Self-supporting gas separation membranes by molecular sieving effects of molecular size pores in 2D macromolecules synthesized by SCAT reaction of helical polymers

• Project/Area Number: 16H04153
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer chemistry
• Research Institution: Niigata University
• Principal Investigator: AOKI Toshiki 新潟大学, 自然科学系, 教授 (80212372)
• Co-Investigator(Kenkyū-buntansha): 金子 隆司 新潟大学, 自然科学系, 教授 (90272856) ; 寺口 昌宏 新潟大学, 自然科学系, 助教 (30334650)
• Project Period (FY): 2016-04-01 – 2021-03-31
• Project Status: Completed (Fiscal Year 2020)
• Budget Amount: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000); Fiscal Year 2020: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000); Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2016: ¥8,580,000 (Direct Cost: ¥6,600,000、Indirect Cost: ¥1,980,000)
• Keywords: 高分子合成 / 合成化学 / 反応・分離工学 / 分子認識 / 高分子構造・物性 / 高分子

Outline of Final Research Achievements

A thin layer of 2D macromolecules with molecular-sized pores was synthesized by solid-solid interface polycondensation in laminated membranes of two cis-cisoid poly(imino-containing phenylacetylene)s followed by highly selective photocyclic aromatization (SCAT). The precise 2D molecular structure including fraction and size of rings (pores) can be fully estimated. The composite membranes of the 2D macromolecule showed good oxygen permselectivity exceeding the Robeson upper line.

Academic Significance and Societal Importance of the Research Achievements

学術的意義：高分子はありふれた身の回りにあるそして我々の生体を構成している物質であるが、その分子構造の多くは一次元(1D)あるいは三次元(3D)である。一方で、二次元(2D)の高分子の例は殆どなく、また、知られているものも不溶であり、その分子構造の精密なキャラクタリゼーションは達成されていない。本研究では、新しい方法で可溶な2D高分子の合成とキャラクタリゼーションに成功した。
社会的意義：従来の酸素と窒素の分離膜は、高分子の分子間隙という不安定な孔をその透過経路としており、分離性は低く、性能の安定性も不十分であった。本研究では、高分子内に安定な分子孔を形成させ、高く安定な分離性の実現に成功した。

Research Products

• [Journal Article] Synthesis of cis-cisoid or cis-transoid poly(phenyl- 2 acetylene)s having one or two carbamate groups as 3 oxygen permeation membrane materials (2020)
  • Author(s): Yu Zang, Yinghui Lun, Masahiro Teraguchi, Takashi kaneko, Hongge Jia, Fengjuan Miao, Xunhai Zhang, Toshiki Aoki
  • Journal Title: Membranes Volume: 10(9) Issue: 9 Pages: 199-199
  • DOI: 10.3390/membranes10090199
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and Permselectivity of a Soluble Two-Dimensional Macromolecular Sheet by Solid-Solid Interfacial Polycondensation followed by Chemical Exfoliation (2020)
  • Author(s): Yanqing Qu, Xiaoyu Du, Kehan Cheng, Yu Zang, Liang Xu, Ken-ichi Shinohara, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
  • Journal Title: ACS Materials Lett. Volume: 2 Issue: 9 Pages: 1121-1128
  • DOI: 10.1021/acsmaterialslett.0c00178
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of well-defined chiral oligopinanylsiloxane graft copolyphenylacetylenes by macromonomer method and their enantioselective permeability (2020)
  • Author(s): Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Fengjuan Miao
  • Journal Title: ACS Appl. Polym. Mater. Volume: 2(2) Issue: 2 Pages: 853-861
  • DOI: 10.1021/acsapm.9b01111
