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Development of photorefractive ferroelectric liquid crystals for real time amplification of optical signals

Research Project

Project/Area Number 16H04224
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionTokyo University of Science

Principal Investigator

Sasaki Takeo  東京理科大学, 理学部第二部化学科, 教授 (80261501)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2018: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords強誘電性液晶 / フォトリフラクティブ効果 / 非線形光学材料 / ホログラム / 光増幅 / 光学材料 / 2光波結合 / 構造・機能材料 / 光導電性化合物 / スメクチック液晶 / 光物性 / 高分子合成 / 高分子構造・物性
Outline of Final Research Achievements

The purpose of this research subject is to bring the optical signal amplification system to practical level using liquid crystal photorefractive material. For that purpose, the design guidelines for ferroelectric liquid crystal materials showing excellent photorefractive properties (high diffraction efficiency, large gain constant, fast response) were explored. A large photorefractive effect was obtained with liquid crystals exhibiting a smectic C phase mixed with a very small amount of a chiral compound. This is quite different from the results expected so far and is interesting.

Academic Significance and Societal Importance of the Research Achievements

フォトリフラクティブ効果に及ぼす材料的な要因は多岐にわたる。平成30年度は平成29年度に引き続き液晶材料の組成に重点を置き、①各種強誘電性液晶のフォトリフラクティブ特性の違い、②光導電性化合物による違い、③光導電性キラルドーパントを含む強誘電性液晶混合物の開発の3項目について検討を行った。アルキル鎖の長さが異なる液晶性化合物を混合すると欠陥が少なく光散乱の小さなモノドメイン相を形成しやすいことが分かった。また、ごく少量のキラル化合物を混合したスメクチックC液晶が特異的な性能を示すことを明らかにした。これは光学材料開発の新しい指針の一つとなる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (33 results)

All 2019 2018 2017 2016

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (26 results) (of which Int'l Joint Research: 12 results,  Invited: 9 results) Book (2 results)

  • [Journal Article] Direct fabrication of a q-plate array by scanning wave photopolymerization2019

    • Author(s)
      Aizawa Miho、Ota Megumi、Hisano Kyohei、Akamatsu Norihisa、Sasaki Takeo、Barrett Christopher J.、Shishido Atsushi
    • Journal Title

      Journal of the Optical Society of America B

      Volume: 36 Issue: 5 Pages: D47-D47

    • DOI

      10.1364/josab.36.000d47

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Molecular Design for Preparation of Hexagonal-Ordered Porous Films Based on Side-Chain-Type Liquid-Crystalline Star Polymer2018

    • Author(s)
      Naka Yumiko、Takayama Hiromu、Koyama Teruhisa、Le Khoa Van、Sasaki Takeo
    • Journal Title

      Langmuir

      Volume: 34 Issue: 21 Pages: 6210-6216

    • DOI

      10.1021/acs.langmuir.8b01104

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral lyotropic chromonic liquid crystals composed of disodium cromoglycate doped with water-soluble chiral additives2018

    • Author(s)
      Shirai Tatsuya、Shuai Min、Nakamura Keita、Yamaguchi Akihiro、Naka Yumiko、Sasaki Takeo、Clark Noel A.、Le Khoa V.
    • Journal Title

      Soft Matter

      Volume: 14 Issue: 9 Pages: 1511-1516

    • DOI

      10.1039/c7sm02262j

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of Photosensitivity of Photorefractive Ferroelectric Liquid Crystal Blends to Green and Red Wavelength Regions Using Oligothiophene Photoconductive Dopants2017

    • Author(s)
      Sasaki Takeo、Morino Shouta、Sumiya Azusa、Yamamoto Yuta、Nakano Masaya、Le Khoa Van、Naka Yumiko、Sassa Takafumi
    • Journal Title

      J. Phys. Chem. C

      Volume: 121 Issue: 31 Pages: 16951-16958

    • DOI

      10.1021/acs.jpcc.7b05921

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Laser irradiation durability of photorefractive ferroelectric liquid crystal blends containing terthiophene photoconductive chiral dopants2016

    • Author(s)
      T. Sasaki, M. Yoshino, Y. Naka, K. V. Le and T. Sassa
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 74 Pages: 70573-70580

    • DOI

      10.1039/c6ra12231k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Photorefractive Effect in Ferroelectric Liquid Crystal Blends Containing Oligo-thiophene Photoconductive Dopant2018

    • Author(s)
      Takeo Sasaki
    • Organizer
      PHOTONICS2018 The International Conference on Fiber Optics and Photonics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photorefractive effect in smectic c liquid crystal blends containing small amount of chiral dopant2018

    • Author(s)
      Takeo Sasaki
    • Organizer
      SPIE Optics+Photonics 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フォトリフラクティブ強誘電性液晶用クォーターチオフェン系光導電性キラルドーパントの開発2018

    • Author(s)
      角坂美保、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2018年度日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フォトリフラクティブ強誘電性液晶セルの配向処理の検討2018

    • Author(s)
      寺園竜也、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2018年度日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 強誘電性液晶を用いたフォトリフラクティブ効果による画像光信号増幅2018

