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Construction of high performance photocatalysts by advanced band engineering

Research Project

Project/Area Number 16H04186
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Energy-related chemistry
Research InstitutionTohoku University

Principal Investigator

Kato Hideki  東北大学, 多元物質科学研究所, 准教授 (60385515)

Research Collaborator YAMAKATA Akira  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2018: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2016: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Keywords固溶体 / バンドポテンシャル / 人工光合成 / 光触媒 / 助触媒 / 酸素生成 / 水分解 / Zスキーム / 再生可能エネルギー / 水素 / 光電気化学反応 / 酸窒化物
Outline of Final Research Achievements

Many kinds of photocatalysts have been developed by the concept of band potential control based on formation of solid solutions and design of new compounds based on crystal chemistry. In perovskite-type oxynitrides, band potentials are significantly affected by constituent elements occupying A-site even though the O/N ratio and B-site constituents are the same. This clearly demonstrates the importance of advanced band control for construction of high performance photocatalysts. In addition, it was also revealed that activities of band-controlled photocatalysts strongly affected by the synthetic methods and conditions, and improvements of some photocatalysts have been achieved in this research.

Academic Significance and Societal Importance of the Research Achievements

窒素による価電子帯ポテンシャル制御は可視光応答性光触媒開発において重要な手法である。本研究において価電子帯ポテンシャルが窒素/酸素比のみでは決まらないことを明らかになった点は有用な知見であり,今後の光触媒設計に有効に活用される。本研究で開発した高活性化のための合成手法は,今回検討した光触媒のみならず,ほかの光触媒にも活用されると期待される。このように,本研究で得られた知見は光触媒による人工光合成の発展に寄与し,ひいては将来的な持続可能社会に貢献する可能性がある。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (20 results)

All 2019 2018 2017 2016

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results)

  • [Journal Article] Z-scheme water splitting by microspherical Rh-doped SrTiO3 photocatalysts prepared by a spray drying method2019

    • Author(s)
      Duong Hong Phong、Mashiyama Takahiro、Kobayashi Makoto、Iwase Akihide、Kudo Akihiko、Asakura Yusuke、Yin Shu、Kakihana Masato、Kato Hideki
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 252 Pages: 222-229

    • DOI

      10.1016/j.apcatb.2019.04.009

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Expansion of the photoresponse window of a BiVO4 photocatalyst by doping with chromium(vi)2018

    • Author(s)
      Okuno Kazuya、Kato Hideki、Vequizo Junie Jhon M.、Yamakata Akira、Kobayashi Hisayoshi、Kobayashi Makoto、Kakihana Masato
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 67 Pages: 38140-38145

    • DOI

      10.1039/c8ra07830k

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Rare Earth Niobate and Tantalate Powders via a Peroxo Complex Route2017

    • Author(s)
      H. Kato, K. Shimizu, K. Nakajima, M. Kobayashi, M. Kakihana
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 10 Pages: 1515-1517

    • DOI

      10.1246/cl.170652

    • NAID

      130006140011

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis and photocatalytic properties of tetragonal tungsten Bronze type oxynitrides2017

    • Author(s)
      K. Shimizu, H. Kato, M. Kobayashi, and M. Kakihana
    • Journal Title

      Appl. Catal. B

      Volume: 206 Pages: 444-448

    • DOI

      10.1016/j.apcatb.2017.01.057

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] LaTiO2N光触媒の水素生成活性向上に向けた検討2019

    • Author(s)
      加藤英樹, 淺田崇之, 小林亮, 垣花眞人
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] BiVO4光触媒へのボールミル処理効果2019

    • Author(s)
      奥野和哉, Junie M. Jhon VEQUIZO, 山方啓, 垣花眞人, 加藤英樹
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] LaNbON2-ATiO3固溶体光触媒の高活性化の検討2018

    • Author(s)
      青柳良輔, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] CrドープBiVO4光触媒の高活性化2018

    • Author(s)
      奥野和哉, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Improvements of Z-schematic water splitting by modification of SrTiO3:Rh with two kinds of cocatalyst2018

    • Author(s)
      H. P. Duong, H. Kato, M. Kobayashi, A. Iwase, A. Kudo, M. Kakihana
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Photocatalytic and photoelectrochemical water oxidation using oxynitrides2018

    • Author(s)
      H. Kato
    • Organizer
      International Congress on Pure and Applied Chemistry 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] クロムドープによるバナジン酸ビスマス光触媒の長波長応答化2018

    • Author(s)
      奥野和哉, 加藤英樹, 小林久芳, 小林亮, 垣花眞人
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] La0.5Sr0.5Ta0.5Ti0.5O2N光触媒の高活性化のための後処理の検討2018

    • Author(s)
      永井惇, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] バンドポテンシャル制御による新規ニオブ系酸窒化物光触媒の開発2018

    • Author(s)
      青柳良輔, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第121回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] La0.5Sr0.5Ta0.5Ti0.5O2N光触媒合成における前駆体調製法の検討2017

    • Author(s)
      永井惇, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 (神奈川県,横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Improvement of Water Oxidation Ability of Oxynitrides Aiming at Application to Photoanodes2017

    • Author(s)
      H. Kato
    • Organizer
      2017 MRS Spring Meeing
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Study on preparation methods for La0.5Sr0.5Ta0.5Ti0.5O2N photocatalyst2017

    • Author(s)
      S. Nagai, H Kato, M. Kobayashi, M. Kakihana
    • Organizer
      16th Korea-Japan Symposium on Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] La0.5Sr0.5Ta0.5Ti0.5O2Nの光アノード特性2017

    • Author(s)
      永井惇, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 太陽光水素製造を目指した光触媒のバンド制御2017

    • Author(s)
      加藤英樹
    • Organizer
      日本石油学会東北支部講演会
    • Place of Presentation
      秋田大学 (秋田県・秋田市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ペロブスカイト型タンタル系酸窒化物固溶体の光触媒特性2016

    • Author(s)
      永井惇, 加藤英樹, 小林亮, 垣花眞人
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学(岩手県・盛岡市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photocatalytic properties of perovskite-type oxynitride solid solutions2016

    • Author(s)
      Hideki Kato
    • Organizer
      International Symposium on Pure & Applied Chemistry 2016
    • Place of Presentation
      Kuching (Malaysia)
    • Year and Date
      2016-08-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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