| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2019: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2016: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
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| Outline of Final Research Achievements |
We developed syntheses of various palladium complexes containing a Ru(II), Ir(III), or Cu(I) photosensitizing unit. According to the photosensitizing unit, we developed a suitable synthetic route for the fine synthesis of the palladium catalysts. All the catalysts have been fully characterized by NMR spectrosopy and some of the structures have been determined by single crystal X-ray diffraction studies.
All the catalysts showed highly ligiht-sensitive reactivity toward light irradiation, which led to the control of initiation and stopping of the polymerization by just switching on and off the light source. The results showed that the polymerization can be controlled by the external stimuli. We expanded the reaction to copolymerization.
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