| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2019: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2018: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2017: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
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| Outline of Final Research Achievements |
The evaluation of COPV derivatives using radical cations and dications showed that the charge delocalization effect of COPV is due to the ideal electron conjugation effect and that COPV is useful as an electronic wire. We also succeeded in synthesizing a double-decker COPV derivative to evaluate the electronic interaction through space. Furthermore, the usefulness of thermodynamically and kinetically stabilized derivatives for improving the stability of open-shell systems and excited states was confirmed from their synthesis and stability evaluation. Based on these basic research results ,the room-temperature resonance tunneling phenomenon was also observed in single molecule device applications.
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