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Fabrication of doped ZnO spherical crystals by optical vortex laser processing

Research Project

Project/Area Number 16H03888
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Optical engineering, Photon science
Research InstitutionKyushu University

Principal Investigator

NAKAMURA DAISUKE  九州大学, システム情報科学研究院, 准教授 (40444864)

Research Collaborator OKADA Tatsuo  
IKENOUE Hiroshi  
OMATSU Takashige  
MAMIDANNA SRI RAMACHANDRA Ramachandra Rao  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2018: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2017: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2016: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Keywords微小共振器 / ウィスパリングギャラリーモード / 光渦レーザープロセス / 微小光共振器
Outline of Final Research Achievements

We proposed optical vortex laser processing to fabricate semiconductor microspherical crystals and to control their size and ejection direction. Size- and position-controlled ZnO microspherical crystals were successfully fabricated by optical vortex laser ablation in air, and they showed ultraviolet (UV) whispering gallery mode (WGM) lasing under pulse laser excitation. In order to expand the functionalities of the sphere-based optical micro-cavity, alloy and doped microspherical crystals such as ZnMgO and Ho-doped ZnO were fabricated. The WGM lasing wavelength of ZnMgO microspherical crystal was blue-shifted from 400 nm to 355 nm with increasing concentration of Mg. In addition, we demonstrated that UV and visible WGM from single Ho-doped ZnO microspherical crystal with different laser excitation of 355 nm pulse laser and 488 nm continuous laser.

Academic Significance and Societal Importance of the Research Achievements

近年,光渦レーザーを材料加工に応用する研究が注目されてきている中で,本研究ではマイクロサイズの半導体結晶球を大気中にて合成し,そのサイズおよび飛翔方向を制御可能であることを実験的に明らかにした点において学術的意義がある.合成した不純物ドープZnO結晶球は,紫外から可視領域においてWGMスペクトルが得られるため,微小レーザーや高感度センサ応用が期待できる.また,ZnOは生体適合性の高い材料でもあるため,バイオセンサ等へも応用が期待できる.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (37 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (3 results) Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 6 results,  Open Access: 3 results) Presentation (27 results) (of which Int'l Joint Research: 13 results,  Invited: 8 results)

  • [Int'l Joint Research] Indian Institute of Technology, Madras/Indian Institute of Technology, Indore(インド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Indian Institute of Technology, Madras/Indian Institute of Technology, Indore(India)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Indian Institute of Technology, Madras/Indian Institute of Technology, Indore(India)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] ボトムアップ/トップダウンレーザー加工による半導体ナノ・マイクロ結晶合成2019

    • Author(s)
      中村大輔
    • Journal Title

      光アライアンス

      Volume: 30 Pages: 38-42

    • NAID

      40021765909

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Room temperature WGM resonances in the red spectral range from Ho3+ activated ZnO micro-spherical cavities2018

    • Author(s)
      K. Fabitha, F. Nagasaki, Y. Fujiwara, Y. Wakiyama, D. Nakamura, M. S. Ramachandra Rao
    • Journal Title

      Applied Physics Letters

      Volume: 112 Issue: 26 Pages: 262102-262102

    • DOI

      10.1063/1.5031838

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High-speed observation of semiconductor microsphere generation by laser ablation in the air2018

    • Author(s)
      R. Tasaki, M. Higashihata, A. Suwa, H. Ikenoue, D. Nakamura
    • Journal Title

      Applied Physics A

      Volume: 124 Issue: 2 Pages: 161-161

    • DOI

      10.1007/s00339-018-1596-3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and magnetic characterization of transition metal ion doped ZnO microspheres synthesized via laser ablation in air2017

    • Author(s)
      Parvathy Anitha Sukkurji, Yuki Fujiwara, Nilesh Jayantilal Vasa, M. S. Ramachandra Rao, Mitsuhiro Higashihata, Daisuke Nakamura
    • Journal Title

      Proceeding of SPIE

      Volume: 10090 Pages: 100901X-100901X

    • DOI

      10.1117/12.2253560

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Spherical ZnO Microcrystals by Laser Ablation in Air2016

    • Author(s)
      Daisuke Nakamura, Toshinobu Tanaka, Tatsuya Ikebuchi, Takeshi Ueyama, Mitsuhiro Higashihata, Tatsuo Okada
    • Journal Title

      Electronics and Communications in Japan

      Volume: 99 Issue: 10 Pages: 58-63

    • DOI

      10.1002/ecj.11874

    • NAID

      210000160504

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fabrication of P-, Sb-, and Mg-Doped ZnO Spherical Microcrystals by Laser Ablation in Air2016

