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Construction of innovative expanded pai-conjugation leading to the light-emitting materials by hybridization of metals and heteroatoms

Research Project

Project/Area Number 16H04138
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional solid state chemistry
Research InstitutionOsaka Prefecture University

Principal Investigator

Ogawa Akiya  大阪府立大学, 工学(系)研究科(研究院), 教授 (30183031)

Co-Investigator(Kenkyū-buntansha) 矢野 重信  奈良女子大学, 大和・紀伊半島学研究所, 協力研究員 (60011186)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥11,050,000 (Direct Cost: ¥8,500,000、Indirect Cost: ¥2,550,000)
Fiscal Year 2018: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords機能物性化学 / 分子素子 / 有機典型元素 / 共役系分子 / 発光物質 / パイ共役系 / リン光発光 / ヘテロ元素 / 有機化学 / 複合材料・物性 / 有機工業化学 / ハイブリッド化 / 有機典型元素化学
Outline of Final Research Achievements

Recent progress in nanotechnology for materials science leads to investigate luminescent or conductive molecules based on inorganic-organic hybridization. In this study, the precise synthesis to hybridize pai conjugated molecules with metal atoms and heteroatoms was investigated for generation of innovative inorganic-organic hybridized materials. The results showed that boron, platinum, and phosphine atoms introduced into unsaturated bonds. In addition, fluorous or nitrile groups which have importance in functional materials, were successfully incorporated. Moreover, compounds including platinum atom formed pai conjugation with sulfur or selenium, and remarkable phosphorescence was observed as novel phosphorescent materials.

Academic Significance and Societal Importance of the Research Achievements

現代の化学、機械、電気などの各産業は、一次的に容易に製造される製品では製造技術としては継続困難であり、このため他の追随を許さないような強固な権利体制、またはノウハウを秘めていなければ長期的産業としては成立し得ず、種々の基盤研究も結果的には社会性の無い短期的研究となってしまう。本研究では、高度な精密ものづくりを支える次世代型複合合成法を確立するとともに、新材料の開発に有用な化学反応系のいくつかを開発するに至った。化学産業は資源の乏しい我が国において非常に重要な産業基盤技術の一つであり、本研究では諸外国の激しい技術追随に対しても大きな優位性を持った基盤研究成果を挙げることに成功した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (70 results)

All 2019 2018 2017 2016 Other

All Journal Article (23 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 23 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (45 results) (of which Int'l Joint Research: 12 results) Remarks (2 results)

  • [Journal Article] Synthesis of Bis(phosphanyl)alkane Monosulfides by the Addition of Diphosphane Monosulfides to Alkenes under Light2019

    • Author(s)
      Sato Yuki、Kawaguchi Shin-ichi、Nomoto Akihiro、Ogawa Akiya
    • Journal Title

      Chemistry - A European Journal

      Volume: 25 Issue: 9 Pages: 2295-2302

    • DOI

      10.1002/chem.201805114

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Cyanothiolation of Internal Alkynes Using Organic Disulfides and tert-Butyl Isocyanide2018

    • Author(s)
      Higashimae Shinya、Kurata Daichi、Kawaguchi Shin-ichi、Kodama Shintaro、Sonoda Motohiro、Nomoto Akihiro、Ogawa Akiya
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 83 Issue: 9 Pages: 5267-5273

    • DOI

      10.1021/acs.joc.8b00052

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Furan- and Thiophene-2-Carbonyl Amino Acid Derivatives Activate Hypoxia-Inducible Factor via Inhibition of Factor Inhibiting Hypoxia-Inducible Factor-12018

    • Author(s)
      Kawaguchi Shin-Ichi, Gonda Yuhei, Yamamoto Takuya, Sato Yuki, Shinohara Hiroyuki, Kobiki Yohsuke, Ichimura Atsuhiko, Dan Takashi, Sonoda Motohiro, Miyata Toshio, Ogawa Akiya, Tsujita Tadayuki
    • Journal Title

