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Synthesis of conjugated organic compounds using fluorinated isobenzofurans

Research Project

Project/Area Number 16H04143
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionGunma University

Principal Investigator

Amii Hideki  群馬大学, 大学院理工学府, 教授 (00284084)

Co-Investigator(Kenkyū-buntansha) 杉石 露佳  群馬大学, 大学院理工学府, 助教 (30636220)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2018: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2017: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2016: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywordsフッ素 / 有機合成化学 / トリフルオロメチル基 / イソベンゾフラン / 環化付加 / 共役化合物 / 有機合成反応 / 環化付加反応
Outline of Final Research Achievements

Fluorinated isobenzofurans are considered to be promising building blocks for the synthesis of fluorine-containing carbocyclic and heterocyclic systems. We have developed a novel method for the generation of trifluoromethylated isobenzofurans. The cascade trifluoromethylation/intramolecular acetalization of o-phthalaldehyde proceeded smoothly to give the lactol in high yield. The lactol easily underwent dehydration under acidic conditions to generate trifluoromethylated isobenzofuran, which underwent the intermolecular Diels-Alder reactions with alkenes to give the adducts in good yields. The resultant bicyclo compounds are good precursors of functionalized 1-trifluoromethylnaphthalenes. For instance, [4+2] cycloaddition with naphthpquinone and the subsequent transformations gave trifluoromethylated tetracene. We have obtained several interesting products by the [4+2] cycloaddition of trifluoromethylated isobenzofuran with 1,4-benzoquinone and acenaphthylene.

Academic Significance and Societal Importance of the Research Achievements

π共役系有機化合物は、光電子物性を司る主幹構成部位として、材料、デバイス開発の根幹を担っている。共役系が拡張した化合物は、一般的には空気中で不安定なものが多い。今回の一連の研究により、フッ素の特性を活かして、多様な構造をもつ安定なπ共役系有機分子を選択的に合成する方法を見出だした。本研究が新しい材料創製に繋がることを期待している。

Report

(4 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (74 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (6 results) Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 12 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (54 results) (of which Int'l Joint Research: 26 results,  Invited: 19 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] University of Louisville(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Universite Paul Sabatier/Universite de Montpellier(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Universitat de Valencia(スペイン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University of Louisville(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Universite Paul Sabatier(フランス)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Universitat de Valencia(スペイン)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center2019

    • Author(s)
      Shimoaka Takafumi、Sonoyama Masashi、Amii Hideki、Takagi Toshiyuki、Kanamori Toshiyuki、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 123 Issue: 18 Pages: 3985-3991

    • DOI

      10.1021/acs.jpca.8b11613

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Solvent-Promoted Catalyst-Free Nucleophilic Fluoroalkylation of Aldehydes2019

    • Author(s)
      Kazuki Komoda, Ai Shimokawa, and Hideki Amii
    • Journal Title

      ChemistrySelect

      Volume: 4 Issue: 8 Pages: 2374-2378

    • DOI

      10.1002/slct.201900456

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stability of the two-dimensional lattice of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine bilayers2019

    • Author(s)
      Takahashi Hiroshi、Yoshino Masaru、Morita Kohei、Takagi Toshiyuki、Yokoyama Yasunori、Kikukawa Takashi、Amii Hideki、Kanamori Toshiyuki、Sonoyama Masashi
    • Journal Title

      Biochimica et Biophysica Acta (BBA) - Biomembranes

      Volume: 1861 Issue: 3 Pages: 631-642

    • DOI

      10.1016/j.bbamem.2018.12.015

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] opper-Promoted Cross-Coupling Reactions for the Synthesis of Aryl(difluoromethyl)phosphonatesUsing Trimethylsilyl(difluoromethyl)phosphonate2018

    • Author(s)
      Kazuki Komoda, Rei Iwamoto, Masakazu Kasumi, and Hideki Amii
    • Journal Title

      Molecules

      Volume: 23 Issue: 12 Pages: 3292-3292

    • DOI

      10.3390/molecules23123292

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate2017

    • Author(s)
      Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, Hideki Amii
    • Journal Title