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis, In-situ Membrane Preparation, and Good Gas Permselectivity of Insoluble Poly(substituted acetylene)s Loosely Cross-linked with Short and Soft Siloxane and Silanol Linkages (2020)
  • Author(s): Jianjun Wang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polymer Volume: 187 Pages: 122081-122081
  • DOI: 10.1016/j.polymer.2019.122081
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Helix-sense-selective Polymerization of 3,5-bis(hydroxymethyl)phenylacetylene Rigidly Bearing Galvinoxyl Residues and Their Chiroptical Properties (2019)
  • Author(s): Zhichun Shi, Jianjun Wang, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
  • Journal Title: Polymers Volume: 11(11) Issue: 11 Pages: 1877-1877
  • DOI: 10.3390/polym11111877
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Antiparallel Arrangement of 2,7-Substituted 9,10-Bis(phenylethynyl)anthracene Assisted by Hydrogen Bonding of Terminal Units (2019)
  • Author(s): Takashi Kaneko, Yosuke Araki, Ken-ichi Shinohara, Masahiro Teraguchi, Toshiki Aoki
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 92 Issue: 10 Pages: 1672-1678
  • DOI: 10.1246/bcsj.20190156
  • NAID: 130007728632
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] New synthetic methods of novel nanoporous polycondensates and excellent oxygen permselectivity of their composite membranes (2019)
  • Author(s): Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Hongge Jia, Liqun Ma, Fengjuan Miao
  • Journal Title: Nanomaterials Volume: 9(6) Issue: 6 Pages: 859-859
  • DOI: 10.3390/nano9060859
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Simultaneous improvement of permeability and selectivity in enantioselective permeation through solid chiral membranes from a newly synthesized one-handed helical polyphenylacetylene with aldehyde pendant groups by enantioselective reaction (2019)
  • Author(s): Yu Zang, Yanqing Qu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Hongge Jia, Liqun Ma, Fengjuan Miao
  • Journal Title: Polymer Volume: 171 Pages: 45-49
  • DOI: 10.1016/j.polymer.2019.03.039
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of a novel AB block copolyaceylene consisting of a dynamic cis-transoidal racemic helical sequence and a static cis-cisoidal one-handed helical sequence (2019)
  • Author(s): Guanwu Yin, Junpei Suzuki, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chem. Lett. Volume: 48(6) Issue: 6 Pages: 506-509
  • DOI: 10.1246/cl.190109
  • NAID: 130007659774
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Helix-Sense-Selective Polymerization of Phenylacetylenes Having a Porphyrin and a Zinc-Porphyrin Group: One-Handed Helical Arrangement of Porphyrin Pendants (2019)
  • Author(s): Masahiro Teraguchi, Nobuyuki Nahata, Takahiro Nishimura, Toshiki Aoki, Takashi Kaneko
  • Journal Title: Polymers Volume: 11 Issue: 2 Pages: 274-274
  • DOI: 10.3390/polym11020274
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and Ultrahigh Oxygen Permeability of Silicon-containing <i>cis</i>-<i>cisoidal</i> Poly(substituted phenylacetylene)s (2018)
