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Synchrotron Mossbauer small-angle scattering using a variable bandwidth nuclear spectrometer

Research Project

Project/Area Number 16H03909
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Quantum beam science
Research InstitutionNational Institutes for Quantum and Radiological Science and Technology

Principal Investigator

Mitsui Takaya  国立研究開発法人量子科学技術研究開発機構, 関西光科学研究所 放射光科学研究センター, 上席研究員(定常) (20354988)

Co-Investigator(Kenkyū-buntansha) 増田 亮  京都大学, 複合原子力科学研究所, 研究員 (50455292)
平尾 直久  公益財団法人高輝度光科学研究センター, 利用研究促進部門, 研究員 (70374915)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Keywordsメスバウアー分光 / 超単色X線 / 放射光 / 小角散乱 / 磁性材料 / 核共鳴散乱 / 金属微細組織 / 超高分解能 / 量子ビーム / メスバウアー効果 / 超高圧
Outline of Final Research Achievements

A high performance nuclear spectrometer has been developed to generate bandwidth controlled 57Fe synchrotron radiation Mossbauer gamma rays and it was applied to nuclear resonant small angle scattering spectroscopy. This novel method enables local analysis of the electron magnetic structure related to the micro structure, strain, defects and ordered phase fluctuation of iron-based materials. The developed measurement techniques are impossible with non-directed gamma rays from conventional radioactive isotopes. A variable-bandwidth 57Fe synchrotron Mossbauer source will open up new possibilities of synchrotron studies with an ultra-high resolution of neV to μeV.

Academic Significance and Societal Importance of the Research Achievements

neV~μeV領域でバンド幅可変の放射光メスバウアーγ 線の生成とその応用は、世界的に例がなく、本研究で開発する放射光メスバウアー小角散乱法は、物質内部の微細構造や歪、欠陥や揺らいだ秩序相の電子-磁気構造解析を可能にする新しい量子ビーム利用技術である。開発された計測法は、鋼材、磁性体、超伝導体から地球惑星物質等の広い材料分野での応用が期待できる。neV~μeV領域の放射光メスバウアーγ 線の高出力での生成の成功は、超高分解能放射光X線非弾性散乱を可能にするもので、新しい研究分野の開拓にも繋がる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (48 results)

All 2019 2018 2017 2016 Other

All Journal Article (22 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 22 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (23 results) (of which Int'l Joint Research: 5 results,  Invited: 4 results) Remarks (3 results)

  • [Journal Article] 64- and 128-pixel Si-APD linear array x-ray detectors with 0.5 ns time resolution2019

    • Author(s)
      S. Kishimoto, T. Mitsui, R. Haruki, S. Shimazaki, and M. Tanaka
    • Journal Title

      AIP Conference Proceedings

      Volume: 2054 Pages: 060068-060068

    • DOI

      10.1063/1.5084699

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nuclear Bragg reflection of 57FeBO3 in radio-frequency magnetic field observed with Si-APD linear array detector2019

    • Author(s)
      S. Kishimoto, R. Haruki, M. Tanaka, and T. Mitsui
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: 1 Pages: 016501-016501

    • DOI

      10.7567/1347-4065/aae89c

    • NAID

      210000135188

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Variable-bandwidth 57Fe Synchrotron Mossbauer Source2018

    • Author(s)
      Mitsui Takaya、Masuda Ryo、Seto Makoto、Hirao Naohisa
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 9 Pages: 093001-093001

    • DOI

      10.7566/jpsj.87.093001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic properties and compressional behavior of Fe-Si alloys at high pressure2018

    • Author(s)
      Kamada Seiji、Suzuki Nanami、Maeda Fumiya、Hirao Naohisa、Hamada Maki、Ohtani Eiji、Masuda Ryo、Mitsui Takaya、Ohishi Yasuo、Nakano Satoshi
    • Journal Title

      American Mineralogist

      Volume: 103 Issue: 12 Pages: 1959-1965

    • DOI

      10.2138/am-2018-6425

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Experimental Examination of Thermal Conductivity Anisotropy in hcp Iron2018

    • Author(s)
      Ohta Kenji、Nishihara Yu、Sato Yuki、Hirose Kei、Yagi Takashi、Kawaguchi Saori I.、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      Frontiers in Earth Science

      Volume: 6 Pages: 1-15

    • DOI

      10.3389/feart.2018.00176

    • NAID

      120006889161

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Valence fluctuating compound Valence fluctuating compound α-YbAlB4 studied by 174Yb Mossbauer spectroscopy and X-ray diffraction using synchrotron radiation2018

    • Author(s)
      Momoko Oura, Shugo Ikeda, Ryo Masuda, Yasuhiro Kobayashi, Makoto Seto, Yoshitaka Yoda, Naohisa Hirao, Saori I. Kawaguchi, Yasuo Ohishi, Shintaro Suzuki, Kentaro Kuga, Satoru Nakatsuji, Hisao Kobayashi
    • Journal Title