      Molecules

      Volume: 23 Issue: 4 Pages: 885-885

    • DOI

      10.3390/molecules23040885

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Metal-Free Synthesis of N-Containing Heterocycles from o-Substituted Aniline Derivatives via 2,4,6-Trihydroxybenzoic Acid-Catalyzed Oxidative Dehydrogenation of Benzylamines under Oxygen Atmosphere2018

    • Author(s)
      Ogawa Akiya、Kumazawa Shun、Uematsu Akinori、Dong Chun-ping、Kodama Shintaro、Nomoto Akihiro、Ueshima Michio
    • Journal Title

      HETEROCYCLES

      Volume: 97 Issue: 2 Pages: 842-842

    • DOI

      10.3987/com-18-s(t)60

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Radical Hydrophosphorylation of Alkynes with R2P(O)H Generating Alkenylphosphine Oxides: Scope and Limitations2018

    • Author(s)
      Huang Tianzeng、Saga Yuta、Guo Haiqing、Yoshimura Aya、Ogawa Akiya、Han Li-Biao
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 83 Issue: 15 Pages: 8743-8749

    • DOI

      10.1021/acs.joc.8b01042

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Aryl Iodides from Arylhydrazines and Iodine2018

    • Author(s)
      Dong Chun-ping、Nakamura Kentaro、Taniguchi Toshihide、Mita Soichiro、Kodama Shintaro、Kawaguchi Shin-ichi、Nomoto Akihiro、Ogawa Akiya、Mizuno Takumi
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 8 Pages: 9814-9821

    • DOI

      10.1021/acsomega.8b01559

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis, characterization, thermal and luminescent properties of thiophenol-functionalized platinum(II) bis(acetylide) complexes2018

    • Author(s)
      Rahman Md. Mostafizur、Pramanik Shishir Kanti、Paul Dababrata、Sarkar M. A. A. Shofi Uddin、Ahmed Md. Jalal、Saha Ramkrishna、Ogawa Akiya
    • Journal Title

      Transition Metal Chemistry

      Volume: 44 Issue: 3 Pages: 247-252

    • DOI

      10.1007/s11243-018-0287-4

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Reaction of arylhydrazines with diaryl ditellurides in the air: Insight into bimolecular homolytic substitution on tellurium via Aryl-Te bond cleavage2018

    • Author(s)
      Yamamoto Yuki、Sato Fumiya、Kodama Shintaro、Nomoto Akihiro、Ogawa Akiya
    • Journal Title

      Heteroatom Chemistry

      Volume: 29 Issue: 5-6

    • DOI

      10.1002/hc.21471

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular Cyclization of 3,3-Diarylpropenylamides of Electron-Deficient Alkenes: Stereoselective Synthesis of Functionalized Hexahydrobenzo[f]isoindoles2018

    • Author(s)
      Sugiura Hirotaka、Yamazaki Shoko、Go Kakeru、Ogawa Akiya
    • Journal Title

      European Journal of Organic Chemistry

      Volume: 2019 Issue: 1 Pages: 204-220

    • DOI

      10.1002/ejoc.201801508

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal structures of phenylalanine ester-introduced palladium(II) and platinum(II) complexes and their cytotoxicities2018

    • Author(s)
      Akihiro Nomoto, Nozomi Sakamoto, Yuta Sakai, Keisuke Fukumoto, Shun-ichiro Ogura, Katao Shouhei, Kiyomi Kakiuchi, Jun-ichi Kikuchi, Shigenobu Yano, Akiya Ogawa
    • Journal Title

      Research on Chemical Intermediates

      Volume: 45 Issue: 1 Pages: 3-12

    • DOI

      10.1007/s11164-018-3623-6

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic study of silica-gel or FeCl3-promoted ring-opening aromatization of 7-oxanorborna-2,5-dienes affording 2-bromo-3-hydroxybenzoate derivatives2018

    • Author(s)
      Sonoda Motohiro、Ikeda Ayu、Shinohara Hiroyuki、Hayagane Naoya、Ogawa Akiya、Tanimori Shinji
    • Journal Title

