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Development of Hybrid Process for Simultaneous Recovery of Lithium and Boron from Geothermal Water

Research Project

Project/Area Number 16H04555
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionThe University of Kitakyushu

Principal Investigator

Yoshizuka Kazuharu  北九州市立大学, 国際環境工学部, 教授 (70191567)

Co-Investigator(Kenkyū-buntansha) 西浜 章平  北九州市立大学, 国際環境工学部, 教授 (00347668)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2018: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2016: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywords吸着 / 電気透析 / 地熱水 / リチウム / ホウ素 / ハイブリッドシステム / 分離回収 / ハイブリッドプロセス / 化学工学 / 反応・分離工学 / 資源開発工学
Outline of Final Research Achievements

Hybrid process for selective recovery of lithium and boron from geothermal water together with direct production of lithium hydroxide and boric acid was developed by combining the chromatographic recovery of lithium and boron using the adsorbents and the bipolar electrodialysis process. The study was conducted (1) Recovery of lithium tetraborate from geothermal water using lithium adsorbent and boron adsorbent, (2) Separation and recovery of lithium tetraborate from geothermal water using an adsorption column connected with a lithium adsorption column and a boron adsorption column, and (3) simultaneous and direct production of lithium hydroxide and boric acid using a bipolar electrodialysis method from lithium tetraborate recovered from geothermal water.

Academic Significance and Societal Importance of the Research Achievements

本研究の学術的意義は、地熱水から高付加価値なレアメタル資源を同時採取可能な分離回収プロセスを開発するとともに、我が国オリジナルの技術であるバイポーラ電気透析法を用いた生成物への直接変換と濃縮プロセスを組み合わせたハイブリッドプロセスを開発したことである。また、社会的意義は、未利用資源である地熱水から国産のレアメタルを回収することによって我が国の資源確保問題の解決に貢献できることである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2018 2017 2016 Other

All Int'l Joint Research (3 results) Journal Article (9 results) (of which Int'l Joint Research: 8 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (13 results) (of which Int'l Joint Research: 10 results,  Invited: 4 results) Book (1 results) Remarks (3 results)

  • [Int'l Joint Research] エーゲ大学(トルコ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] エーゲ大学(トルコ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] エーゲ大学(トルコ)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Lithium Recovery from Various Resources Using Ion Exchange2018

    • Author(s)
      吉塚和治
    • Journal Title

      Journal of Ion Exchange

      Volume: 29 Issue: 2 Pages: 17-24

    • DOI

      10.5182/jaie.29.17

    • NAID

      130006733903

    • ISSN
      0915-860X, 1884-3360
    • Year and Date
      2018-05-09
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Acid-Base Solutions Used in Acid-Base Compartments for Simultaneous Recovery of Lithium and Boron from Aqueous Solution Using Bipolar Membrane Electrodialysis (BMED).2018

    • Author(s)
      Ipekci, D.; Altiok, E.; Bunani, S.; Yoshizuka, K.; Nishihama, S.; Arda, M.; Kabay, N.
    • Journal Title

      Desalination

      Volume: 448 Pages: 69-75

    • DOI

      10.1016/j.desal.2018.10.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Packed Bed Column Dynamic Study for Boron Removal from Geothermal Brine by a Chelating Fiber and Breakthrough Curve Analysis by Using Mathematical Models2018

    • Author(s)
      Recepoglu, Y.K.; Kabay, N.; Yilmaz-Ipek, I.; Arda, M.; Yuksel, M.; Yoshizuka, K.; Nishihama, S.
    • Journal Title

      Desalination

      Volume: 437 Pages: 1-6

    • DOI

      10.1016/j.desal.2018.02.022

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Operational Conditions on Separation of Lithium from Geothermal Water by λ-MnO2 Using Ion Exchange Membrane Filtration Hybrid Process2018

    • Author(s)
      Recepoglu, Y.K.; Kabay, N.; Yoshizuka, K.; Nishihama, S.; Yilmaz-Ipek, I.; Arda, M.; Yuksel, M.
    • Journal Title

      Solvent Extra. Ion Exch.

      Volume: 36(5) Issue: 5 Pages: 499-512

    • DOI

      10.1080/07366299.2018.1529232

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Elimination of Boron and Lithium Coexisting in Geothermal Water by Adsorption-Membrane Filtration Hybrid Process.2018

    • Author(s)
      Recepoglu, Y.K.; Kabay, N.; Yilmaz-Ipek, I.; Arda, M.; Yuksel, M.; Yoshizuka, K.; Nishihama, S.
    • Journal Title

      Sep. Sci. Technol.

      Volume: 53(6) Issue: 6 Pages: 856-862

    • DOI

      10.1080/01496395.2017.1405985

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Application of Bipolar Membrane Electrodialysis (BMED) for Simultaneous Separation and Recovery of Boron and Lithium from Aqueous Solutions2017

    • Author(s)
      Bunani, S., Yoshizuka, K., Nishihama, S., Arda, M., Kabay, N.
    • Journal Title

      Desalination

      Volume: 424 Pages: 34-44

    • DOI

      10.1016/j.desal.2017.09.029

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Equilibrium and Kinetic Studies on Lithium Adsorption from Geothermal Water by λ-MnO22017

    • Author(s)
      Recepoglu, Y. K., Kabay, N., Yilmaz-Ipek, I., Arda, M., Yoshizuka, K., Nishihama, S., Yuksel, M.
    • Journal Title

      Solvent Extr. Ion Exch.

