probed by spin-polarized positron annihilation spectroscopy2017

    • Author(s)
      Maekawa Masaki、Abe Hiroshi、Miyashita Atsumi、Sakai Seiji、Yamamoto Shunya、Kawasuso Atsuo
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 17 Pages: 172402-172402

    • DOI

      10.1063/1.4979696

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The direct exchange mechanism of induced spin polarization of low-dimensional π-conjugated carbon- and h -BN fragments at LSMO(001) MnO-terminated interfaces2017

    • Author(s)
      Kuklin Artem V.、Kuzubov Alexander A.、Kovaleva Evgenia A.、Lee Hyosun、Sorokin Pavel B.、Sakai Seiji、Entani Shiro、Naramoto Hiroshi、Avramov Paul
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 440 Pages: 23-29

    • DOI

      10.1016/j.jmmm.2016.12.096

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Theoretical Investigation of the Interfaces and Mechanisms of Induced Spin Polarization of 1D Narrow Zigzag Graphene- and h-BN Nanoribbons on a SrO-Terminated LSMO(001) Surface2017

    • Author(s)
      P. Avramov, A. A. Kuzubov, A. V. Kuklin, H. Lee, E. A. Kovaleva, S. Sakai, S. Entani, H. Naramoto, P. B. Sorokin
    • Journal Title

      J. Phys. Chem. A

      Volume: 121 Issue: 3 Pages: 680-689

    • DOI

      10.1021/acs.jpca.6b09696

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] One-atom-thick 2D copper oxide clusters on graphene2017

    • Author(s)
      E. Kano, D. G. Kvashnin, S. Sakai, L. A. Chernozatonskii, P. B. Sorokin, A. Hashimoto, M. Takeguchi
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 11 Pages: 3980-3985

    • DOI

      10.1039/c6nr06874j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Direct observation of site-selective hydrogenation and spin-polarization in hydrogenated hexagonal boron nitride on Ni(111)2017

    • Author(s)
      M. Ohtomo, Y. Yamauchi, X. Sun, A. A. Kuzubov, N. S. Mikhaleva, P. V. Avramov, S. Entani, Y. Matsumoto, H. Naramoto, S. Sakai
    • Journal Title

      Nanoscale

      Volume: 9 Issue: 6 Pages: 2369-2375

    • DOI

      10.1039/c6nr06308j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Proximity-Induced Spin Polarization of Graphene in Contact with Half-Metallic Manganite2016

    • Author(s)
      S. Sakai, S. Majumdar, Z. I. Popov, P. V. Avramov, Y. Hasagawa, Y. Yamada, H. Huhtinen, H. Naramoto, P. B. Sorokin, Y. Yamauchi
    • Journal Title

      ACS Nano

      Volume: 10 Issue: 8 Pages: 7532-7541

    • DOI

      10.1021/acsnano.6b02424

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electronic Structure and Spin States of 2D graphene/VX2 (X=S, Se) Heterostructures2016

    • Author(s)
      Z. I. Popov, M. S. Mikhaleva, M. A. Visotin, A. A. Kuzubov, S. Entani, H. Naramoto, S. Sakai, P. B. Sorokin, P. V. Avramov
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 48 Pages: 33047-33052

    • DOI

      10.1039/c6cp06732h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Magnetoresistance effect in Fe20Ni80/graphene/Fe20Ni80 vertical spin valves2016

    • Author(s)
      S. Entani, T. Seki, Y. Sakuraba, T. Yamamoto, S. Takahashi, H. Naramoto, K. Takanashi, and S. Sakai
    • Journal Title

      Applied Physics Letters

      Volume: 116 Issue: 8 Pages: 082406-082406

    • DOI

      10.1063/1.4961669

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pt- and Au-induced monodirectional nanowires on Ge(110)2016

    • Author(s)
      T. Watanabe, Y. Yamada, M. Sasaki, S. Sakai, Y. Yamauchi
    • Journal Title

      Surf. Sci.

      Volume: 653 Pages: 71-75

    • DOI

      10.1016/j.susc.2016.05.009

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 酸化グラフェンに吸着したアルカリ金属のXAFSによる研究2019

    • Author(s)
      圓谷 志郎、本田 充紀、下山 巌、滝沢 優、李 松田、馬場 祐治、楢本 洋、境 誠司
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] スピン偏極陽電子ビームによるグラフェン/強磁性薄膜のスピン偏極の検出2019

    • Author(s)
      河裾 厚男, 宮下 敦巳, 前川 雅樹, 萩原 聡, 和田 健, 李 松田, 境 誠司
    • Organizer
      日本物理学会 第74回年次大会(2019年)
    • Related Report
      2018 Annual Research Report
  • [Presentation] スピン偏極陽電子ビームを用いた金属酸化物・窒化物の空孔誘起磁性検出2019

    • Author(s)
      前川 雅樹, 境 誠司, 萩原 聡, 和田 健, 宮下 敦己, 河裾 厚男
    • Organizer
      日本物理学会 第74回年次大会(2019年)
    • Related Report
      2018 Annual Research Report
  • [Presentation] グラフェン/YIGヘテロ構造のディラックコーンスピン分極2018