  • Author(s): Chenxi Xu, Toshiki Aoki, Liqun Ma, Hongge Jia, Massahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chemistry Letters Volume: 47 Issue: 10 Pages: 1314-1317
  • DOI: 10.1246/cl.180641
  • NAID: 130007496064
  • ISSN: 0366-7022, 1348-0715
  • Year and Date: 2018-10-05
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] [Rh(L-alanine)(1,5-Cyclooctadiene)] Catalyzed Helix-Sense-SelectivePolymerizations of Achiral Phenylacetylenes (2018)
  • Author(s): Qingyu Wang, Hongge Jia, Yongqiang Shi, Liqun Ma, Guoxing Yang, Yazhen Wang, Shuangping Xu, Jianjun Wang, Yu Zang, Toshiki Aoki,
  • Journal Title: Polymers Volume: 10(11) Issue: 11 Pages: 1223-1223
  • DOI: 10.3390/polym10111223
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and oxygen permeability of novel graft copolymers consisting of a polyphenylacetylene backbone and long oligosiloxane grafts from phenylacetylene-type macromonomers (2018)
  • Author(s): Yu Zang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Liqun Ma, Hongge Jia, Fengjuan Miao,
  • Journal Title: Polymer Volume: 156 Pages: 66-70
  • DOI: 10.1016/j.polymer.2018.09.048
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Chiral Teletransmission in the Cis-cisoidal Sequence of Copoly(substituted acetylene)s by Multiple Stage Solvent Exchange of the Copolymer Solution through a Membrane (2018)
  • Author(s): Lijia Liu, Yuanyuan Gu, Yudan Wang, Toshiki Aoki*, Guan Wang, Takashi Kaneko, Masahiro Teraguchi
  • Journal Title: Polymer Volume: 154 Pages: 253-257
  • DOI: 10.1016/j.polymer.2018.09.023
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Enhanced performances of enantioselective permeation through one-handed helical polymer membranes by enantioselective imine exchange reaction with permeants and by partially decomposed reaction of the membrane (2018)
  • Author(s): Yanqing Qu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polymer Volume: 156 Pages: 39-43
  • DOI: 10.1016/j.polymer.2018.09.009
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Solvent-tuned dual emission of a helical poly[3,5-bis(hydroxymethyl)phenylacetylene] connected with a π-conjugated chromophore (2018)
  • Author(s): Shi Zhichun、Kwak Giseop、Jin Young-Jae、Teraguchi Masahiro、Aoki Toshiki、Kaneko Takashi
  • Journal Title: Polymer Journal Volume: 50 Issue: 7 Pages: 533-537
  • DOI: 10.1038/s41428-018-0045-7
  • NAID: 40021575871
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Ultrahigh oxygen permeability of chemically-modified membranes of novel (co)polyacetylenes having a photodegradative backbone and crosslinkable side chains (2018)
  • Author(s): Mingyu Zhang, Toshiki Aoki*, Lijia Liub, Jianjun Wang, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polymer Volume: 149 Pages: 117-123
  • DOI: 10.1016/j.polymer.2018.06.075
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of soluble oligsiloxane-end-capped hyperbranched polyazomethine and their application to CO2/N2 separation membranes (2018)