      Synthesis

      Volume: 49 Issue: 08 Pages: 1874-1878

    • DOI

      10.1055/s-0036-1589477

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Study of Perfluoroalkyl Chain-Specific Band Shift in Infrared Spectra on the Chain Length2017

    • Author(s)
      Shimoaka Takafumi、Sonoyama Masashi、Amii Hideki、Takagi Toshiyuki、Kanamori Toshiyuki、Hasegawa Takeshi
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 121 Issue: 44 Pages: 8425-8431

    • DOI

      10.1021/acs.jpca.7b08940

    • NAID

      120006364087

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index2017

    • Author(s)
      Zhichao Lu, Junbin Han, Otome Okoromoba, Naoto Shimizu, Hideki Amii, Hideki; Claudio Tormena, Gerald B. Hammond, Bo Xu
    • Journal Title

      Organic Letters

      Volume: 19 Issue: 21 Pages: 5848-5851

    • DOI

      10.1021/acs.orglett.7b02829

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enolate-Based Strategies to Construct <i>gem</i>-Difluoromethylene Compounds2017

    • Author(s)
      Hideki Amii
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 75 Issue: 11 Pages: 1125-1132

    • DOI

      10.5059/yukigoseikyokaishi.75.1125

    • NAID

      130006196250

    • ISSN
      0037-9980, 1883-6526
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 便利!汎用試薬を使うトリフルオロメチル化反応2017

    • Author(s)
      杉石露佳, 網井秀樹
    • Journal Title

      月刊「化学」

      Volume: 72 Pages: 66-67

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trifluoromethylation of Aryl Iodides Catalyzed by the Copper(I)-Phen Complex2016

    • Author(s)
      Naoto Shimizu, Hideaki Kondo, Masahiro Oishi, Kenichi Fujikawa, Kazuki Komoda, and Hideki Amii
    • Journal Title

      Organic Syntheses

      Volume: 93 Pages: 147-162

    • DOI

      10.15227/orgsyn.093.0147

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Lateral Diffusion and Molecular Interaction in a Bilayer Membrane Consisting of Partially Fluorinated Phospholipids2016

    • Author(s)
      Y. Okamoto, T. Motegi, K. Morita, T. Takagi, H. Amii, T. Kanamori, M. Sonoyama, R. Tero
    • Journal Title

      Langmuir

      Volume: 32 Issue: 41 Pages: 10712-10718

    • DOI

      10.1021/acs.langmuir.6b02874

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface Properties of a Single Perfluoroalkyl Group on Water Surfaces Studied by Surface Potential Measurements2016

    • Author(s)
      Takafumi Shimoaka, Yuki Tanaka, Nobutaka Shioya, Kohei Morita, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Takeshi Hasegawa
    • Journal Title

      J. Colloid Interface Sci.

      Volume: 483 Pages: 353-359

    • DOI

      10.1016/j.jcis.2016.08.055

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] Recent Progress in Aromatic Fluoroalkylation2019

    • Author(s)
      Hideki Amii
    • Organizer
      International Conference on Chemical Sciences and Nanomaterials (ICCSN2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 二種のアルキンを用いたトリフルオロメチルピロールの合成2019

    • Author(s)
      海老沼明希, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第99春季年会2019
    • Related Report
      2018 Annual Research Report
  • [Presentation] Generation and Applications of Fluorobenzyl Anions2019

    • Author(s)
      Hideki Amii
    • Organizer
      257th ACS National Meeting & Exposition
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ジフルオロメチレン化合物合成の新展開2018

    • Author(s)
      網井秀樹
    • Organizer
      フッ素化学の最前線とフッ素化学工業セミナー2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 有機フッ素化合物の触媒的合成:技術開発と展開2018

    • Author(s)
      網井秀樹
    • Organizer
      有機合成化学協会中国四国支部第77回パネル討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] エトキシカルボニルジフルオロメチル基の芳香環への触媒的導入反応2018