    • Author(s)
      境 誠司、Sorokin Pavel、Zakhar Popov、渡邉 貴弘、山田 洋一、李 松田、圓谷 志郎、楢本 洋、白 怜士、安藤 和也、山内 泰
    • Organizer
      2018年 第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] スピン偏極陽電子ビームを用いたガドリニウム添加窒化ガリウム薄膜の空孔誘起磁性検出2018

    • Author(s)
      前川 雅樹, 境 誠司, 萩原 聡, 和田 健, 宮下 敦己, 河裾 厚男, 薮内 敦, 長谷川 繁彦
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高エネルギーイオン照射法によるグラフェン化合物の作製2018

    • Author(s)
      圓谷 志郎, 水口 将輝, 渡邉 英雄, 滝沢 優, 李 松田, 楢本 洋, 境 誠司
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 多孔質アルミナ基板上の酸化グラフェンの化学状態分析2018

    • Author(s)
      高岡 航大, 圓谷 志郎, 境 誠司, 光原 圭, 滝沢優
    • Organizer
      日本物理学会 2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Proximity-induced spin polarization of graphene supported on magnetic insulator2018

    • Author(s)
      Seiji Sakai
    • Organizer
      Advanced Materials World Congres
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] First Direct Synthesis of Graphene/Half-metallic Heusler Alloy Heterostructure for Spintronic (Poster Award)2018

    • Author(s)
      Songtian Li, Takahiro Watanabe, Yoichi Yamada, Shiro Entani, Pavel B. Sorokin, Yuya Sakuraba, Kenta Amemiya
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] EMIM TFSIの電界印加XAFSその場測定2018

    • Author(s)
      圓谷 志郎、本田 充紀、Tomilin Felix、李 松田、楢本 洋、Avramov Pavel、境 誠司
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] X線定在波用によるサファイア上に転写したグラフェンの構造解析2018

    • Author(s)
      圓谷 志郎、本田 充紀、李 松田、楢本 洋、境 誠司
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Graphene/Half-metallic Heusler Alloy: A New Heterostructure Towards High-performance Graphene Spintronic Devices2018

    • Author(s)
      Songtian Li
    • Organizer
      NanoWorld Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単層h-BNを用いた金属ナノ粒子の磁性制御2017

    • Author(s)
      渡邉 貴弘、山田 洋一、佐々木 正洋、小出 明広、圓谷 志郎、雨宮 健太、境 誠司
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Heteroatom-Doping into Two-Dimensional Materials by High-Energy Ion Irradiation2017

    • Author(s)
      Shiro Entani, Masaki Mizuguchu, Hideo Watanabe, Masaru Takizawa, Konstantine Larinov, Liubov Y. Antipina, Pavel B. Sorokin, Pavel V. Avramov, Songtian Li, Hiroshi Naramoto, Seiji Sakai
    • Organizer
      MRS Fall Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] イットリウム鉄ガーネット上のグラフェンのスピン分極と異常ホール効果2016

    • Author(s)
      境 誠司、Sorokin Pavel、白 怜士、山田 洋一、圓谷 志郎、楢本 洋、Avramov Pavel、安藤 和也、山内 泰
    • Organizer
      第77回応用物理学会秋期学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Book] World Scientific Reference on Spin in Organics, Volume 2: Spinterface2018

    • Author(s)
      S Majumdar, P Avramov and S Sakai
    • Total Pages
      244
    • Publisher
      World Scientific
    • ISBN
      9789813228962
    • Related Report
      2017 Annual Research Report
  • [Remarks] プロジェクト「二次元物質スピントロニクス研究」 ホームページ

    • URL

      http://www.taka.qst.go.jp/eimr_div/Molspin/index_j.html

    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] Perpendicular Magnetic Recording Medium and Magnetic Storage Apparatus2017

    • Inventor(s)
      K.Hasegawa, S.Entani, S.Sakai
    • Industrial Property Rights Holder
      昭和電工株式会社, 量子科学技術研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Acquisition Date
      2019
    • Related Report
      2018 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 垂直磁気記録媒体及び磁気記録再生装置2016

    • Inventor(s)
      中島 悟, 長谷川 浩太, 境 誠司, 圓谷 志郎
    • Industrial Property Rights Holder
      昭和電工株式会社, 量子科学技術研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016
    • Acquisition Date
      2019
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 垂直磁気記録媒体の製造方法及び磁気記録再生装置2016

    • Inventor(s)
      中島 悟, 長谷川 浩太, 境 誠司, 圓谷 志郎
    • Industrial Property Rights Holder
      昭和電工株式会社, 量子科学技術研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016
    • Acquisition Date
      2019
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 垂直磁気記録媒体及び磁気記録再生装置2016

    • Inventor(s)
      長谷川浩太, 鵜飼高広, 山川栄進, 圓谷志郎, 境誠司
    • Industrial Property Rights Holder
      昭和電工株式会社, 量子科学技術研究開発機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016
    • Acquisition Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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