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Development of novel functions generated by photo-self-reduction of iron oxyhydroxide, and elucidation of the mechanism

Research Project

Project/Area Number 16H04498
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo University of Science

Principal Investigator

Katsumata Ken-ichi  東京理科大学, 基礎工学部材料工学科, 准教授 (70550242)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2018: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2017: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2016: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Keywordsオキシ水酸化鉄 / 光触媒 / 光フェントン反応 / 光自己還元 / 水素生成 / 酸素消費 / 機能性セラミックス材料 / 有機廃液処理 / フォトン・フェントン反応 / 水素 / 酸素 / アルコール / オキシ水酸化物
Outline of Final Research Achievements

The synthesized iron oxyhydroxide has showed a high hydrogen generating ability as compared with the commercially available reagent. When the pH of the aqueous solution was low, it showed high hydrogen-producing activity. In addition, it was found that the amount of oxygen decreased with the generation of hydrogen, and there was a tendency for the hydrogen generation capacity to decrease under anoxic conditions. It was considered that iron oxyhydroxide produced a low valence iron ion by photo-self-reduction, which contributed to hydrogen production. Examination of other oxyhydroxides revealed that hydrogen is also produced in nickel oxyhydroxide and aluminum oxyhydroxide.

Academic Significance and Societal Importance of the Research Achievements

本研究は、伝導帯位置がプロトンの還元電位よりも低いため、水素生成が不可能であると考えられてきたオキシ水酸化鉄に対して、光エネルギーにより最表面を自己還元させ水素の生成を目指すという新しい光機能の開拓とその機構解明といった点が学術的に特色のある研究である。特にオキシ水酸化鉄はクラーク数の高いユビキタス元素で構成されているだけではなく身の回りにありふれた鉄錆であり、元素戦略という点からも学術的に大変意義がある。また、本実験系の特徴は無酸素条件下では起こらない反応であり、その利点は水素生成濃度が爆発限界(4%)を超えたとしても無酸素条件のため安全に扱えることができる。

Report

(4 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (19 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 7 results,  Invited: 4 results) Remarks (6 results)

  • [Int'l Joint Research] Gachon University(韓国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] University College London(英国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Hydrogen Production System by Light-Induced a-FeOOH Coupled with Photoreduction2020

    • Author(s)
      Tetsuya Yamada, Norihiro Suzuki, Kazuya Nakata, Chiaki Terashima, Nobuhiro Matsushita, Kiyoshi Okada, Akira Fujishima, Ken-ichi Katsumata
    • Journal Title

      Chemistry - A European Journal

      Volume: 26 Issue: 11 Pages: 2380-2385

    • DOI

      10.1002/chem.201903642

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Synthesis of β-FeOOH and its Photo-Functional Property2019

    • Author(s)
      Y. Yoon, K. Katsumata, K. Kim, J. Hong
    • Organizer
      The 3rd International Symposium on Recent Progress of Energy and Environmental Photocatalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of δ-FeOOH by Solution Process for Hydrogen Production2019

    • Author(s)
      M. Lee, K. Katsumata, K. Kim, J. Hong
    • Organizer
      The 3rd International Symposium on Recent Progress of Energy and Environmental Photocatalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photo-functional Properties of Iron Oxyhydroxide2019

    • Author(s)
      J. Hong, K. Kim, K. Katsumata
    • Organizer
      The 5th International Conference on Advanced Electromaterials (ICAE 2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 特異ナノ構造の合成と光触媒への応用展開2018

    • Author(s)
      勝又健一
    • Organizer
      第12回新機能無機物質探索研究センターシンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 溶液プロセスで合成した鉄錆の光機能性評価2018

    • Author(s)
      洪正洙、白井孝、勝又健一
    • Organizer
      第56回セラミックス基礎科学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hydrogen production of FeOOH with photo-self-reduction2017

    • Author(s)
      Ken-ichi Katsumata
    • Organizer
      IUMRS International Conference in Asia 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of FeOOH by Solution Process and Their Photo-functional Property2017

    • Author(s)
      Ken-ichi Katsumata
    • Organizer
      International Union of Materials Research Society-International Conference of Advanced Materials (IUMRS-ICAM) 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 光触媒を利用した環境・エネルギー材料の開発2017

    • Author(s)
      勝又健一
    • Organizer
      第7回エネルギー変換の材料科学研究会
    • Place of Presentation
      日本大学 駿河台キャンパス(東京都)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Photo-Functional Properties of Iron Oxyhydroxides (α, β, γ, δ-FeOOH)2016

    • Author(s)
      J. Hong, K. Katsumata, K. Nakata, C. Terashima, A. Fujishima
    • Organizer
      2016 MRS Fall Meeting & Exhibit
    • Place of Presentation
      Boston, Massachusetts, USA
    • Year and Date
      2016-11-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of α-FeOOH with Needle Structure2016

    • Author(s)
      J. Hong, K. Katsumata, K. Nakata, C. Terashima, A. Fujishima
    • Organizer
      The 22nd China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME'22)
    • Place of Presentation
      Element Suzhou Science and Technology Town, Suzhou, China
    • Year and Date
      2016-09-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 東京理科大学 光触媒国際研究センター

    • URL

      https://www.rs.tus.ac.jp/pirc/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東京理科大学 光触媒研究推進拠点

    • URL

      https://www.pirc.tus.ac.jp/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東京理科大学 スペース・コロニー研究センター

    • URL

      https://www.tus.ac.jp/rcsc/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東京理科大学×SDGs

    • URL

      https://www.tus.ac.jp/sdgs/370

    • Related Report
      2018 Annual Research Report
  • [Remarks] 東京理科大学 光触媒国際研究センター

    • URL

      http://www.rs.tus.ac.jp/pirc/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京理科大学 光触媒研究推進拠点

    • URL

      http://www.pirc.tus.ac.jp/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2022-06-10  

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