      Research on Chemical Intermediates

      Volume: 45 Issue: 1 Pages: 13-21

    • DOI

      10.1007/s11164-018-3627-2

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-Free Blue Dye Synthesis: Oxidative Coupling of Benzylamines and N,N-Dimethylanilines to Yield 4,4′-Diaminotriarylmethanes in the Presence of Salicylic Acid as a Co-oxidant2017

    • Author(s)
      Dong Chun-ping、Kodama Shintaro、Uematsu Akinori、Nomoto Akihiro、Ueshima Michio、Ogawa Akiya
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 82 Issue: 23 Pages: 12530-12538

    • DOI

      10.1021/acs.joc.7b02296

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Benzoyl Peroxide/Diphenyl Diselenide Binary System for Functionalization of Alkynes Leading to Alkenyl and Alkynyl Selenides2017

    • Author(s)
      Shintaro Kodama, Tomokazu Saeki, Kei Mihara, Shinya Higashimae, Shin-ichi Kawaguchi, Motohiro Sonoda, Akihiro Nomoto, Akiya Ogawa
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 82 Issue: 23 Pages: 12477-12484

    • DOI

      10.1021/acs.joc.7b02276

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper-catalyzed tandem reaction directed toward synthesis of 2,2-disubstituted quinazolinones from vinyl halides and 2-aminobenzamides2017

    • Author(s)
      Yamaguchi Kotaro、Kawaguchi Shin-ichi、Sonoda Motohiro、Tanimori Shinji、Ogawa Akiya
    • Journal Title

      Tetrahedron Letters

      Volume: 58 Issue: 43 Pages: 4043-4047

    • DOI

      10.1016/j.tetlet.2017.09.001

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced Coupling Reaction of Diphenyl(2,4,6-trimethylbenzoyl)phosphine Oxide with Interelement Compounds: Application to the Synthesis of Thio- or Selenophosphinates2017

    • Author(s)
      Kawaguchi Shin-ichi、Ogawa Akiya、Sato Yuki、Nomoto Akihiro
    • Journal Title

      Synthesis

      Volume: 49 Issue: 16 Pages: 3558-3567

    • DOI

      10.1055/s-0036-1588867

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold-Catalyzed Anti-Markovnikov Selective Hydrothiolation of Unactivated Alkenes2017

    • Author(s)
      Tamai, Taichi; Fujiwara, Keiko; Higashimae, Shinya; Nomoto, Akihiro; Ogawa, Akiya
    • Journal Title

      Organic Letters

      Volume: 18(9) Issue: 9 Pages: 2114-2117

    • DOI

      10.1021/acs.orglett.6b00746

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced metal-free diboration of alkynes in the presence of organophosphine catalysts2016

    • Author(s)
      Yoshimura, Aya; Takamachi, Yuki; Mihara, Kei; Saeki, Tomokazu; Kawaguchi, Shin-ichi; Han, Li-Biao; Nomoto, Akihiro; Ogawa, Akiya
    • Journal Title

      Tetrahedron

      Volume: 72(48) Issue: 48 Pages: 7832-7838

    • DOI

      10.1016/j.tet.2016.06.040

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intramolecular [2 + 2] and [4 + 2] Cycloaddition Reactions of Cinnamylamides of Ethenetricarboxylate in Sequential Processes2016

    • Author(s)
      Yamazaki Shoko; Sugiura Hirotaka; Ohashi Shinnosuke; Ishizuka Keisuke; Saimu Rina; Sugiura Hirotaka; Ogawa Akiya; Mikata Yuji
    • Journal Title

      The Journal of organic chemistry

      Volume: 82(22) Issue: 22 Pages: 10863-10886

    • DOI

      10.1021/acs.joc.6b01947

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A tri-aromatic amide hemicryptophane host: synthesis and acetylcholine binding2016

    • Author(s)
      Makita, Yoshimasa; Katayama, Natsuki; Lee, Hsien-Han; Abe, Taro; Sogawa, Kento; Nomoto, Akihiro; Fujiwara, Shin-ichi; Ogawa, Akiya
    • Journal Title