  • Author(s): Liang Xu, Tianyang Lei, Boyu Jing, Yu Zang*, Fengjuan Miao, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Des. Monomers Polym. Volume: 21(1) Issue: 1 Pages: 99-104
  • DOI: 10.1080/15685551.2018.1472720
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and oxygen permeation of novel well-defined homopoly(phenylacetylene)s with different sizes and shapes of oligosiloxanyl side groups (2018)
  • Author(s): Yu Zang, Toshiki Aoki, Kazuki Shoji, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Fengjuan Miao
  • Journal Title: J. Membrane. Sci. Volume: 561 Pages: 26-38
  • DOI: 10.1016/j.memsci.2018.04.031
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of two well-defined quadruple-stranded copolymers having two kinds of backbones by post polymerization of a helical template polymer (2017)
  • Author(s): Yu Zang*, Toshiki Aoki*, Hiroyoki Tanagi, Kana Matsui, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Ken-ichi Shinohara
  • Journal Title: Macromol. Rapid Commun. Volume: 39(4) Issue: 4 Pages: 1700556-1700560
  • DOI: 10.1002/marc.201700556
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Transformer of Achiral Amounts to Chirality: Double Reversal of Enantioselectivity Using a Single Cocatalyst in Asymmetric Polymerization (2017)
  • Author(s): Guanwu Yin, Geng Zhang, Toshiki Aoki,* Masahiro Teraguchi, Takashi Kaneko, Jesus Rodriguez Castanon, Masashi Shiotsuki, Fumio Sanda
  • Journal Title: Macromolecules Volume: 50(19) Issue: 19 Pages: 7468-7474
  • DOI: 10.1021/acs.macromol.7b01671
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Oxygen permselectivities through supramolecular polymer membranes prepared by highly selective photocyclic aromatization of poly(substituted acetylene) (2017)
  • Author(s): Guanwu Yin, Eri Ohtaka, Toshiki Aoki, Jianjun Wang, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Polymer Volume: 127 Pages: 232-235
  • DOI: 10.1016/j.polymer.2017.08.066
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Subnanoporous Highly Oxygen Permselective Membranes from Poly(conjugated hyperbranched macromonomer)s Synthesized by One-pot Simultaneous Two-mode Homopolymerization of 1,3-Bis(silyl)phenylacetylene Using a Single Rh Catalytic System : Control of their Structures and Permselectivities (2017)
  • Author(s): Jianjun Wang, Jun Li, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Zhichun Shi, Hongge Jia
  • Journal Title: Macromolecules Volume: 50(18) Issue: 18 Pages: 7121-7136
  • DOI: 10.1021/acs.macromol.7b01458
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] A New Analysis Method for Quantitative Determination of Triads of Copoly(Substituted Acetylene)s’ Backbones by Highly Selective Photocyclic Aromatization (2017)
  • Author(s): Guanwu Yin, Nennei Nagaoka, Lijia Liu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chem. Lett. Volume: 46(11) Issue: 11 Pages: 1608-1611
  • DOI: 10.1246/cl.170697
  • NAID: 130006837434
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Oxygen permselectivities of novel multi-bridged copolymers synthesized by imine metathesis between N-imines and C-imines in the pendant groups of two poly(substituted acetylene)s (2017)