      Physica B

      Volume: 536 Pages: 162-164

    • DOI

      10.1016/j.physb.2017.09.035

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Melting experiments on Fe?Si?S alloys to core pressures: Silicon in the core?2018

    • Author(s)
      Tateno Shigehiko、Hirose Kei、Sinmyo Ryosuke、Morard Guillaume、Hirao Naohisa、Ohishi Yasuo
    • Journal Title

      American Mineralogist

      Volume: 103 Issue: 5 Pages: 742-748

    • DOI

      10.2138/am-2018-6299

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synchrotron Mossbauer Spectroscopy Measurement2018

    • Author(s)
      T. Mitsui
    • Journal Title

      Magmas Under Pressure, Elsevier

      Volume: chapter7 Pages: 179-210

    • DOI

      10.1016/b978-0-12-811301-1.00007-1

    • ISBN
      9780128113011
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 57Fe Nuclear Resonant Inelastic Scattering of Fe1.1Te2018

    • Author(s)
      M. Kurokuzu S. Kitao, Y. Kobayashi, M. Saito, R. Masuda, T. Mitsui,Y. Yoda, M. Seto
    • Journal Title

      Hyperfine Interact.

      Volume: 239 Issue: 1 Pages: 9-9

    • DOI

      10.1007/s10751-017-1484-9

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 61Ni synchrotron-radiation-based M?ssbauer absorption spectroscopy of Ni nanoparticle composites2018

    • Author(s)
      Masuda Ryo、Kobayashi Hirokazu、Aoyama Yoshimasa、Saito Makina、Kitao Shinji、Ishibashi Hiroki、Hosokawa Shuichi、Mitsui Takaya、Yoda Yoshitaka、Kitagawa Hiroshi、Seto Makoto
    • Journal Title

      Hyperfine Interactions

      Volume: 239 Issue: 1 Pages: 11-11

    • DOI

      10.1007/s10751-018-1488-0

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Emergence of a new valence-ordered structure and collapse of the magnetic order under high pressure in EuPtP2018

    • Author(s)
      Akihiro Mitsuda, Shigeki Manabe, Masafumi Umeda, Hirofumi Wada, Kazuyuki Matsubayashi, Yoshiya Uwatoko, Masaichiro Mizumaki, Naomi Kawamura, Kiyofumi Nitta, Naohisa Hirao, Yasuo Ohishi, Naoki Ishimatsu
    • Journal Title

      J. Phys.: Condens. Matter.

      Volume: 30 Issue: 10 Pages: 105603-105603

    • DOI

      10.1088/1361-648x/aaaca3

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin state and electronic environment of iron in basaltic glass in the lower mantle2017

    • Author(s)
      Fumiya Maeda, Seiji Kamada, Eiji Ohtani, Naohisa Hirao, Takaya Mitusi, Ryo Masuda, Masaaki Miyahara, Catherine McCammon
    • Journal Title

      American Mineralogist

      Volume: 102 Issue: 10 Pages: 2106-2112

    • DOI

      10.2138/am-2017-6035

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Crystal-site-selective spectrum of Fe<sub>3</sub>BO<sub>6</sub> by synchrotron Mössbauer diffraction with pure nuclear Bragg scattering2017

    • Author(s)
      S. Nakamura, T. Mitsui, K. Fujiwara, N. Ikeda, M. Kurokuzu, and S. Shimomura
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 86 Issue: 8 Pages: 084701-084701

    • DOI

      10.7566/jpsj.86.084701

    • NAID

      210000134471

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 放射光メスバウアー回折による結晶サイト選択的スペクトルの測定2017

    • Author(s)
      中村真一,三井隆也
    • Journal Title

      固体物理

      Volume: 52 Pages: 551-558

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of synchrotron-radiation-based Mossbauer absorption spectroscopy for various isotopes2017

    • Author(s)
      Makoto Seto, Ryo Masuda, Yasuhiro Kobayashi, Shinji Kitao, Masayuki Kurokuzu, Makina Saito, Shuuich Hosokawa, Hiroki Ishibashi, Takaya Mitsui, Yoshitaka Yoda, Ko Mibu
    • Journal Title

      Hyperfine Interactions

      Volume: 238 Issue: 1 Pages: 78-78

    • DOI

      10.1007/s10751-017-1446-2

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal-site-selective spectrum of Fe<sub>3</sub>O<sub>4</sub> obtained by Mössbauer diffraction2017

    • Author(s)
      Shin Nakamura, Takaya Mitsui, Kosuke Fujiwara, Naoshi Ikeda, Masayuki Kurokuzu, Susumu Shimomura
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 86 Issue: 2 Pages: 0237061-4