      Tetrahedron Letters

      Volume: 57(46) Issue: 46 Pages: 5112-5115

    • DOI

      10.1016/j.tetlet.2016.10.017

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition2016

    • Author(s)
      Yamazaki, Shoko; Sugiura, Hirotaka; Ohashi, Shinnosuke; Ishizuka, Keisuke; Saimu, Rina; Mikata, Yuji; Ogawa, Akiya
    • Journal Title

      Organic Letters

      Volume: 18(7) Issue: 7 Pages: 1614-1617

    • DOI

      10.1021/acs.orglett.6b00473

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Inter- and Intramolecular Diels-Alder Reaction of Ethenetricarboxylate Derivatives2016

    • Author(s)
      Yamazaki, S.; Sugiura, H.; Niina, M.; Mikata, Y.; Ogawa, A.
    • Journal Title

      Heterocycles

      Volume: 92 Issue: 3 Pages: 485-510

    • DOI

      10.3987/com-15-13394

    • NAID

      40020766398

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] An efficient base-catalyzed double addition of H-phosphine oxides to alkynes2016

    • Author(s)
      Yoshimura, Aya; Saga, Yuta; Sato, Yuki; Ogawa, Akiya, Tieqiao, Chen; Li-Biao, Han
    • Journal Title

      Tetrahedron Letters

      Volume: 57(30) Issue: 30 Pages: 3382-3384

    • DOI

      10.1016/j.tetlet.2016.06.079

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, spectroscopic characterization, thermal and luminescent properties of new organosulfurfunctionalized platinum(II) bis(alkenylarylalkynyl) complexes2016

    • Author(s)
      Md. Mostafizur, Rahman; Muhammad, Younus; Masnun, Naher; Mostafa, Kamal, Masud; Nomoto, Akihiro; Ogawa, Akiya; Alexander, Rudnick; Anna, Kohler
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 818 Pages: 185-194

    • DOI

      10.1016/j.jorganchem.2016.06.006

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 腫瘍選択的光線力学療法のための新規グルコース連結クロリン誘導体の合成2019

    • Author(s)
      山口浩明,野元昭宏,矢野重信,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光線力学療法のためのクロリンe6エステルへの糖鎖導入反応の検討2019

    • Author(s)
      増田理人,野元昭宏,矢野重信,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] トリアリールメタン系色素合成の環境低負荷学酸化プロセスの開発2019

    • Author(s)
      岡田知也,野元昭宏,山本美伽,山本結生,植嶌陸男,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 末端ジインを有する芳香族化合物への位置選択的および立体選択的なカルコゲン原子導入反応の開発2019

    • Author(s)
      酒井辰也,野元昭宏,植嶌陸男,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] テルル上でのラジカル置換反応を利用した非対称ジアリールテルリドの選択的合成2019

    • Author(s)
      佐藤史哉,山本結生,小玉晋太朗,野元昭宏,植嶌陸男,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] サリチル酸誘導体を有機触媒に用いたアミンのイミンへのグリーンオキシデーションとその応用2019

    • Author(s)
      山本結生,董春萍,植松晃基,小玉晋太朗,植嶌陸男,野元昭宏,小川昭弥
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Selective Synthesis of Imines and α-Diimines by Palladium-Catalyzed Diarylation of Isocyanides with Tetraarylleads2019

    • Author(s)
      C. C. TRAN, S.-i. KAWAGUCHI, P. D. TRAN, Y. KOBIKI, S. KODAMA, A. NOMOTO, A. OGAWA
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] A Cyclic Tetranuclear Gold Complex [(PPh3)4Au4(SPh)2](NTf2)2: A Novel Catalyst for Anti-Markovnikov Hydrothiolation of Unactivated Alkenes2018

    • Author(s)
      S. Kodama, T. Tamai, K. Fujiwara, A. Nomoto, M. Ueshima, A. Ogawa
    • Organizer
      The 15th International Symposium on Inorganic Ring Systems
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Quinolinol-based Ligands Bearing Sugar or Amino Acid Moiety and Their Conjugation with Palladium or Platinum for Development of Anticancer Agents2018