      Volume: 35 Issue: 3 Pages: 221-231

    • DOI

      10.1080/07366299.2017.1319235

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Deboronation of Geothermal Water Using N-methyl-D-glucamine Based Chelating Resins and a Novel Fiber Adsorbent: Batch and Column Studies2017

    • Author(s)
      Recepoglu, Y. K., Kabay, N., Yilmaz-Ipek, I., Arda, M., Yoshizuka, K., Nishihama, S., Yuksel, M.
    • Journal Title

      J. Chem. Technol. Biotechnol.

      Volume: 92 Issue: 7 Pages: 1540-1547

    • DOI

      10.1002/jctb.5234

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Process Conditions on Recovery of Lithium and Boron from Water using Bipolar Membrane Electrodialysis (BMED)2017

    • Author(s)
      Bunani, S.; Arda, M.; Kabay, N.; Yoshizuka, K.; Nishihama, S.
    • Journal Title

      Desalination

      Volume: 416 Pages: 10-15

    • DOI

      10.1016/j.desal.2017.04.017

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Lithium Recovery from Brine of Salar de Uyuni, Bolivia2018

    • Author(s)
      Yoshizuka, K.
    • Organizer
      Heidelberg Alumni International Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Lithium Recovery from Untapped Resources2018

    • Author(s)
      Yoshizuka, K.; Nishihama, S.
    • Organizer
      Second Interdisciplinary and Research Alumni Symposium (iJaDe2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Lithium Recovery from Various Resources Using Integrated Ion Exchange Technology2018

    • Author(s)
      Yoshizuka, K.
    • Organizer
      Boren Seminar (Seminerlerimiz Devam Ediyor)
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] イオン交換法を駆使した様々な資源からのリチウム回収に関する研究2017

    • Author(s)
      吉塚和治
    • Organizer
      第33回日本イオン交換研究発表会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Separation of Lithium from Salt Lake Brine by Solvent Extraction with Mixture of Tributyl Phosphate and Ionic Liquid2017

    • Author(s)
      関本拓真,西浜章平,吉塚和治
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Removal of Boron from Geothermal Water with Ion Exchange Technique2017

    • Author(s)
      塩田也人,西浜章平,吉塚和治,Muserref Arda,Nalan Kabay
    • Organizer
      The 21st International Solvent Extraction Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Separation of Boron from Water Environment with Glucamine-Based Chelate Adsorbents2017

    • Author(s)
      西浜章平,塩田也人,住吉勇樹,吉塚和治
    • Organizer
      2017 Korea/Japan/Taiwan Chemical Engineering Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorptive Removal of Boron from Geothermal Water Using Glucamine-Based Chelate Adsorbent2017

    • Author(s)
      塩田也人,西浜章平,吉塚和治,Muserref Arda,Nalan Kabay
    • Organizer
      2017 Korea/Japan/Taiwan Chemical Engineering Conference
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorptive Recovery of Lithium from Geothermal Water2017

    • Author(s)
      臼井ありさ,西浜章平,吉塚和治
    • Organizer
      The 30th International Symposium on Chemical Engineering (ISChE 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Separation and Removal of Boron from Geothermal Water of Balcova (Turkey) Using Glucamine-Based Chelate Adsorbents2016

    • Author(s)
      塩田也人、西浜章平、吉塚和治、Muserref ARDA、Nalan KABAY
    • Organizer
      The 29th International Symposium on Chemical Engineering
    • Place of Presentation
      フェニックス・シーガイア・リゾート コンベンションセンター (宮崎県宮崎市)
    • Year and Date
      2016-12-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] メチルグルカミン型キレート吸着剤を用いた地熱水からのホウ素の除去2016

    • Author(s)
      塩田也人、西浜章平、吉塚和治、Muserref Arda、Nalan Kabay
    • Organizer
      第32回日本イオン交換研究発表会
    • Place of Presentation
      関西大学千里山キャンパス (大阪府吹田市)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] Separation of Boron and Lithium from Aqueous Solution with Bipolar Membrane Electrodialysis (BPED)2016

    • Author(s)
      Samuel Bunani、吉塚和治、西浜章平、Muserref Arda、Nalan Kabay
    • Organizer
      IEX 2016: The International Ion Exchange Conference
    • Place of Presentation
      Robinson College, University of Cambridge, ケンブリッジ, イギリス
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Comparative Study for Selective Separation of Boron from Geothermal Water by a Novel Chelating Fiber Adsorbent and Boron Selective Ion Exchange Resins2016

    • Author(s)
      Yasar Kemal Recepoglu、Nalan Kabay、Idil Tilmaz Ipek、Muserref Arda、Mithat Yukusel、吉塚和治、西浜章平
    • Organizer
      IEX 2016: The International Ion Exchange Conference
    • Place of Presentation
      Robinson College, University of Cambridge, ケンブリッジ, イギリス
    • Year and Date
      2016-07-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] GeothermalWater Management2018

    • Author(s)
      Nalan Kabay, Idil Y. Ipek, Pelin K. Yilmaz, Saba Samatya, Marek Bryjak, Kazuharu Yoshizuka, S. Ali Tuncel, Umran Yuksel, Mithat Yuksel
    • Total Pages
      462
    • Publisher
      CRC Press
    • ISBN
      9781315734972
    • Related Report
      2017 Annual Research Report
  • [Remarks] 北九州市立大学国際環境工学部分離工学研究室

    • URL

      http://chemeng.env.kitakyu-u.ac.jp/jp/index_j.html

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 北九州市立大学国際環境工学部エネルギー循環化学科 吉塚和治

    • URL

      https://www-st.kitakyu-u.ac.jp/env/subject/d-energy/Kazuharu_Yoshizuka/index.html

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 北九州学術研究都市研究者情報 吉塚和治

    • URL

      http://fais.ksrp.or.jp/05kenkyusha/srchresult.asp?ID=k-yoshizuka01

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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