Study on manganese based layer oxides for 4-volt sodium-ion batteries

• Project/Area Number: 16H04225
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Device related chemistry
• Research Institution: Tokyo University of Science
• Principal Investigator: KOMABA Shinichi 東京理科大学, 理学部第一部応用化学科, 教授 (20302052)
• Research Collaborator: KUBOTA Kei
• Project Period (FY): 2016-04-01 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000); Fiscal Year 2018: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2017: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000); Fiscal Year 2016: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
• Keywords: 蓄電池 / 酸化物 / レドックス / インターカレーション / ナトリウムイオン電池 / 層状酸化物 / 電気化学 / ナトリムイオン電池

Outline of Final Research Achievements

To realize high capacity and 4 volt operation of sodium-ion batteries, we investigated the correlation between crystal strutucres and chemical composition of layer sodium manganese oxides. We found that the partial doping with nickel, aluminium, are titanium are efficient to enhnace the battery performance.

Academic Significance and Societal Importance of the Research Achievements

高性能リチウムイオン電池は，レアメタルであるリチウムが必要で，リチウム資源は輸入に依存している．そこで非リチウムで，低コストマンガン酸化物に着目して，４ボルト作動を目指した材料開発を行った．得られた成果は，低コスト高性能蓄電池の実現に資するもので，次世代の環境・エネルギー技術としての意義だけでなく，マンガン酸化物の結晶構造と化学組成，電気化学特性の相関を解明する学術研究として意義がある．

