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Adsorption of prebiotically essential molecules on oxide minerals

Research Project

Project/Area Number 16H04074
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionTokyo Institute of Technology

Principal Investigator

Norio Kitadai  東京工業大学, 地球生命研究所, 研究員 (80625723)

Co-Investigator(Kenkyū-buntansha) 福士 圭介  金沢大学, 環日本海域環境研究センター, 准教授 (90444207)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywords表面錯体モデリング / アストロバイオロジー / 生命の起源 / 化学進化 / 初期地球 / 赤外分光 / その場観測
Outline of Final Research Achievements

Adsorption is among the most fundamental reactions in natural aqueous systems from soils to oceans, controlling a variety of geochemical processes including the migration of ions, metals, and trace or radioactive elements, the formation of low-crystalline oxyhydroxides, ice nucleation on mineral aerosols, and ion uptake by plants. To predict the geochemical impact of adsorption in natural waters, here we evaluated adsorption behaviors of biologically important ions (e.g., sulfate, phosphate, and carbonate) on a wide variety of oxide minerals over a full range of environmental conditions by using the extended triple-layer model (ETLM). The obtained dataset should significantly contribute to a better understanding of the geochemical processes, including the origin of life, occurring at the mineral-water interface.

Academic Significance and Societal Importance of the Research Achievements

本研究で使用した吸着理論であるETLMは,一般に広く利用されている地球化学モデルプログラム(例えばvisual-MINTEQ, PHREEQC, MINTEQL+, GEOSURF)で利用できます.また淡水や海水,採鉱過程で排出された水など,幅広い水質条件に適用可能です.このため,本研究で得られた吸着反応式やパラメータは,天然水を対象とする様々な評価に活かすことができると考えられます.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (30 results)

All 2018 2017 2016

All Journal Article (15 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 15 results,  Open Access: 8 results,  Acknowledgement Compliant: 3 results) Presentation (15 results) (of which Int'l Joint Research: 2 results,  Invited: 8 results)

  • [Journal Article] A comprehensive predictive model for sulfate adsorption on oxide minerals2018

    • Author(s)
      Kitadai N., Nishiuchi K. and Tanaka M.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 238 Pages: 150-168

    • DOI

      10.1016/j.gca.2018.06.032

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 土壌鉱物による微量元素吸着挙動の予測2018

    • Author(s)
      福士圭介
    • Journal Title

      土壌の物理性

      Volume: 138 Pages: 13-20

    • NAID

      130008042796

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Amorphous silica-promoted lysine dimerization: A thermodynamic prediction2018

    • Author(s)
      Kitadai N., Nishiuchi K., Nishii A., Fukushi K.
    • Journal Title

      Origin of Life and Evolution of Biospheres

      Volume: 48 Issue: 1 Pages: 23-34

    • DOI

      10.1007/s11084-017-9548-z

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Geoelectrochemical CO production: Implications for the autotrophic origin of life2018

    • Author(s)
      Kitadai N., Nakamura R., Yamamoto M., Takai K., Li Y., Yamaguchi A., Gilbert A., Ueno Y., Yoshida N., Oono Y.
    • Journal Title

      Science Advances

      Volume: 4 Issue: 4 Pages: 1-7

    • DOI

      10.1126/sciadv.aao7265

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Dissolved divalent metal and pH effects on amino acid polymerization: A thermodynamic evaluation2017

    • Author(s)
      Kitadai, N.
    • Journal Title

      Origins of Life and Evolution of Biospheres

      Volume: 47 Issue: 1 Pages: 13-37

    • DOI

      10.1007/s11084-016-9510-5

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Glycine polymerization on oxide minerals2017

    • Author(s)
      Kitadai, N., Oonishi H., Umemoto K., Usui T., Fukushi K. and Nakashima S.
    • Journal Title

      Origins of Life and Evolution of Biospheres

      Volume: 印刷中 Issue: 2 Pages: 123-143

    • DOI

      10.1007/s11084-016-9516-z

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Origins of building blocks of life: a review2017

    • Author(s)
      Kitadai N., Maruyama S.
    • Journal Title

      Geoscience Frontiers

      Volume: - Issue: 4 Pages: 1117-1153

    • DOI

      10.1016/j.gsf.2017.07.007

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Origin of the reductive tricarboxylic acid (rTCA) cycle-type CO2 fixation: A perspective2017

    • Author(s)
      Kitadai N., Kameya M., Fujishima K.
    • Journal Title

      Life

      Volume: 7 Issue: 4 Pages: 39-39

    • DOI

      10.3390/life7040039

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Modelling Sorption Processes of Trace Elements by Earth Surface Materials2017

    • Author(s)
      福士圭介
    • Journal Title

      Journal of Geography (Chigaku Zasshi)

      Volume: 126 Issue: 3 Pages: 325-341

    • DOI

      10.5026/jgeography.126.325

    • NAID

      130005893333

    • ISSN
      0022-135X, 1884-0884
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Speciation of Magnesium in monohydrocalcite: XANES, ab initio and geochemical modeling.2017

    • Author(s)
      K. Fukushi, Y. Suzuki, J. Kawano, T. Ohno, M. Ogawa, T. Yaji, and Y. Takahashi,
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 213 Pages: 457-474