    • Author(s)
      Hanan Alaghawani, 藤川憲一, 杉石露佳, 網井秀樹
    • Organizer
      第7回JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 急進展する有機フッ素化合物の触媒的合成2018

    • Author(s)
      網井秀樹
    • Organizer
      第53回有機反応若手の会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Reactions of Fluorinated Benzocyclobutenone Derivatives2018

    • Author(s)
      Hideki Amii
    • Organizer
      The 22nd International Symposium on Fluorine Chemistry (ISFC-22)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ジフルオロベンゾシクロブテノン誘導体を用いた環化付加反応の開発2018

    • Author(s)
      小茂田和希, 田中惟吹, 大嶋拓也, 杉石露佳, 網井秀樹
    • Organizer
      第8回フッ素化学若手の会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Reactions of Trifluoromethyl Isobenzofurans with Quinones2018

    • Author(s)
      Yukari Matsumoto, Yoshimasa Hikobe, Shun Shinada, Masanori Inaba, Yuta Nishina, and Hideki Amii
    • Organizer
      International Symposium on Main Group Chemistry Directed towards Organic Synthesis (MACOS)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent Progress of Aromatic Difluoromethylation and the Related Reactions2018

    • Author(s)
      Hideki Amii
    • Organizer
      1st International Symposium of Soft Molecular Activation Research Center (SMARC)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis and Reactions of Fluorinated Benzocyclobutenone Derivatives2018

    • Author(s)
      Hideki Amii
    • Organizer
      International Congress on Pure & Applied Chemistry Langkawi 2018 (ICPAC Langkawi 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Generation and Applications of Monofluorobenzyl Anions2018

    • Author(s)
      Taku Kitahara, Yuuta Tagami, Masaki Ono, Tsuyuka Sugiishi, S. Matsubara, Santos Fustero,and Hideki Amii
    • Organizer
      The 13th International Symposium on Organic Reactions (ISOR-13)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フッ素化シクロプロパンの環拡大反応による3-フルオロフランの合成2018

    • Author(s)
      松村千穂里,杉石露佳,網井秀樹
    • Organizer
      第76回有機合成化学協会関東支部シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Studies of Development of Nucleophilic α-(Pheylthio)difluoromethylation2018

    • Author(s)
      Naoto Ogaki, Kazuki Komoda, Tsuyuka Sugiisi, Hideki Amii
    • Organizer
      The 6th International Symposium of Gunma University Initiative for Advanced Research (GIAR)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Synthesis of o-(Difluoromethyl)benzoates from (o-Bromoaryl)difluoroacetates2018

    • Author(s)
      Takuya Oshima, Kazuki Komoda, Tsuyuka Sugiishi, Hideki Amii
    • Organizer
      The 6th International Symposium of Gunma University Initiative for Advanced Research (GIAR)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] eneration and Reactions of 2,2,2-Trifluoro-1-(phenylsulfonyl)ethyl Anion2018

    • Author(s)
      Ryosuke Arai, Yoshiyuki Murata, Aiichiro Nagaki, Junichi Yoshida, Hideki Amii
    • Organizer
      The First International Conference on Automated Flow and Microreactor Synthesis (ICAMS-1)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Generation and Synthetic Applications of Trifluoromethyl Isobenzofurans2018

    • Author(s)
      Shun Shinada, Masanori Inaba, Yoshimasa Hikobe, Yuta Nishina, and Hideki Amii
    • Organizer
      The First International Conference on Automated Flow and Microreactor Synthesis (ICAMS-1)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 触媒的芳香族トリフルオロメチル化2018

    • Author(s)
      網井秀樹
    • Organizer
      JSPS第155委員会主催講演会平成29年度第2回「フッ素と医療の研究最前線」
    • Related Report
      2017 Annual Research Report
  • [Presentation] 有機フッ素化合物の合成法開発と18F放射性医薬の創製・臨床応用の新展開2018

