| Budget Amount *help |
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2019: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
|
|---|
| Outline of Final Research Achievements |
Synthesis of coordinatively unsaturated complexes is one of the straightforward way to develop the highly active transition metal catalysts. We have recently described that the introduction of the organosilyl ligands to the metal centers effectively contribute to stabilize the coordinatively unsaturated complexes. In this project, we focused on the synthesis of coordinatively unsaturated first-row transition metal complexes based on the use of organosilyl ligands, and application of the obtained complexes as the catalysts. We found that introduction of chelating organosilyl ligand as well as silyl anion is the efficient synthetic methods to construct the coordinatively unsaturated first-row transition metal complexes such as iron in a simple manner. In addition, high catalytic performance of the obtained complexes was also revealed in some catalytic reactions including hydrosilylation, hydrogenation, and reductive silylation of dinitrogen.
|