Research Products

• [Int'l Joint Research] ソルボンヌ大学(フランス)
• [Int'l Joint Research] イエーナ大学/カールスルーエ工科大学(ドイツ)
• [Int'l Joint Research] ピエール・エ・マリー・キュリー大学(フランス)
• [Int'l Joint Research] CIC(スペイン)
• [Int'l Joint Research] ウルム大学/イエーナ大学(ドイツ)
• [Int'l Joint Research] 世宗大学(韓国)
• [Int'l Joint Research] マラケシ大学(モロッコ)
• [Journal Article] Optimizing Micrometer-Sized Sn Powder Composite Electrodes for Sodium-Ion Batteries (2019)
  • Author(s): FUKUNISHI Mika、HORIBA Tatsuo、DAHBI Mouad、KUBOTA Kei、YASUNO Satoshi、KOMABA Shinichi
  • Journal Title: Electrochemistry Volume: 87 Issue: 1 Pages: 70-77
  • DOI: 10.5796/electrochemistry.18-00069
  • NAID: 130007542953
  • ISSN: 1344-3542, 2186-2451
  • Year and Date: 2019-01-05
  • Peer Reviewed / Open Access
• [Journal Article] States of thermochemically or electrochemically synthesized NaxPy compounds analyzed by solid state 23Na and 31P nuclear magnetic resonance with theoretical calculation (2019)
  • Author(s): Ryohei Morita, Kazuma Gotoh, Mouad Dahbi, Kei Kubota, Shinichi, Komaba, Kazuyasu Tokiwa, Saeid Arabnejad, Koichi Yamashita, Kenzo Deguchi, Shinobu Ohki, Tadashi Shimizu, Robert Laskowski, Hiroyuki Ishida
  • Journal Title: J. Power Sources Volume: 413 Pages: 418-424
  • DOI: 10.1016/j.jpowsour.2018.12.070
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Correlation of carbonization condition with metallic property of sodium clusters formed in hard carbon studied using 23Na nuclear magnetic resonance (2019)
  • Author(s): Ryohei Morita, Kazuma Gotoh, Kei Kubota, Shinichi Komaba, Kenjiro Hashi, Tadashi Shimizu, Hiroyuki Ishida
  • Journal Title: Carbon Volume: 145 Pages: 712-715
  • DOI: 10.1016/j.carbon.2019.01.080
  • Peer Reviewed / Open Access
• [Journal Article] Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry (2019)
  • Author(s): Dou Xinwei、Hasa Ivana、Saurel Damien、Vaalma Christoph、Wu Liming、Buchholz Daniel、Bresser Dominic、Komaba Shinichi、Passerini Stefano
  • Journal Title: Materials Today Volume: 23 Pages: 87-104
  • DOI: 10.1016/j.mattod.2018.12.040
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Electrochemistry and Solid-State Chemistry of NaMeO2 (Me = 3d Transition Metals) (2018)
  • Author(s): Kei Kubota, Shinichi Kumakura, Yusuke Yoda, Kazutoshi Kuroki, and Shinichi Komaba
  • Journal Title: Advanced Energy Materials Volume: 印刷中 Issue: 17 Pages: 1703415-1703415
  • DOI: 10.1002/aenm.201703415
  • Peer Reviewed / Open Access
• [Journal Article] Hard carbons issued from date palm as efficient anode materials for sodium-ion batteries (2018)
  • Author(s): Izanzar Ilyasse、Dahbi Mouad、Kiso Manami、Doubaji Siham、Komaba Shinichi、Saadoune Ismael
  • Journal Title: Carbon Volume: 137 Pages: 165-173
  • DOI: 10.1016/j.carbon.2018.05.032
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Insights into Li+, Na+, and K+ Intercalation in Lepidocrocite-Type Layered TiO2 Structures (2018)
  • Author(s): Reeves Kyle G.、Ma Jiwei、Fukunishi Mika、Salanne Mathieu、Komaba Shinichi、Dambournet Damien
  • Journal Title: ACS Applied Energy Materials Volume: 1 Issue: 5 Pages: 2078-2086
  • DOI: 10.1021/acsaem.8b00170
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Synthesis and Electrochemical Performance of C-Base-Centered Lepidocrocite-like Titanates for Na-Ion Batteries (2018)
  • Author(s): Katogi Akihiro、Kubota Kei、Chihara Kuniko、Miyamoto Koji、Hasegawa Tatsuya、Komaba Shinichi
  • Journal Title: ACS Applied Energy Materials Volume: 1 Issue: 8 Pages: 3630-3635
  • DOI: 10.1021/acsaem.8b00345
  • Peer Reviewed / Open Access
• [Journal Article] Synthesizing higher-capacity hard-carbons from cellulose for Na- and K-ion batteries (2018)
  • Author(s): Yamamoto Hijiri、Muratsubaki Shotaro、Kubota Kei、Fukunishi Mika、Watanabe Hiromu、Kim Jungmin、Komaba Shinichi
  • Journal Title: Journal of Materials Chemistry A Volume: 6 Issue: 35 Pages: 16844-16848
  • DOI: 10.1039/c8ta05203d
  • Peer Reviewed / Open Access
• [Journal Article] Poly-γ-glutamate Binder To Enhance Electrode Performances of P2-Na2/3Ni1/3Mn2/3O2 for Na-Ion Batteries (2018)
  • Author(s): Yoda Yusuke、Kubota Kei、Isozumi Hayata、Horiba Tatsuo、Komaba Shinichi
  • Journal Title: ACS Applied Materials & Interfaces Volume: 10 Issue: 13 Pages: 10986-10997
  • DOI: 10.1021/acsami.8b01362
  • Peer Reviewed
• [Journal Article] Towards K-Ion and Na-Ion Batteries as “Beyond Li-Ion” (2018)
  • Author(s): Kubota Kei、Dahbi Mouad、Hosaka Tomooki、Kumakura Shinichi、Komaba Shinichi
  • Journal Title: The Chemical Record Volume: 18 Issue: 4 Pages: 459-479
  • DOI: 10.1002/tcr.201700057
  • Peer Reviewed
• [Journal Article] Unraveling the Role of Doping in Selective Stabilization of NaMnO2 Polymorphs: Combined Theoretical and Experimental Study (2018)
  • Author(s): Shishkin Maxim、Kumakura Shinichi、Sato Syuhei、Kubota Kei、Komaba Shinichi、Sato Hirofumi
  • Journal Title: Chemistry of Materials Volume: 30 Issue: 4 Pages: 1257-1264
  • DOI: 10.1021/acs.chemmater.7b04394