    • DOI

      10.7566/jpsj.86.023706

    • NAID

      210000134244

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-Pressure-Hydrogen-Induced Spin Reconfiguration in GdFe2 Observed by 57Fe-Polarized Synchrotron Radiation M&ouml;ssbauer Spectroscopy with Nuclear Bragg Monochromator2016

    • Author(s)
      Takaya Mitsui, Yasuhiko Imai, Naohisa Hirao, Takahiro Matsuoka, Yumiko Nakamura, Kouji Sakaki, Hirotoshi Enoki, Naoki Ishimatsu, Ryo Masuda, Makoto Seto
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 85 Issue: 12 Pages: 1237071-5

    • DOI

      10.7566/jpsj.85.123707

    • NAID

      210000134177

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Observation of flux-grown α-Fe<sub>2</sub>O<sub>3</sub> single crystal at the morin transition by <sup>57</sup>Fe synchrotron radiation mössbauer diffraction2016

    • Author(s)
      Takaya Mitsui, Shin Nakamura, Naoshi Ikeda, Kohsuke Hujiwara, Ryo Masuda, Yasuhiro Kobayashi, and Makoto Seto
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 85 Issue: 5 Pages: 0547051-5

    • DOI

      10.7566/jpsj.85.054705

    • NAID

      210000133942

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Observation of Enhancement of the Morin Transition Temperature in Iridium-Doped α-Fe2O3 Thin Film by 57Fe-Grazing Incidence Synchrotron Radiation Mossbauer Spectroscopy2016

    • Author(s)
      T. Mitsui, K. Mibu, M. Seto, M. Kurokuzu, S. P. Pati, T. Nozaki and M. Sahashi
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 85 Issue: 6 Pages: 0636011-4

    • DOI

      10.7566/jpsj.85.063601

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Magnetic and spin transitions in w&uuml;stite: A synchrotron M&ouml;ssbauer spectroscopic study2016

    • Author(s)
      M. Hamada, S. Kamada, E. Ohtani, T. Mitsui, R. Masuda, T. Sakamaki, N. Suzuki, F. Maeda and M. Akasaka
    • Journal Title

      Physical Review B

      Volume: 93 Issue: 15 Pages: 155165-155165

    • DOI

      10.1103/physrevb.93.155165

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of Mössbauer diffractometer by using nuclear resonant scattering at SPring-8 BL11XU2016

    • Author(s)
      S. Nakamura, T. Mitsui, K. Fujiwara, N. Ikeda, Y. Kobayashi and S. Shimomura
    • Journal Title

      Hyperfine Interactions

      Volume: 237 Issue: 1 Pages: 1571-9

    • DOI

      10.1007/s10751-016-1370-x

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of cation substitution on bridgmanite elasticity: A key to interpret seismic anomalies in the lower mantle2016

    • Author(s)
      Hiroshi Fukui, Akira Yoneda, Akihiko Nakatsuka, Noriyoshi Tsujino, Seiji Kamada, Eiji Ohtani, Anton Shatskiy, Naohisa Hirao, Satoshi Tsutsui, Hiroshi Uchiyama, Alfred Q. R. Baron
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 33337-33337

    • DOI

      10.1038/srep33337

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] SPring-8 高度化に向けた核共鳴散乱研究計画について2019

    • Author(s)
      三井隆也
    • Organizer
      第 12 回 SPRUC 核共鳴散乱研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 放射光メスバウアー分光による物質の局所構造解析2018

    • Author(s)
      三井隆也
    • Organizer
      放射光設備利用講習会 平成30年度文部科学省ナノテクノロジープラットフォーム事業
    • Related Report
      2018 Annual Research Report
  • [Presentation] 核共鳴散乱を用いた物質研究と将来展望2018

    • Author(s)
      三井隆也
    • Organizer
      SPring-8シンポジウム2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 可搬型核モノクロメーターの開発と応用2018

    • Author(s)
      藤原孝将, 三井隆也, 櫻井吉晴, 池田直
    • Organizer
      日本物理学会 2018 年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] バンド幅と発散角を制御可能な放射光メスバウアー線源で観測した核共鳴小角散乱2018

    • Author(s)
      三井隆也
    • Organizer
      日本物理学会 2018 年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Advanced Mossbauer spectroscopy with nuclear Bragg monochromator in SPring-82018

    • Author(s)
      Takaya Mitsui
    • Organizer
      The 9th TOYOTA RIKEN International Workshop on New Developments and Prospects for Future of Mossbauer Spectroscopy (IWMS2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development and application for mobile type nuclear monochromator of 57Fe2018

    • Author(s)
      K. Fujiwara, T. Mitsui, Y. Sakurai, and N. Ikeda
    • Organizer
      The 9th TOYOTA RIKEN International Workshop on New Developments and Prospects for Future of Mossbauer Spectroscopy (IWMS2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 放射光メスバウアー散乱分光法の現状と課題2018