    • Author(s)
      Daisuke Nakamura, Toshinobu Tanaka, Takeshi Ueyama, Tatsuya Ikebuchi, Yuki Fujiwara, Fumiaki Nagasaki, Shuhei Takao, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Journal Title

      Journal of Laser Micro / Nanoengineering

      Volume: 11 Issue: 3 Pages: 337-340

    • DOI

      10.2961/jlmn.2016.03.0010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and characterization of Sb-doped ZnO microspheres by pulsed laser ablation2016

    • Author(s)
      Fumiaki Nagasaki, Tetsuya Shimogaki, Toshinobu Tanaka, Tatsuya Ikebuchi, Takeshi Ueyama, Yuki Fujiwara, Mitsuhiro Higashihata, Daisuke Nakamura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 8S3 Pages: 08RE07-08RE07

    • DOI

      10.7567/jjap.55.08re07

    • NAID

      210000147037

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] レーザーを用いたHoドープZnOマイクロ結晶球の合成2019

    • Author(s)
      中村 大輔,脇山 祐一朗,大島 広暉,東畠 三洋,池上 浩,N. J. Vasa,M. S. R. Rao
    • Organizer
      レーザー学会第39回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fabrication of multicomponent semiconductor microspheres by laser ablation in air2019

    • Author(s)
      Daisuke Nakamura, Yuichiro Wakiyama, Hiroki Oshima, Mitsuhiro Higashihata, Hiroshi Ikenoue, Nilesh J. Vasa, M. S. R. Rao
    • Organizer
      Photonics West 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Oxide Semiconductor Nano/Micro Crystals for Optoelectronic Application2019

    • Author(s)
      D. Nakamura, Y. Wakiyama, K. Fabitha, H. Oshima, M. Higashihata, H. Ikenoue, N. J. Vasa, M. S. R. Rao
    • Organizer
      The 30th Annual General Meeting of MRSI and the First Indian Materials Conclave
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光渦パルスによるSiドロップレット飛翔の挙動観察2019

    • Author(s)
      大島 広暉,脇山 祐一朗,川本 実季,東畠 三洋,池上 浩,中村 大輔
    • Organizer
      第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] On-Demand Fabrication of Semiconductor Microspherical Crystal by Laser Ablation2018

    • Author(s)
      D. Nakamura
    • Organizer
      International Workshop on Frontiers in Lasers and Applications
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of ZnO nano/micro crystals by laser ablation-based technique2018

    • Author(s)
      D. Nakamura, Y. Wakiyama, M. Higashihata, H. Ikenoue, I. A. Palani, N. J. Vasa, M. S. R. Rao
    • Organizer
      Indo-Japan Bilateral Symposium in Futuristic Materials and Manufacturing
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] レーザーアブレーション法による不純物ドープZnOマイクロ結晶球の作製2018

    • Author(s)
      脇山 祐一朗,東畠 三洋,諏訪 輝,池上 浩,Nilesh. J Vasa,M. S. Ramachandra Rao,中村 大輔
    • Organizer
      レーザー学会九州支部学生講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Blueshift of whispering-gallery-mode lasing peaks from ZnMgO spheres2018

    • Author(s)
      脇山 祐一朗,東畠 三洋,諏訪 輝,池上 浩,Nilesh J. Vasa,M. S. Ramachandra Rao,中村 大輔
    • Organizer
      第71回電気・情報関係学会九州支部連合大会(国際セッション)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光渦を利用したZnOマイクロドロップレットの飛翔制御2018

    • Author(s)
      大島 広暉,脇山 祐一朗,川本 実季,東畠 三洋,中村 大輔
    • Organizer
      第71回電気・情報関係学会九州支部連合大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Semiconductor Microspherical Crystal Whispering Gallery Mode Lasers2018

    • Author(s)
      Daisuke Nakamura, Ryohei Tasaki, Yuichiro Wakiyama, Sho Kawagoe, Hiroki Oshima, Mitsuhiro Higashihata, Hiroshi Ikenoue, Nilesh J. Vasa, M. S. R. Rao
    • Organizer
      The International Congress on Applications of Lasers & Electro-Optics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 不純物添加によるZnOマイクロ結晶球のレーザー発振波長制御2018

    • Author(s)
      脇山 祐一朗,東畠 三洋,諏訪 輝,池上 浩,Nilesh J. Vasa,M. S. Ramachandra Rao,中村 大輔
    • Organizer
      応用物理学会九州支部学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] レーザーアブレーションによる半導体結晶球の合成と制御2018