    • Author(s)
      網井秀樹
    • Organizer
      日本学術振興会フッ素化学第155委員会第111回研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Recent Progress in Nucleophilic Fluoroalkylations2018

    • Author(s)
      Hideki Amii
    • Organizer
      Conferencia, Universitat de Valencia
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] マイクロフロー法によるラジカル的ペルフルオロアルキル化の反応制御2018

    • Author(s)
      渡部鯨波, 新井椋介, 園山正史, 網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ素化ベンゾシクロブテノン誘導体の合成と反応2018

    • Author(s)
      小茂田和希,田中惟吹,杉石露佳,網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] α-フルオロベンジルジアニオン等価体の反応2018

    • Author(s)
      田上祐太, 北原拓, 小野雅樹, 杉石露佳, 松原誠二郎, 網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] 求核的α-(フェニルチオ)ジフルオロメチル化反応の新開発2018

    • Author(s)
      大垣直登, 小茂田和希, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ素化シクロプロパンの環拡大反応による3-フルオロフランの合成2018

    • Author(s)
      松村千穂里, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] トリフルオロメチル化イソベンゾフランとキノン類の反応2018

    • Author(s)
      松本由香理, 彦部圭政, 品田瞬, 稲葉公則, 仁科勇太, 網井秀樹
    • Organizer
      日本化学会第98春季年会2018
    • Related Report
      2017 Annual Research Report
  • [Presentation] 芳香族モノフルオロメチル化合物のラジカル的変換反応2017

    • Author(s)
      下川あい,上山晃平,森岡亮,杉石露佳,網井秀樹
    • Organizer
      第6回 JACI/GSCシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] アリールジフルオロメチルアニオン種の不飽和エステルへの1,4-付加反応2017

    • Author(s)
      甲谷渉, 杉石露佳, 網井秀樹
    • Organizer
      第6回 JACI/GSCシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Recent Progress in Catalytic Aromatic Fluoroalkylation2017

    • Author(s)
      Hideki Amii
    • Organizer
      The 8th International Meeting on Halogen Chemistry (HALCHEM VIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Generation and Reactions of 2,2,2-Trifluoro-1-(phenylsulfonyl)ethyl Carbanion2017

    • Author(s)
      Ryosuke Arai, Yoshiyuki Murata, Aiichiro Nagaki, Junichi Yoshida, Hideki Amii
    • Organizer
      The 8th International Meeting on Halogen Chemistry (HALCHEM VIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Generation and Reaction of Simple a-Monofluorobenzyl Anions2017

    • Author(s)
      Yuta Tagami, Taku Kitahara, Tsuyuka Sugiishi, Hideki Amii
    • Organizer
      The 8th International Meeting on Halogen Chemistry (HALCHEM VIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Copper-Catalyzed Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate2017

    • Author(s)
      Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, Hideki Amii
    • Organizer
      The 8th International Meeting on Halogen Chemistry (HALCHEM VIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 急進展する有機フッ素化合物の合成法2017

    • Author(s)
      網井秀樹
    • Organizer
      第15回有機合成化学談話会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ホウ素反応剤を用いる触媒的芳香族ペンタフルオロエチル化2017

    • Author(s)
      杉石露佳, 河内大佑, 佐藤瑞記, 坂井達也, 網井秀樹
    • Organizer
      第35回メディシナルケミストリーシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis and Application of Fluorinated Benzocyclobutenone Derivatives2017

    • Author(s)
      Kazuki Komoda, Takuya Oshima, Tsuyuka Sugiishi, Hideki Amii
    • Organizer
      The 10th Japanese-French Joint Seminar on Fluorine Chemistry
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アリールジフルオロメチルアニオン種の不飽和エステルへの共役付加反応2017

    • Author(s)
      甲谷渉, 杉石露佳, 網井秀樹
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] フッ素化ベンゾシクロブテノン誘導体の開環反応とその応用2017

    • Author(s)
      小茂田和希, 大嶋拓也, 杉石露佳, 網井秀樹
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Fluoroalkylation/Cyclization Route to Fluorinated Phthalides2017