    • Author(s)
      三井隆也
    • Organizer
      第5回先進的放射光メスバウアー分光研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 低温,高温,真空条件下全反射メスバウアー分光法の開発研究2018

    • Author(s)
      三井隆也
    • Organizer
      第6回先進的放射光メスバウアー分光研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] バンド幅可変核モノクロメーター開発の現状2018

    • Author(s)
      三井隆也
    • Organizer
      第11回SPRUC核共鳴散乱研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 核共鳴散乱研究会 ― 核共鳴散乱を用いた研究成果と今後の展望 ―2017

    • Author(s)
      三井隆也
    • Organizer
      SPring-8シンポジウム2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 鋼材のミクロな欠陥を探査する - 溶接部・腐食部のピンポイント 分析 -2017

    • Author(s)
      三井隆也
    • Organizer
      ナノテクノロジープラットフォーム放射光設備利用講習会
    • Related Report
      2017 Annual Research Report
  • [Presentation] バンド幅可変核モノクロメーターの開発研究2017

    • Author(s)
      三井隆也
    • Organizer
      2017 年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] BL10XUにおけるX線マイクロビームを利用した低温高圧X線回折測定2017

    • Author(s)
      平尾直久,大石泰生,河口沙織,松岡岳洋
    • Organizer
      第58回高圧討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] High pressure and low temperature micro-beam X-ray diffraction system in beamline BL10XU at SPring-82017

    • Author(s)
      N. Hirao, Y. Ohishi, S. kawaguchi
    • Organizer
      The 26th internation conference on high pressure science and technology (AIRAPT 26) joint with the 8th Asian conference on high pressure reseach (ACHPR 8) and the 19th China high pressure conference
    • Related Report
      2017 Annual Research Report
  • [Presentation] 放射光メスバウアー散乱分光法の現状と課題2017

    • Author(s)
      三井隆也
    • Organizer
      第5回先進的放射光メスバウアー分光研究会
    • Place of Presentation
      名古屋工業大学(愛知県名古屋市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 放射光メスバウアー分光による水素関連物質の局所構造解析2017

    • Author(s)
      三井隆也
    • Organizer
      第1回物質材料意見交換会
    • Place of Presentation
      高崎量子応用研究所(群馬県 高崎市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 放射光超単色ビームを用いたメスバウアー分光による局所磁性探査2016

    • Author(s)
      三井隆也
    • Organizer
      量子ビーム科学研究交流会
    • Place of Presentation
      高崎量子応用研究所(群馬県 高崎市)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] SPring-8 の高圧ビームラインの現状と将来展望2016

    • Author(s)
      大石泰生,平尾直久,肥後祐司,丹下慶範,今田沙織
    • Organizer
      第57回高圧討論会
    • Place of Presentation
      筑波大学(茨城県つくば市)
    • Year and Date
      2016-10-26
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Current status of the high pressure research beamline BL10XU at SPring-82016

    • Author(s)
      N. Hirao, Y. Ohishi, S. Kawaguchi
    • Organizer
      2016 International Union of Crystallography High Pressure workshop
    • Place of Presentation
      Pohang, Korean
    • Year and Date
      2016-09-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 核ブラッグモノクロメーターによる高温条件下全反射メスバウアー分光法の開発研究2016

    • Author(s)
      三井隆也, 壬生攻, 瀬戸誠, 黒葛真行, Satya Prakash Pati, 野崎 友大, 佐橋政司
    • Organizer
      日本物理学会 秋季大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Pressure-induced electronic change of iron in complicated silicate glasses2016

    • Author(s)
      F. Maeda, S. Kamada, E. Ohtani, T. Sakamaki, N. Hirao, T. Mitsui, R. Masuda
    • Organizer
      54th EHPRG Meeting
    • Place of Presentation
      Bayreuth, Germany
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical Property and Compressional Behavior of Fe-Si Alloys Under High Pressure2016

    • Author(s)
      N. Suzuki, S. Kamada, F. Maeda, E. Ohtani, N. Hirao, Y. Ohishi, R. Masuda, T. Mitsui, S. Nakano
    • Organizer
      Goldschmidt
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2016-06-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Remarks] エネルギー幅可変核モノクロメーターの開発

    • URL

      https://www.qst.go.jp/uploaded/attachment/3802.pdf

    • Related Report
      2018 Annual Research Report
  • [Remarks] 第9回豊田理研国際ワークショップ(IWMS2018)にてPoster Awardを受賞

    • URL

      https://www.qst.go.jp/uploaded/attachment/10290.pdf

    • Related Report
      2018 Annual Research Report
  • [Remarks] メスバウアー回折で結晶サイト選択的メスバウアースペクトルの測定に成功

    • URL

      http://www.kansai.qst.go.jp/topics-2017001.html

    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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