  • Peer Reviewed
• [Journal Article] Electrochemistry and Solid-State Chemistry of NaMeO2 (Me = 3d Transition Metals) (2018)
  • Author(s): Kei Kubota, Shinichi Kumakura, Yusuke Yoda, Kazutoshi Kuroki, and Shinichi Komaba
  • Journal Title: Advanced Energy Materials Volume: in press
• [Journal Article] P′2-Na2/3Mn0.9Me0.1O2 (Me = Mg, Ti, Co, Ni, Cu, and Zn): Correlation between Orthorhombic Distortion and Electrochemical Property (2017)
  • Author(s): Kumakura Shinichi、Tahara Yoshiyuki、Sato Syuhei、Kubota Kei、Komaba Shinichi
  • Journal Title: Chemistry of Materials Volume: 29 Issue: 21 Pages: 8958-8962
  • DOI: 10.1021/acs.chemmater.7b02772
  • Peer Reviewed
• [Journal Article] Origin of Enhanced Capacity Retention of P2-Type Na2/3Ni1/3-xMn2/3CuxO2 for Na-Ion Batteries (2017)
  • Author(s): Kubota Kei、Yoda Yusuke、Komaba Shinichi
  • Journal Title: J Electrochem. Soc. Volume: 164 Issue: 12 Pages: A2368-A2373
  • DOI: 10.1149/2.0311712jes
  • Peer Reviewed
• [Journal Article] High performance red phosphorus electrode in ionic liquid-based electrolyte for Na-ion batteries (2017)
  • Author(s): Dahbi Mouad、Fukunishi Mika、Horiba Tatsuo、Yabuuchi Naoaki、Yasuno Satoshi、Komaba Shinichi
  • Journal Title: J. Power Sources Volume: 363 Pages: 404-412
  • DOI: 10.1016/j.jpowsour.2017.07.089
  • Peer Reviewed
• [Journal Article] Sodium and Manganese Stoichiometry of P2-Type Na2/3MnO (2016)
  • Author(s): Shinichi Kumakura, Yoshiyuki Tahara, Kei Kubota, Kuniko Chihara, and Shinichi Komaba
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 41 Pages: 12760-12763
  • DOI: 10.1002/ange.201606415
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Polymer Binder: A Key Component in Negative Electrodes for High-Energy Na-ion Batteries (2016)
  • Author(s): Wanjie Zhang, Mouad Dahbi, and Shinichi Komaba
  • Journal Title: Current Opinion in Chem. Engineering Volume: 13 Pages: 36-44
  • DOI: 10.1016/j.coche.2016.08.001
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Effect of Hexafluorophosphate and Fluoroethylene Carbonate on Electrochemical Performance and Surface Layer of Hard Carbon for Sodium-Ion Batteries (2016)
  • Author(s): Mouad Dahbi, Takeshi Nakano, Naoaki Yabuuchi, Shun Fujimura, Kuniko Chihara, Kei Kubota, Jin-Young Son, Yi-Tao Cui, Hiroshi Oji, and Shinichi Komaba
  • Journal Title: ChemElectroChem Volume: 3 Issue: 11 Pages: 1856-1867
  • DOI: 10.1002/celc.201600365
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Thermal Stability of NaxCrO2 for Rechargeable Sodium Batteries; Studies by High-Temperature Synchrotron X-Ray Diffraction (2016)
  • Author(s): Naoaki Yabuuchi, Issei Ikeuchi, Kei Kubota, and Shinichi Komaba
  • Journal Title: ACS Appl. Mater. Interfaces. Volume: 8 Issue: 47 Pages: 32292-9
  • DOI: 10.1021/acsami.6b09280
  • Peer Reviewed
• [Presentation] NaMeO2 for Na-ion batteries (2018)
  • Author(s): Shinichi Komaba
  • Organizer: ICNaB 2018; 5th International Conference on Sodium Batteries
  • Int'l Joint Research / Invited
• [Presentation] Towards Na-ion and K-ion batteries besides Li-ion (2018)
  • Author(s): Shinichi Komaba
  • Organizer: XV International Conference on “Topical problems of energy conversion in lithium electrochemical systems”
  • Int'l Joint Research / Invited
• [Presentation] Carbon electrodes for Li-, Na-, and K-ion batteries (2018)
  • Author(s): Shinichi Komaba, Kei Kubota, Shotaro Muratsubaki, Hiroo Onuma
  • Organizer: CMCEE 2018 (12th International Conference on Ceramic Materials and Components for Energy and Environmental Applications)
  • Int'l Joint Research / Invited
• [Presentation] Hard carbons made from cellulosefor Na- and K-ion batteries (2017)
  • Author(s): Shinichi Komaba, Hijiri Yamamoto, Kei Kubota, Shotaro Muratsubaki,Mouad Dahbi, and Ayyakkannu Manivannan
  • Organizer: 231st ECS meeting, New Orleans
  • Int'l Joint Research / Invited
• [Presentation] 汎用アルカリ金属の炭素電極への電気化学的挿入 (2017)
  • Author(s): 駒場 慎一，久保田 圭，ダビ ムアッド，村椿 将太郎，小沼 宏生
  • Organizer: 第386回電池技術委員会
  • Invited
• [Presentation] Layered Na-Mn oxides for high-capacity rechargeable battery (2017)
  • Author(s): Shinichi Komaba, Shinichi Kumakura, and Kei Kubota
  • Organizer: RSC 13th International Conference on Materials Chemistry (MC13),Liverpool, UK
  • Int'l Joint Research / Invited
• [Presentation] Layered oxides for Na- and K-ion batteries (Lead Plenary Lecture) (2016)
  • Author(s): Shinichi Komaba
  • Organizer: 3rd International Conference on Sodium Batteries
  • Place of Presentation: Geelong, Australia
  • Int'l Joint Research / Invited
• [Book] 理工系の基礎「教養化学」 (2016)
  • Author(s): 駒場慎一 他25名
  • Total Pages: 254
  • Publisher: 丸善出版
• [Remarks] 東京理科大学 駒場研究室
  • URL: https://www.rs.kagu.tus.ac.jp/komaba/
• [Remarks] 東京理科大学 駒場研究室
  • URL: http://www.rs.kagu.tus.ac.jp/komaba/
• [Remarks] 第4回 ナトリウム電池国際会議
  • URL: http://www.rs.tus.ac.jp/inab2017/
• [Funded Workshop] The 4th International Conference on Sodium Batteries (2017)