  • Author(s): Yinghui Lun, Yu Zang, Toshiki Aoki*, Masahiro Teraguchi, Takashi Kaneko
  • Journal Title: Chem Lett. Volume: 46 Issue: 3 Pages: 401-404
  • DOI: 10.1246/cl.161104
  • NAID: 130005436585
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Helix-sense-selective Polymerization of Achiral Phenylcetylenes and Unique Properties of the Resulting Cis-cisoidal Polymers (2016)
  • Author(s): Liu Lijia*, Yu Zang*, Hongge Jia, Toshiki Aoki*, Takashi Kaneko, Shingo Hadano, Masahiro Teraguchi, Mari Miyata, Geng Zhang, Takeshi Namikoshi
  • Journal Title: Polym. Rev. Volume: 56 Issue: 1 Pages: 89-118
  • DOI: 10.1080/15583724.2016.1160930
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis of One-handed Helical Block Copoly(substituted Acetylene)s Consisting of Dynamic Cis-transoidal and Static Cis-cisoidal Block : Chiral Teleinduction in Helix-sense-selective Polymerization Using a Chiral Living Polymer as an Initiator (2016)
  • Author(s): Lijia Liu*, Geng Zhang, Toshiki Aoki*, Yudan Wang, Takashi Kaneko, Masahiro Teraguchi, Chunhong Zhang, Hongxing Dong
  • Journal Title: ACS Macro Letters Volume: 5 Issue: 12 Pages: 1381-1385
  • DOI: 10.1021/acsmacrolett.6b00809
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Presentation] 水酸基とアルキル鎖を持つフェニルアセチレンのコポリマー膜の酸素選択透過性 (2021)
  • Author(s): 山口 湧也、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第101春季年会
• [Presentation] ３種の重合官能基を持つモノマーの段階的な重合によるトリプルストランドネットワーク２Ｄポリマー膜の合成と酸素選択透過性の向上 (2021)
  • Author(s): 程 柯涵、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第101春季年会
• [Presentation] 4位にかさ高いトリアルキルシリル基を持つシスシソイダル型ポリ{3,5-ビス(ヒドロキシメチル)フェニルアセチレン}の合成および高選択的環化芳香族化分解(SCAT) (2021)
  • Author(s): 阿部 幸也、金子 隆司、青木 俊樹、寺口 昌宏
  • Organizer: 日本化学会第101春季年会
• [Presentation] ターフェニル基を含むシス-シソイダル型ポリ[3,5-ビス(ヒドロキシメチル)フェニルアセチレン]の合成とそれらの光学的特性 (2021)
  • Author(s): 澤 真弘、金子 隆司、青木 俊樹、寺口 昌宏
  • Organizer: 日本化学会第101春季年会
• [Presentation] Application of Highly Selective Photocyclicaromatization of cis-cisoidal poly(substituted phenylacetylene)s (2019)
  • Author(s): Toshiki Aoki
  • Organizer: 2019 International Symposium on Polymer Materials and Chemical Engineering, Harbin, China
  • Int'l Joint Research / Invited
• [Presentation] Application of Highly Selective Photocyclicaromatization of cis-cisoidal poly(substituted phenylacetylene)s (2019)
  • Author(s): Toshiki Aoki
  • Organizer: 15thIUPAC International Conference on Novel Materials and their Synthesis(NMS-XV), Shenyang, China
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and gas permeation of two-dimensional ladderphan polymers (2019)
  • Author(s): Toshiki Aoki
  • Organizer: 2019 Collaborative Conference on Materials Research, Seoul, Korea
  • Int'l Joint Research / Invited
• [Presentation] Excellent oxygen permeability of novel silicon-containing cis-cisoidal poly (substituted phenylacetylene) membranes (2019)
  • Author(s): Toshiki Aoki
  • Organizer: Industrial Chemistry and Water Treatment2019, Vancouver, Canada
  • Int'l Joint Research / Invited
• [Presentation] 第2の官能基と2つの水酸基を持つフェニルアセチレンと疎水性フェニルアセチレンとの共重合体の酸素選択透過性 (2019)