    • Author(s)
      A. Nomoto, S. Yano, Y. Komai, N. Sakamoto, Y. Sakai, Y. Kinoshita, R. Sakai, H. Kataoka, A. Ogawa
    • Organizer
      43rd International Conference on Coordination Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Metal-Free Synthesis of Sulfur-Containing N-Heterocycles and Related Compounds from o-Substituted Anilines via Salicylic Acid-Catalyzed Oxidative Dehydrogenation of Benzylamines under an Oxygen Atmosphere2018

    • Author(s)
      A. UEMATSU, C.-p. DONG, S. KODAMA, A. NOMOTO, M. UESHIMA, A. OGAWA
    • Organizer
      28th International Symposium on the Organic Chemistry of Sulfur
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Metal-free Oxidative Coupling of Benzylamines Using Salicylic Acid Derivatives as Organocatalysts and Its Application to Blue Dye Synthesis2018

    • Author(s)
      C.-p. DONG, S. KODAMA, A. NOMOTO, M. UESHIMA, A. OGAWA
    • Organizer
      The 14th International Kyoto Conference on New Aspects of Organic Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] マルトトリオース連結クロリンの抗腫瘍活性評価および重原子導入による発光挙動の変化2018

    • Author(s)
      山本美伽,野元昭宏,片岡洋望,矢野重信,鳴海敦,小川昭弥
    • Organizer
      第28回金属の関与する生体関連反応シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] ポルフィリン骨格へのエチニルベンゼン部位の導入による金属配位構造物の合成2018

    • Author(s)
      張立昊,野元昭宏,牧浦理恵,小川昭弥
    • Organizer
      第28回金属の関与する生体関連反応シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノ酸誘導体の希土類イオンとの錯形成とキレート剤への応用2018

    • Author(s)
      吉田春香,野元昭宏,尾崎紀哉,小川昭弥
    • Organizer
      第28回金属の関与する生体関連反応シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 新規抗がん性糖連結白金およびパラジウム錯体の合成と転移抑制能の評価2018

    • Author(s)
      駒井優貴,坂本望,野元昭宏,堺隆一,矢野重信,小川昭弥
    • Organizer
      第28回金属の関与する生体関連反応シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 糖連結クロリン誘導体の合成と金属導入反応の検討2018

    • Author(s)
      山口浩明,野元昭宏,片岡洋望,矢野重信,小川昭弥
    • Organizer
      第28回金属の関与する生体関連反応シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光がん治療に応用可能な糖鎖部位を有するクロリンe6誘導体の合成2018

    • Author(s)
      増田理人,山口浩明,野元昭宏,植嶌陸男,小川昭弥
    • Organizer
      第38回有機合成若手セミナー
    • Related Report
      2018 Annual Research Report
  • [Presentation] トリフェニルメタン系色素製造における環境低負荷酸化触媒の開発2018

    • Author(s)
      伊藤詣二,西ケ花完,辻元英孝,野元昭宏
    • Organizer
      2018年度色材研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] クリーンなトリフェニルメタン系色素製造の工業化への課題2018

    • Author(s)
      藤詣二,西ケ花完,辻元英孝,野元昭宏
    • Organizer
      2018年度色材研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水中の重金属イオンの固定化が可能なジチオカルボン酸誘導体の合成と除去能評価2018

    • Author(s)
      山口浩明,尾崎紀哉,野元昭宏,小川昭弥
    • Organizer
      2018年度日本農芸化学会関西支部大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アリールヒドラジンとヨウ素を用いたアリールヨージドの合成2018

    • Author(s)
      三田宗一朗,董春萍,中村健太郎,谷口寿英,小玉晋太朗,川口真一,野元昭宏,水野卓巳,小川昭弥
    • Organizer
      第21回 ヨウ素学会シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] パラジウム触媒によるジスルフィドおよびイソシアニドを用いた内部アルキンの高選択的シアノチオ化反応の開発2018