    • Author(s)
      中村 大輔,田崎 涼平,脇山 祐一朗,東畠 三洋,池上 浩
    • Organizer
      レーザー学会第38回年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Simple fabrication of semiconductor microspheres by laser ablation in air2018

    • Author(s)
      Daisuke Nakamura, Ryohei Tasaki, Yuichiro Wakiyama, Sho Kawagoe, Hiroki Oshima, Mitsuhiro Higashihata, Nilesh J. Vasa, Hiroshi Ikenoue
    • Organizer
      Photonics West 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 混晶によるZnOマイクロ結晶球WGMレーザーの短波長化2018

    • Author(s)
      脇山祐一郎、田崎涼平、東畠三洋、諏訪輝、池上浩、N. J. Vasa、M. S. R. Rao、中村大輔
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of Semiconductor Microspheres by Laser Ablation2017

    • Author(s)
      D. Nakamura, R. Tasaki, M. Higashihata, A. Suwa, H. Ikenoue
    • Organizer
      18th International Symposium on Laser Precision Microfabrication
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-speed observation of semiconductor microsphere generation by laser ablation in the air2017

    • Author(s)
      R. Tasaki, M. Higashihata, A. Suwa, H. Ikenoue, D. Nakamura
    • Organizer
      International Conference On Laser Ablation 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気中レーザーアブレーションによるHoドープZnOマイクロスフィアの作製2017

    • Author(s)
      脇山祐一郎、田崎涼平、東畠三洋、諏訪輝、池上浩、N. J. Vasa、M. S. R. Rao、中村大輔
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Generation dynamics of semiconductor microsphere by laser ablation in the air2017

    • Author(s)
      R. Tasaki, M. Higashihata, A. Suwa, H. Ikenoue, N. J. Vasa, D. Nakamura
    • Organizer
      第70回電気・情報関係学会九州支部連合大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気中レーザーアブレーションによるZnMgOマイクロスフィアの作製2017

    • Author(s)
      脇山祐一郎、田崎涼平、東畠三洋、諏訪輝、池上浩、N. J. Vasa、M. S. R. Rao、中村大輔
    • Organizer
      第70回電気・情報関係学会九州支部連合大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fabrication of Semiconductor Nano/Micro Crystals by Laser Ablation2017

    • Author(s)
      Daisuke Nakamura, Koji, Oda, Ryohei Tasaki, Yuichiro Wakiyama,Mitsuhiro Higashihata, Hiroshi Ikenoue, N. J. Vasa and M. S. R. Rao
    • Organizer
      International Conference on Laser Deposition 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Semiconductor Nano/Micro Crystals for Optoelectronic and Laser Applications2017

    • Author(s)
      D. Nakamura, K. Oda, R. Tasaki, Y. Wakiyama, M. Higashihata, H. Ikenoue, I. A. Palani, N. J. Vasa, M. S. R. Rao
    • Organizer
      The Conference on Precision Engineering (COPEN 10)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 大気中レーザーアブレーションによる半導体マイクロ結晶球生成の挙動観察2017

    • Author(s)
      田崎 涼平, 藤原 優輝, 永嵜 史明, 諏訪 輝, 池上 浩, 中村 大輔, 岡田 龍雄
    • Organizer
      レーザー学会学術講演会第37回年次大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] High-speed observation of ZnO microspherical crystals produced by laser ablation2017

    • Author(s)
      Daisuke Nakamura, Ryohei Tasaki, Yuki Fujiwara, Fumiaki Nagasaki, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      SPIE Photonics West 2017
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気中レーザーアブレーションによる半導体マイクロ球生成と制御2017

    • Author(s)
      田崎 涼平, 東畠 三洋, 中村 大輔, 諏訪 輝, 池上 浩
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Bandgap engineering of semiconductor droplet for micro-cavity laser2016

    • Author(s)
      Daisuke Nakamura, Yuki Fujiwara, Fumiaki Nagasaki, Ryohei Tasaki, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      EMN droplet 2016
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication and doping of ZnO spherical crystal by laser ablation2016

    • Author(s)
      Daisuke Nakamura, Toshinobu Tanaka, Takeshi Ueyama, Tatsuya Ikebuchi, Yuki Fujiwara, Fumiaki Nagasaki, Shuhei Takao, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      17th International Symposium on Laser Precision Microfabrication
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] レーザアブレーションによる酸化亜鉛マイクロ結晶球生成の挙動観察2016

    • Author(s)
      田崎 涼平, 永嵜 史明, 藤原 優輝, 東畠 三洋, 池上 浩, 中村 大輔
    • Organizer
      電気・情報関係学会九州支部連合大会
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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