  • Author(s): 下斗米 伊吹、細野 晋太朗、桑原 薫、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第100春季年会
• [Presentation] ビニル基と2つの水酸基を持つフェニルアセチレンよりの剛直らせんポリマー膜の製膜条件の後重合および酸素選択透過性への効果 (2019)
  • Author(s): 庄子 和樹、木村 優香、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第100春季年会
• [Presentation] シスシソイダルポリフェニルアセチレンの高選択光環化芳香族化分解で得た超分子ポリマー純粋膜の酸素選択透過性の最適化 (2019)
  • Author(s): 細野 晋太朗、成田 隼也、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第100春季年会
• [Presentation] 二種の鋳型分子を用いた架橋ポリフェニルアセチレンインプリント膜の光学異性体および酸素選択透過性 (2019)
  • Author(s): 尾田 友洋、柴田 みちる、木村 優香、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 日本化学会第100春季年会
• [Presentation] テトラフェニルエチレン部位を有するらせんフォルダマーの合成と刺激応答性蛍光発光 (2019)
  • Author(s): 番場 望、今井 淳、青木 俊樹、金子 隆司、寺口 昌宏
  • Organizer: 第68回高分子討論会
• [Presentation] 含ホウ素置換基を有するプッシュ-プル型ポリ(ジフェニルアセチレン)類の合成と蛍光特性 (2019)
  • Author(s): 荒木 大地、郭 起燮、ジン ヤンジェ、青木 俊樹、金子 隆司、寺口 昌宏
  • Organizer: 第68回高分子討論会
• [Presentation] らせんアセチレンポリマーの高選択光環化芳香族化反応生成物の利用と機能－超分子キラルポリマー調製、ポリマーのミクロ構造分析と超分子膜の分離性能－ (2019)
  • Author(s): 長岡 年寧、Yanqing Qu、山口 湧也、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 第68回高分子学会年次大会
• [Presentation] アミド基を持つアキラルフェニルアセチレンの種々のらせん選択重合と生成ポリマーの反応、性質と機能 (2019)
  • Author(s): 大友 諒平、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 第68回高分子学会年次大会
• [Presentation] Optical resolution of dl-alcohol by enantiomer-selective helix-sense-selective polymerization followed by helix-sense selective highly selective photocyclic aromatization (2019)
  • Author(s): Yanan Tang、Jumpei Suzuki、Masairo Teraguchi、Takashi Kaneko、Toshiki Aoki
  • Organizer: 第68回高分子学会年次大会
• [Presentation] Synthesis and good oxygen permselectivity of novel layered network polymer membranes by intermacromolecular condensation between two kinds of imino pendant groups in two tightly helical cis-cisoidal homopolyphenylacetylenes (2019)
  • Author(s): Yanqing Qu、Masairo Teraguchi、Takashi Kaneko、Toshiki Aoki
  • Organizer: 第68回高分子学会年次大会
• [Presentation] 第二，第三の重合官能基を有するフェニルアセチレンよりのスターマルチストランドコポリマーの合成と酸素選択透過性 (2019)
  • Author(s): 大野貴矢、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第41年会
• [Presentation] 選択透過性ビニルエーテル基のオリゴメリゼーションとポリアセチレンの高選択光環化芳香族化分解による改質と選択透過性の変化 (2019)
  • Author(s): 坂田 俊、浪越 毅、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第41年会
• [Presentation] Top down preparation of supramolecular polymers and their membrane performances (2018)
  • Author(s): Toshiki Aoki
  • Organizer: 2018 EMN Meeting on Supramolecular Materials, Auckland, New Zealand
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and Oxygen Permeation of Hyperbranched Polymers from SiH-containing Phenylacetylenes (2018)
  • Author(s): Toshiki Aoki
  • Organizer: 14thIUPAC International Conference on Novel Materials and their Synthesis(NMS-XIV) , Guangzhou, China
  • Int'l Joint Research / Invited
• [Presentation] Application of the Products by Highly Selective Photocyclicaromatization of cis-cisoidalpoly(substituted phenylacetylene) (2018)
  • Author(s): Toshiki Aoki
  • Organizer: Industrial Chemistry and Water Treatment2018, NY, USA
  • Int'l Joint Research / Invited