    • Author(s)
      倉田大地,東前信也,川口真一,小玉晋太朗,園田素啓,野元昭宏,小川昭弥
    • Organizer
      第65回 有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 簡便なアリールラジカル発生にともなうヨウ化ベンゼンおよび一置換ベンゼン類の合成2018

    • Author(s)
      野元昭宏,三田宗一朗,董 春萍,谷口寿英,小玉晋太朗,川口真一,植嶌陸男,水野卓巳,小川昭弥
    • Organizer
      2018 ハロゲン利用ミニシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 腫瘍選択的光線力学療法のためのクロリン誘導体の合成および評価2018

    • Author(s)
      山口浩明,野元昭宏,片岡洋望,矢野重信,小川昭弥
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ジホスフィンモノスルフィドを用いたアルケン類に対する効率的な1,2-付加反応の開発2018

    • Author(s)
      佐藤悠樹,川口真一,野元昭宏,小川昭弥
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 金属固定化キレート剤としてのジチオカルボン酸誘導体の合成と除去能評価2018

    • Author(s)
      山口浩明,尾崎紀哉,野元昭宏,小川昭弥
    • Organizer
      第45回有機典型元素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] テルル上でのラジカル置換反応を経由した非対称ジアリールテルリドの選択的one-pot合成法の開発2018

    • Author(s)
      山本結生,佐藤史哉,小玉晋太朗,野元昭宏,小川昭弥
    • Organizer
      公益社団法人石油学会関西支部第27回研究発表会 一般社団法人日本エネルギー学会関西支部第63回研究発表会 合同研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] リン資源のリサイクル利用を目指したフルオラスホスフィンを用いるWittig反応の開発2018

    • Author(s)
      西村美紗希,佐藤悠樹,嶋田祥久,川口真一,小玉晋太朗,野元昭宏,小川昭弥
    • Organizer
      公益社団法人石油学会関西支部第27回研究発表会 一般社団法人日本エネルギー学会関西支部第63回研究発表会 合同研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] DEVELOPMENT OF FUNCTIONAL PHOSPHINES FOR RECYCLING OF PRECIOUS METALS AND GREEN CATALYTIC PROCESSES2017

    • Author(s)
      佐藤 悠樹 小川 昭弥
    • Organizer
      8th International Conference on Green and Sustainable Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 含フッ素機能性リン化合物を用いた貴金属資源およびリン資源のリサイクル利用2017

    • Author(s)
      佐藤 悠樹 川口 真一 野元 昭宏 小川 昭弥
    • Organizer
      第6回JACI/GSCシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] 遷移金属触媒による一酸化炭素および内部アルキンを用いた環化カルボニル化反応の開発2017

    • Author(s)
      倉田 大地 東前 信也 樋口 嘉博 小川 昭弥
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2-アルキニル安息香酸エステルからのI2/PPh3/H2O複合系を用いたフタリド合成および反応経路の検討2017

    • Author(s)
      中村健太郎 川口 真一 野元 昭宏 小川 昭弥
    • Organizer
      2017ハロゲン利用ミニシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] コバルト触媒による内部アルキンの環化カルボニル化反応におけるジスルフィドの効果2017

    • Author(s)
      倉田大地 東前信也 小川昭弥
    • Organizer
      日本エネルギー学会関西支部「第62回研究発表会」
    • Related Report
      2017 Annual Research Report
  • [Presentation] メタルフリー条件下, o -アルキニル安息香酸エステルを用いたカスケード型フタリド合成2017

    • Author(s)
      中村健太郎 川口 真一 野元 昭宏 小川 昭弥
    • Organizer
      日本エネルギー学会関西支部「第62回研究発表会」
    • Related Report
      2017 Annual Research Report
  • [Presentation] チオグルコースを導入したクロリンe6誘導体の合成と光癌治療への応用2017