    • Author(s)
      Masanori Inaba, Tatsuya Sakai, Shun Shinada, Tsuyuka Sugiishi, Yuta Nishina, Norio Shibata, Hideki Amii
    • Organizer
      The 11th International Symposium on Integrated Synthesis (ISONIS-11)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 官能基を有する芳香族モノフルオロメチル化合物の変換反応2017

    • Author(s)
      下川あい, 森岡 亮, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第97春季年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] フッ素化ベンゾシクロブテノン誘導体の合成と反応2017

    • Author(s)
      小茂田和希, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第97春季年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] A Convenient Decarboxylative Route to Difluoromethylene Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      The 12th International Symposium on Organic Reactions (ISOR-12)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] β-炭素脱離による触媒的芳香族トリフルオロメチル化とペンタフルオロエチル化2016

    • Author(s)
      小茂田和希, 清水直登, 久保田結衣, 杉石露佳, 芹澤宏希, 相川光介, 三上幸一, 網井秀樹
    • Organizer
      第71回有機合成化学協会関東支部シンポジウム (東京農工大シンポジウム)
    • Related Report
      2016 Annual Research Report
  • [Presentation] A Convenient Protocol for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate2016

    • Author(s)
      Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatuya Sakai, and Hideki Amii
    • Organizer
      20th International Symposium on Homogeneous Catalysis (ISHCXX)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Synthesis of gem-Difluoromethylene Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      18th European Symposium on Fluorine Chemistry
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Decarboxylative Route to Organofluorine Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      INTERNATIONAL SYMPOSIUM ON PURE & APPLIED CHEMISTRY (ISPAC)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 置換基を有するトリフルオロメチルイソベンゾフランの発生と合成化学的応用2016

    • Author(s)
      彦部圭彦, 品田瞬, 稲葉公則, 仁科勇太,網井秀樹
    • Organizer
      第6回フッ素化学若手の会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 触媒的フッ素官能基導入反応の新設計と応用2016

    • Author(s)
      網井秀樹
    • Organizer
      Ambitious物質科学セミナー(北海道大学)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Recent Progress in Catalytic Aromatic Trifluoromethylation2016

    • Author(s)
      Hideki Amii
    • Organizer
      3rd International Conference on Past and Present Research Systems of Green Chemistry
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] リフルオロメチル化イソベンゾフランを用いた共役系多環化合物の合成2016

    • Author(s)
      彦部圭政, 品田瞬, 稲葉公則, 仁科勇太, 網井秀樹
    • Organizer
      第39回フッ素化学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Recent Progress in Catalytic Aromatic Trifluoromethylation2016

    • Author(s)
      Hideki Amii
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2016 (C&FC 2016)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Generation and Reactions of Aryldifluoromethyl Radicals2016

    • Author(s)
      Kouhei Ueyama, Ryou Kasuga, Hitomi Kimura, Tsuyuka Sugiishi, and Hideki Amii
    • Organizer
      The 10th International Symposium on Integrated Synthesis (ISONIS-10)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Recent Progress in Nucleophilic Fluoroalkylations2016

    • Author(s)
      Hideki Amii
    • Organizer
      14th National Meeting on Fluorine Chemistry, China
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 触媒的芳香族トリフルオロメチル化と関連反応の開発2016

    • Author(s)
      網井秀樹
    • Organizer
      最新化学談話シリーズ(九州大学)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Book] 有機フッ素化合物の最新動向2018

    • Author(s)
      今野 勉(監修), 網井秀樹(分担執筆)ら
    • Total Pages
      317
    • Publisher
      シーエムシー出版
    • ISBN
      9784781313375
    • Related Report
      2018 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素及びフッ素及び/または塩素を含有したブタジエン骨格を有する化合物の製造方法2017

    • Inventor(s)
      網井 秀樹, 下田 光 春, 池谷 慶彦, 木村 涼
    • Industrial Property Rights Holder
      網井 秀樹, 下田 光 春, 池谷 慶彦, 木村 涼
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-088665
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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