• [Presentation] タイトならせん置換ポリフェニルアセチレンよりのスターマルチストランドコポリマーの合成と酸素選択透過性 (2018)
  • Author(s): 大野貴也、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第67回高分子学会北陸支部研究発表会
• [Presentation] Enantioselective permeation through one?handed helical polymer membranes improved by enantioselective imine exchange reaction with permeants and by partially decomposed reaction of the membrane (2018)
  • Author(s): Qu Yanqing、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 膜シンポジウム2018
• [Presentation] Excellent oxygen permeability of novel silicon?containing cis?cisoidal poly (substituted phenylacetylene) membranes (2018)
  • Author(s): 張明宇、徐晨曦、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 膜シンポジウム2018
• [Presentation] ルースまたはタイトならせん置換ポリフェニルアセチレンのペンダント官能基の後重縮合によるスターマルチストランドコポリマーの合成と酸素透過性 (2018)
  • Author(s): 大野貴矢、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第67回高分子討論会
• [Presentation] ジメシチルボリル基を側鎖に有するポリジフェニルアセチレンの合成と蛍光特性 (2018)
  • Author(s): 荒木大地、寺口昌宏、金子隆司、青木俊樹、ジン ヤンジェ、郭 起燮
  • Organizer: 第67回高分子討論会
• [Presentation] 多分岐ポリフェニレンエチニレンとポリフェニルアセチレンとの複合膜の酸素選択透過性 (2018)
  • Author(s): 宮沢菜美、王 建、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第40年会
• [Presentation] Synthesis and Permeation of ring-containing 2D polymers (2017)
  • Author(s): Toshiki Aoki
  • Organizer: 13th IUPAC International Conference on Novel Materials and their Synthesis(NMS-XIII) , Nanjing, China
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and oxygen permselectivity of 2D parts-containing polymer membranes (2017)
  • Author(s): Toshiki Aoki
  • Organizer: EMN2D Materials Meeting, Lyon, France
  • Int'l Joint Research / Invited
• [Presentation] Unusual phenomena in helix-sense-selective polymerization of achiral acetylenes (2017)
  • Author(s): Toshiki Aoki
  • Organizer: Industrial Chemistry and Water Treatment, Las Vegas, USA
  • Int'l Joint Research / Invited
• [Presentation] Oxygen Permselective Membranes of Tightly Helical Polyacetylenes Containing Oligosiloxane Groups as 2DP Precursor Related-Polymers (2017)
  • Author(s): Mingyu Zhang, Toshiki Aoki
  • Organizer: 13th IUPAC International Conference on Novel Materials and their Synthesis(NMS-XIII) , Nanjing, China
  • Int'l Joint Research
• [Presentation] Optical Resolution Membranes from Tightly Helical Polyacetylene Containing Imine Groups (2017)
  • Author(s): Yanqing Qu, Toshiki Aoki
  • Organizer: 13th IUPAC International Conference on Novel Materials and their Synthesis(NMS-XIII) , Nanjing, China
  • Int'l Joint Research
• [Presentation] 定量的光環化３量体生成物による置換アセチレン重合体の構造の定量分析 (１)GPCまたはNMRによる共重合体の三連子の決定 (2017)
  • Author(s): 長岡年寧、尹官武、金子隆司、寺口昌宏、青木俊樹
  • Organizer: 第66回高分子学会北陸支部研究発表会
• [Presentation] ラセミc-t動的らせんと片巻きc-c静的らせんの連鎖よりなるポリフェニルアセチレンブロック共重合体の調製 (2017)
  • Author(s): 鈴木純平、尹官武、金子隆司、寺口昌宏、青木俊樹
  • Organizer: 第66回高分子学会北陸支部研究発表会
• [Presentation] シリル基含有フェニルアセチレンのペンダント末端修飾による気体選択透過性の改良 (2017)
  • Author(s): 宮沢菜美、王建軍、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 膜シンポジウム2017
• [Presentation] 二つのN-アルケニルアミド基を持つ片巻きらせん置換ポリアセチレンのポストADMET重縮合による二重らせんポリマーの合成 (2017)
  • Author(s): 大友 諒平、寺口 昌宏、金子 隆司、青木俊樹
  • Organizer: 第66回高分子討論会