    • Author(s)
      佐藤悠樹 川口真一 野元昭宏 小川昭弥
    • Organizer
      第44回有機典型元素化学討論会プログラム
    • Related Report
      2017 Annual Research Report
  • [Presentation] BPO-(PhSe)2複合系を用いたメタルフリープロセスによる内部アルキン類への異種ヘテロ原子官能基同時導入反応の開発2016

    • Author(s)
      三原慧, 佐伯智和, 野元昭宏, 小川昭弥
    • Organizer
      石油学会関西支部第25回研究発表会-日本エネルギー学会関西支部第61回研究発表会:合同研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルケン類の高位置選択的なホスフィニルホスフィノ化反応2016

    • Author(s)
      佐藤悠樹, 川口真一, 野元昭宏, 小川昭弥
    • Organizer
      第43回有機典型元素化学討論会
    • Place of Presentation
      仙台
    • Year and Date
      2016-12-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Selective Synthesis of Sulfur-Functionalized Lactones Based on Catalytic Carbonylation of Acetylenic Alcohols.2016

    • Author(s)
      S. Higashimae, A. Nomoto and A. Ogawa
    • Organizer
      2016 4th TKU-OPU Joint Symposium
    • Place of Presentation
      台湾
    • Year and Date
      2016-11-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Oxidative Coupling of Benzylamines to Imines Using Salicylic Acids as Organocatalysts under Oxygen2016

    • Author(s)
      C. P. Dong, S. Kumazawa, A. Nomoto, A. Ogawa
    • Organizer
      The 10th International Symposium on Integrated Synthesis (ISONIS-10)
    • Place of Presentation
      淡路島
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Amine to Imine Oxidation Catalyzed by Salicylic Acids: It’s Application to N-Heterocycles and Catalyst Recycling2016

    • Author(s)
      S. Kumazawa, C. P. Dong, M. Ueshima, A. Ogawa
    • Organizer
      The 10th International Symposium on Integrated Synthesis (ISONIS-10)
    • Place of Presentation
      淡路島
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金触媒を用いた不活性アルケンの位置選択的ヒドロチオレーション2016

    • Author(s)
      藤原慧子、東前信也、玉井太一, 野元昭宏、小川昭弥
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Transition-Metal-Catalyzed Highly Selective Thiolative Lactonization of Acetylenic Alcohols with Carbon Monoxide and Organic Disulfides.2016

    • Author(s)
      S. Higashimae, A. Nomoto and A. Ogawa
    • Organizer
      20th International Symposium on Homogeneous Catalysis (ISHCXX)
    • Place of Presentation
      京都
    • Year and Date
      2016-07-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Highly Selective Synthesis of 1-Phosphinyl-2-phosphinoalkanes via Radical Addition of Diphosphine Monoxides to Alkenes2016

    • Author(s)
      Y. Sato, S-i. Kawaguchi, A. Nomoto and A. Ogawa
    • Organizer
      2016 4th TKU-OPU Joint Symposium
    • Place of Presentation
      台湾
    • Year and Date
      2016-06-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Markovnikov-Selective Hydroselenation of N-Vinyl Lactams with Selenols Catalyzed by Palladium Diacetate.2016

    • Author(s)
      S. Higashimae, T. Tamai, M. Yoshikawa, A. Nomoto and A. Ogawa
    • Organizer
      The 13th International Conference on the Chemistry of Selenium and Tellurium (ICCST-13)
    • Place of Presentation
      岐阜
    • Year and Date
      2016-05-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Highly Selective Introduction of Group 15 and 16 Heteroatoms into Terminal Alkynes Leading to Bifunctional Alkenes2016

    • Author(s)
      Y. Sato, S-i. Kawaguchi, A. Nomoto and A. Ogawa
    • Organizer
      The 13th International Conference on the Chemistry of Selenium and Tellurium (ICCST-13)
    • Place of Presentation
      岐阜
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 大阪府立大学工学研究科有機合成化学研究グループ

    • URL

      http://www2.chem.osakafu-u.ac.jp/ohka/ohka8/index.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 大阪府立大学 有機合成化学研究室

    • URL

      http://www2.chem.osakafu-u.ac.jp/ohka/ohka8/publications.html

    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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