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Fabrication of functional cerium oxide nanomaterials with dealloying process

Research Project

Project/Area Number 16H04209
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionShinshu University

Principal Investigator

Asao Naoki  信州大学, 学術研究院繊維学系, 教授 (60241519)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2018: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2017: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Keywords酸素吸蔵活性 / 酸化セリウム / CZ固溶体 / 脱合金酸化 / ナノ材料 / 環境材料 / 酸素吸蔵能 / 脱合金化 / 触媒・化学プロセス / 金属物性 / ナノ粒子
Outline of Final Research Achievements

Cerium oxide-based materials are used as the co-catalyst for purification of exhaust emissions from automobile combustion engines because of their oxygen storage capacity (OSC). However, the low OSC activity at low temperature is the problem to be solved. The author succeeded to fabricate nanostructured cerium oxide from Ce-Al binary alloy by use of his original dealloying-oxidation method. The obtained materials exhibit remarkable OSC activities, but their thermal stability is low. On the other hand, the ceria-zirconia solid solution prepared from Ce-Zr-Al ternary alloy improve the thermal stability as well as the low-temperature OSC activity.

Academic Significance and Societal Importance of the Research Achievements

近年、環境保護や省資源化の観点からハイブリッド自動車やアイドリングストップ技術の普及が進んでいる。そのため、エンジンが低温の時や回転数が低い時に排出される低温の排ガスをより効率的に浄化する必要性がある。今回報告者は、自身が開発した脱合金酸化法を用いて新たな酸化セリウム系材料の開発に成功し、低温域における活性向上に成功した。本結果は、自動車排ガス触媒の低温域における性能向上に資するものであり、世界的な環境保護に大きく寄与するものである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (10 results)

All 2019 2018 2017 2016

All Journal Article (1 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results)

  • [Journal Article] 脱合金酸化法を用いた酸化セリウムナノ材料の開発と酸素吸蔵活性評価2019

    • Author(s)
      桑原 聖、浅尾直樹
    • Journal Title

      ファインケミカル

      Volume: 48 Pages: 25-30

    • Related Report
      2018 Annual Research Report
  • [Presentation] 脱合金酸化法を用いたセリア-ジルコニア固溶体の作製2019

    • Author(s)
      桑原聖、佐野花織、梅津理恵、加藤秀実、羽田政明、浅尾直樹
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] セリア系酸化物の新規作製法の開発と耐熱性評価2019

    • Author(s)
      桑原聖、佐野花織、梅津理恵、加藤秀実、羽田政明、浅尾直樹
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 脱合金酸化法を用いたセリウムナノ材料の作製と機能性評価2018

    • Author(s)
      桑原 聖、浅尾直樹
    • Organizer
      日本金属学会北陸信越支部 日本鉄鋼協会北陸信越支部 平成30年度総会・連合講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 環境問題に役立つナノ材料2018

    • Author(s)
      浅尾直樹
    • Organizer
      AREC-Fiiプラザ 第201回リレー講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 脱合金化法を利用したナノ材料の作製と応用2018

    • Author(s)
      浅尾直樹
    • Organizer
      日本金属学会・日本鉄鋼協会 北陸信越支部 平成30年度第1回材料技術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Metal Oxide Nanomaterials with Dealloying-Oxidation Approach for Green Chemistry2017

    • Author(s)
      Naoki Asao
    • Organizer
      IUMRS-ICAM 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Metal Oxide Nanomaterials with Dealloying-Oxidation Method2017

    • Author(s)
      Naoki Asao
    • Organizer
      INTERNATIONAL SYMPOSIUM ON PURE & APPLIED CHEMISTRY
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Cerium oxide nanorods with unprecedented low-temperature oxygen storage capacity2016

    • Author(s)
      N. Asao
    • Organizer
      The 16th International Conference on Nanotechnology (IEEE Nano 2016)
    • Place of Presentation
      Sendai International Center, Sendai, Japan
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanostructured Porous Gold Materials as Efficient Catalysts for Molecular Transformations2016

    • Author(s)
      N. Asao
    • Organizer
      EMN Meeting on Mesoporous Materials
    • Place of Presentation
      Prague, Czech
    • Year and Date
      2016-06-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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