    • DOI

      10.1016/j.gca.2017.06.040

    • NAID

      130006198607

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Characterization ascertained from d13C and d14C of particulate organic matter in surface water from a shallow and semi-closed lake Kiba2017

    • Author(s)
      Bui H.T., Nagao S., Ochiai S., Fukushi K., Goto A., Hasegawa T.
    • Journal Title

      Journal of Nuclear and Radiochemical Sciences

      Volume: 17 Pages: 17-22

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Predicting thermodynamic behaviors of non-protein amino acids as a function of temperature and pH,2016

    • Author(s)
      Kitadai, N.
    • Journal Title

      Origins of Life and Evolution of Biospheres

      Volume: 46 Issue: 1 Pages: 3-18

    • DOI

      10.1007/s11084-015-9457-y

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of metabolism: A perspective2016

    • Author(s)
      Kitadai, N., Aono, M., Oono, Y.
    • Journal Title

      Chikyukagaku

      Volume: 50 Issue: 3 Pages: 155-176

    • DOI

      10.14934/chikyukagaku.50.155

    • NAID

      130005267120

    • ISSN
      0386-4073, 2188-5923
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Predictive model for Pb(II) adsorption on soil minerals (oxides and low-crystalline aluminum silicate) consistent with spectroscopic evidence2016

    • Author(s)
      Usiyama, T. and Fukushi, K.
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 190 Pages: 134-155

    • DOI

      10.1016/j.gca.2016.06.022

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High-temperature hydrothermal activities around suboceanic Moho: an example from diopsidite and anorthosite in Wadi Fizh, Oman ophiolite2016

    • Author(s)
      Akizawa, N., Tamura, A., Fukushi, K., Yamamoto, J., Mizukami, T., Python, M. and Arai S.
    • Journal Title

      Lithos

      Volume: 263 Pages: 66-87

    • DOI

      10.1016/j.lithos.2016.07.012

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 生命発生,特に代謝の起源に関する実験的・理論的研究2018

    • Author(s)
      北台紀夫
    • Organizer
      日本地球化学会第65回年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] A comprehensive predictive model for sulfate adsorption on oxide minerals2018

    • Author(s)
      北台紀夫
    • Organizer
      日本地球惑星連合2018年大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノ酸の重合挙動から探る生命起源に有利な環境2018

    • Author(s)
      北台紀夫
    • Organizer
      第43回 生命の起源及び進化学会学術講演
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Origin of life-driven by geo-electrochemical energy2017

    • Author(s)
      Kitadai N.
    • Organizer
      Japanese-Canadian Frontiers of Science Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Universality of the origin of life in the Cosmos2017

    • Author(s)
      北台紀夫
    • Organizer
      生命の起源及び進化学会 夏の学校
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] モノハイドロカルサイトと共存するMgの存在状態:XANES,第一原理計算と地球化学モデリング2017

    • Author(s)
      福士圭介,鈴木雄真,松宮春奈,川野潤,大野剛,小川雅裕,家路豊成,高橋嘉男
    • Organizer
      日本地球化学会 第64会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 土壌鉱物による微量元素吸着挙動の予測2017

    • Author(s)
      福士圭介
    • Organizer
      2017年度土壌物理学会大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 電気化学でもたらす生命の起源2016

    • Author(s)
      北台紀夫,山口晃,Yamei Li,山本正浩,中村龍平,高井研
    • Organizer
      日本微生物生態学会 第31回大会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Electrochemical carbon fixation2016

    • Author(s)
      北台紀夫,本郷やよい,Yamei Li,山口晃,中村龍平,山本正浩,高井研
    • Organizer
      日本地球惑星科学連合2016年大会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] CO2 fixation in hydrothermal vent environments2016

    • Author(s)
      Kitadai N., Hongo Y., Li Y., Yamaguchi A., Nakamura R., Yamamoto M., Takai K.
    • Organizer
      Goldschmidt 2016
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 土壌鉱物における鉛の吸着挙動と表面化学種分布の全水質条件に対応した予測モデル2016

    • Author(s)
      福士圭介,牛山智樹
    • Organizer
      日本地球惑星科学連合2016年大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Inhibitive effects of clay particle organization on cesium desorption: prediction of intrinsic cesium desorption from Na-smectite in cation solutions.2016

    • Author(s)
      Fukushi K., Asahi K., Sakai H., Fukiage T.
    • Organizer
      Goldschmidt 2016
    • Related Report
      2016 Annual Research Report
  • [Presentation] 鉱物-水界面の地球化学2016

    • Author(s)
      福士圭介
    • Organizer
      鉱物科学若手の会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] モノハイドロカルサイトと共存するマグネシウムの存在状態2016

    • Author(s)
      福士圭介,鈴木雄真,大野剛,小川雅裕,家路豊成,高橋嘉夫
    • Organizer
      日本鉱物科学会2016年年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Adsorption of trace amount of uranium on iron oxide: toward the quantitative reconstruction of past water qualities of an ancient lakes in the Baikal catchment area2016

    • Author(s)
      Fukushi K., Kobayashi Y., Ushiyama T.
    • Organizer
      Present Earth Surface Processes and Histrical Environmental Changes in East Asia
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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