• [Presentation] タイトならせんポリフェニルアセチレン膜のペンダントビニルエーテル基の分子内カチオン重合および主鎖の高選択光環化芳香族化分解による気体透過性の最適化 (2017)
  • Author(s): 坂田俊、浪越 毅、寺口 昌宏、金子 隆司、青木 俊樹
  • Organizer: 第66回高分子討論会
• [Presentation] 規則性ポリ置換フェニルアセチレンのペンダントビニル基のADMET重縮合の前駆体ポリマー構造による分子内・分子間制御：マルチストランドコポリマーと含環コポリマーの合成と環構造の酸素選択透過性への効果 (2017)
  • Author(s): 園佳央理、武尾駿、森谷まどか、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第66回高分子学会年次大会
• [Presentation] 6つの水酸基と3つのビニル基を有するC3対称ベンゼン誘導体を基本構造とする異なる経路で得られた種々のADMET重縮合体による酸素選択透過性の改良 (2017)
  • Author(s): 武尾駿、園佳央理、森谷まどか、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第66回高分子学会年次大会
• [Presentation] ペンダントに種々の縮合性官能基を有する規則性ポリ置換フェニルアセチレンよりの種々の含環ポリマー膜の気体選択透過性 (2017)
  • Author(s): 森谷まどか、園佳央理、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第39年会
• [Presentation] 6 つの水酸基を有するC3 対称ベンゼン誘導体よりの超分子ポリマー含有高分子膜の酸素選択透過能 (2017)
  • Author(s): 大高絵里、武尾 駿、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第39年会
• [Presentation] 2Dポリマー(2DP)膜の透過(4):剛直なフェニルアセチレン共重合体膜のペンダント官能基の反応および主鎖の高選択光環化芳香族化分解による酸素選択透過性の向上 (2016)
  • Author(s): 森谷まどか、武尾駿、園佳央理、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 膜シンポジウム2016
  • Place of Presentation: 関西大学100周年記念会館(大阪府吹田市）
  • Year and Date: 2016-12-01
• [Presentation] アキラル条件によるらせん選択重合のキラリティーの制御と機構 (2016)
  • Author(s): 尹官武、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学横浜キャンパス(神奈川県横浜市）
• [Presentation] 自立型2Dポリマー(2DP)膜の合成(11):剛直なシス－シソイダルポリフェニルアセチレンを鋳型とした可溶性２D構造含有グラフトポリマーの合成、キャラクタリゼーションと利用 (2016)
  • Author(s): 園佳央理、森谷まどか、宮田真理、寺口昌宏、金子隆司、青木 俊樹
  • Organizer: 第65回高分子討論会
  • Place of Presentation: 神奈川大学横浜キャンパス(神奈川県横浜市)
• [Presentation] 自立型2Dポリマー(2DP)膜の合成(10)：ビニル基をペンダントに持つシスーシソイダルポリフェニルアセチレンの2DADMET重縮合体膜の高選択光環化芳香族化分解による2D剥離とシロキサングラフト化による可溶化 (2016)
  • Author(s): 佐藤栞、園佳央理、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・展示場(兵庫県神戸市)
• [Presentation] 自立型2Dポリマー(2DP)膜の合成(9)：種々の重合官能基をペンダントに持つシスーシソイダルポリフェニルアセチレンの合成と膜反応 (2016)
  • Author(s): 勝然勇也、武尾駿、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・展示場(兵庫県神戸市)
• [Presentation] 自立型2Dポリマー(2DP)膜の合成(11)：水素結合可能な官能基をペンダントに持つシスーシソイダルポリフェニルアセチレン膜の合成と膜反応 (2016)
  • Author(s): 山下恭平、森谷まどか、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・展示場(兵庫県神戸市)
• [Presentation] 自立型2Dポリマー(2DP)膜の合成(12)：1~3官能性芳香族モノマーの共重縮合による可溶性全共役含環二次元ポリマー(2DP)の合成 (2016)
  • Author(s): 計良祐紀、宮沢菜美、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・展示場(兵庫県神戸市)
• [Presentation] 3,5-ビス(ビスロキシメチル)フェニル基を末端に有するビスフェノキシル置換ポリ(アントリレンエチニレン)モデル化合物による超分子組織体形成と磁気的性質 (2016)
  • Author(s): 荒木陽介、佐藤駿広、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 第65回高分子学会年次大会
  • Place of Presentation: 神戸国際会議場・展示場(兵庫県神戸市)
• [Presentation] 共役平面主鎖をお有するポリフェニルアセチレン誘導体膜からの可溶性四重鎖および七重鎖グラフェンナノリボンの合成と気体透過性 (2016)
  • Author(s): 深井拓也、寺口昌宏、金子隆司、青木俊樹
  • Organizer: 日本膜学会第38年会
  • Place of Presentation: 早稲田大学（東京都新宿区）
• [Remarks] 新潟大学 機能性高分子合成研究室 -青木・金子・寺口研究室-
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/JpnTop.htm
• [Remarks] 新潟大学 機能性高分子合成研究室ー青木・金子・寺口研究室ー
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/JpnTop.htm
• [Remarks] 新潟大学 機能性高分子合成研究室-青木・金子・寺口研究室-
  • URL: http://www.gs.niigata-u.ac.jp/~kantak00/AokenHP/JpnTop.htm