    • Author(s)
      舟田晃一、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2018年度日本液晶学会討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Photorefractive Effect in Ferroelectric Liquid Crystal Blends Containing Oligo-thiophene Photoconductive Dopant2017

    • Author(s)
      Takeo Sasaki
    • Organizer
      ICAOP-2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Light amplification by photorefractive ferroelectric liquid crystal blends measured at 532 nm and 638 nm2017

    • Author(s)
      Takeo Sasaki, Yumiko Naka and Khoa V. Le
    • Organizer
      Optics of Liquid Crystals2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photodetachable Adhesives Composed of Photodepolymerizable Poly(olefin sulfone)s2017

    • Author(s)
      Takeo Sasaki, Khoa V. Le
    • Organizer
      Biospectrum2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dynamic amplification of light signals in photorefractive ferroelectric liquid crystal blends containing photoconductive chiral dopant2017

    • Author(s)
      Takeo Sasaki
    • Organizer
      SPIE Optics+Photonics 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Light amplification by photorefractive ferroelectric liquid crystal blends containing quarter-thiophene photoconductive chiral dopant2017

    • Author(s)
      Takeo Sasaki, Takuya Hara, Yuuta Yamamoto, Yumiko Naka and Khoa Van Le
    • Organizer
      SPIE Optics+Optoelectrinics 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 星型高分子の分子構造がポーラス構造に及ぼす影響2017

    • Author(s)
      高山 明夢、中 裕美子、佐々木 健夫
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ATRP による櫛型ポリメタクリル酸メチルの合成及びポーラス構造形成2017

    • Author(s)
      佐藤 賢哉、中 裕美子、佐々木 健夫
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 局所修飾した星型高分子の合成とBreath-Figure法によるフィルム作製2017

    • Author(s)
      宮本 航、中 裕美子、佐々木 健夫
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分子フォトリフラクティブ材料の記録特性の検討2017

    • Author(s)
      戸田 智之、佐々木 健夫、レ バン・コア
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 拡張ビオロゲン含有高分子の光応答性2017

    • Author(s)
      中 裕美子、伊藤 雷、伊藤 正太、佐々木 健夫
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可塑剤を添加したポリオレフィンスルホンの二液混合型光剥離性解体性接着剤への応用2017

    • Author(s)
      小野 真太郎、佐々木 健夫、レ バン・コア
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 光導電性を有するキラルドーパントの開発2017

    • Author(s)
      祝実穂、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] クロモニック液晶を架橋剤としたヒドロゲルの作成および物性評価2017

    • Author(s)
      中村圭太、吉岡啓、白井達也、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ターチオフェン系高分子により安定化した強誘電性液晶によるフォトリフラクティブ効果2017

    • Author(s)
      中野仁哉、レバンコア、佐々木健夫
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 複数のキラル部位を有する光導電性キラルドーパントを用いたフォトリフラクティブ強誘電性液晶ブレンド2017

    • Author(s)
      須田達也、レバンコア、佐々木健夫
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 三環ビオロゲンの液晶性と光応答性評価2017

    • Author(s)
      伊藤雷、中裕美子、レバンコア、佐々木健夫
    • Organizer
      2017年日本液晶学会討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dynamic Light Amplification in Photorefractive Ferroelectric Liquid Crystal Blends Containing Photoconductive Chiral Dopant2016

    • Author(s)
      Takeo Sasaki
    • Organizer
      IEEE UEMCON2016
    • Place of Presentation
      New York, USA
    • Year and Date
      2016-10-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photorefractive Effect in Ferroelectric Liquid Crystal Blends Containing Quarter-thiophene Photoconductive Dopant2016

    • Author(s)
      Takeo Sasaki
    • Organizer
      IEEE IEMCON2016
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2016-10-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of the Photochemical Reactivity of the Photoconductive Chiral Dopant on the Durability of Photorefractive Ferroelectric Liquid Crystal Blends2016

    • Author(s)
      Takeo Sasaki
    • Organizer
      IEM OPTRONICS2016
    • Place of Presentation
      Kolkata, India
    • Year and Date
      2016-08-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dynamic Hologram Formation in Photorefractive Ferroelectric Liquid Crystal Blends2016

    • Author(s)
      Takeo Sasaki
    • Organizer
      Macro2016
    • Place of Presentation
      Istanbul, Turkey
    • Year and Date
      2016-07-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photorefractive effect in ferroelectric liquid crystal blends containing terthiophene photoconductive chiral dopants2016

    • Author(s)
      Takeo Sasaki, Khoa Van Le
    • Organizer
      Photonics Europe 2016
    • Place of Presentation
      Brussels, Belgium
    • Year and Date
      2016-04-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] Liquid Crystals - Self-Organized Soft Functional Materials for Advanced Applications2019

    • Author(s)
      Takeo Sasaki, Khoa Van Le, Yumiko Naka, Takafumi Sassa
    • Total Pages
      120
    • Publisher
      InTech
    • ISBN
      9781789848847
    • Related Report
      2018 Annual Research Report
  • [Book] Alkenes2018

    • Author(s)
      edited by Reza Davarnejad
    • Total Pages
      170
    • Publisher
      Intech
    • ISBN
      9789535137665
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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