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Development of oxidation catalyst using precious group metal species as promoter

Research Project

Project/Area Number 16H04567
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKyoto University

Principal Investigator

Tanaka Tsunehiro  京都大学, 工学研究科, 教授 (70201621)

Research Collaborator Hosokawa Saburo  
Teramura Kentaro  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2018: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2017: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords燃焼触媒 / 自動車触媒 / 貴金属触媒 / 遷移金属触媒 / 酸素貯蔵材料 / 環境触媒 / 遷移金属酸化物触媒 / 担持貴金属触媒 / 遷移金属(複合)酸化物触媒 / 貴金属 / 触媒燃焼反応 / 酸化反応
Outline of Final Research Achievements

Catalytic combustion method is effective for the removal of volatile organic compounds (VOCs) emitted from automobile or various industrial processes, and the development of novel catalyst material having a high activity at low temperature range is highly desired. This research demonstrates that the catalytic function of transition metal-based mixed oxide is dramatically amplified by adding a trace amount of precious group metal (PGM) species. For CO and C3H6 combustion, catalytic activity of Mn-based catalyst are enhanced by PGM loading. A small amount of PGM species adequately promotes the adsorption of CO or C3H6, resulting in the improvement of catalytic activity of Mn-based catalyst. These results suggest that the development of transition metal-based catalyst having high catalytic activity leads to reduce PGM usage.

Academic Significance and Societal Importance of the Research Achievements

本研究課題では,少量の貴金属元素が遷移金属元素の触媒能を促進するという新規な発想に基づき,貴金属元素をプロモーターとした超高活性燃焼用触媒の開発を目指した.従来まで,貴金属系の触媒の活性点は貴金属サイトであるという固定概念があったが,本研究では遷移金属が活性サイトであり,その機能をアシストするために貴金属を導入するという視点で触媒設計を行った.その結果,触媒活性が非常に高い材料を設計することに成功した.このような触媒設計指針は触媒活性の向上を生むだけでなく,貴金属元素の使用量の低減化も見込めるため,経済的・社会的観点からも意義深い成果であると考えている.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (39 results)

All 2019 2018 2017 2016

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (30 results) (of which Int'l Joint Research: 6 results,  Invited: 4 results)

  • [Journal Article] CO and C3H6 oxidation over platinum-group metal (PGM) catalysts supported on Mn-modified hexagonal YbFeO32019

    • Author(s)
      Saburo Hosokawa, Shogo Matsumoto, Kenya Onishi, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Journal Title

      Catal. Today

      Volume: 印刷中 Pages: 183-188

    • DOI

      10.1016/j.cattod.2018.07.026

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient oxygen storage property of Sr-Fe mixed oxide as automotive catalyst support2019

    • Author(s)
      Kosuke Beppu, Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Journal Title

      J. Mater. Chem. A

      Volume: 7 Issue: 3 Pages: 1013-1021

    • DOI

      10.1039/c8ta08378a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pd/SrFe1-xTixO3-δ as Environmental Catalyst: Purification of Automotive Exhaust Gases2018

    • Author(s)
      Kosuke Beppu, Akito Demizu, Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 10 Issue: 26 Pages: 22182-22189

    • DOI

      10.1021/acsami.8b05169

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Striking Oxygen-Release/Storage Properties of Fe-Site-Substituted Sr3Fe2O7-δ2018

    • Author(s)
      Kosuke Beppu, Saburo Hosokawa, Akito Demizu, Yudai Oshino, Kazuki Tamai, Kazuo Kato, Kenji Wada, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Journal Title

      J. Phys. Chem. C

      Volume: 122 Issue: 21 Pages: 11186-11193

    • DOI

      10.1021/acs.jpcc.7b12754

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Role of lattice oxygen and oxygen vacancy sites in platinum group metal catalysts supported on Sr3Fe2O7-δ for NO-selective reduction2018

    • Author(s)
      Kosuke Beppu, Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura and Tsunehiro Tanaka
    • Journal Title

      Catal. Sci. Technol.

      Volume: 8 Issue: 1 Pages: 147-153

    • DOI

      10.1039/c7cy01861d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Oxygen Release-Storage Property of Pd-Loaded Sr3Fe2O7-d2017

    • Author(s)
      Kosuke Beppu, Saburo Hosokawa, Takuya Shibano, Akito Demizu, Kazuo Kato, Kenji Wada, Hiroyuki Asakura, Kentaro Teramura and Tsunehiro Tanaka
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 21 Pages: 14107-14113

    • DOI

      10.1039/c7cp01614j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Reduction of NO over Cu/Al2O3: Enhanced Catalytic Activity by Infinitesimal Loading of Rh on Cu/Al2O32017

    • Author(s)
      Saburo Hosokawa, Kazuya Matsuki, Kyoko Tamaru, Yudai Oshino, Hirofumi Aritani, Hiroyuki Asakura, Kentaro Teramura, Tsunihiro Tanaka
    • Journal Title

      Molecular Catalysis

      Volume: 442 Pages: 74-82

    • DOI

      10.1016/j.mcat.2017.09.005

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 貴金属使用量低減化を目指したMn修飾六方晶 YbFeO3触媒の創製2017

    • Author(s)
      細川三郎,松本祥吾,多田稜平,芝野卓也,田中庸裕
    • Journal Title

      J. Jpn. Soc. Powder Powder Metallurgy

      Volume: 64 Pages: 583-588

    • NAID

      130006224983

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Promoter Effect of Pd Species on Mn Oxide Catalysts Supported on Rare-Earth-Iron Mixed Oxide2016

    • Author(s)
      Saburo Hosokawa, Ryohei Tada, Takuya Shibano, Shogo Matsumoto, Kentaro Teramura, Tsunehiro Tanaka
    • Journal Title

      Catal. Sci. Technol.

      Volume: 6 Issue: 21 Pages: 7868-7874

    • DOI

      10.1039/c6cy01462c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] Sr-Fe系複合酸化物のNOx酸化および吸着特性2019

    • Author(s)
      玉井和樹・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fe-Nb系複合酸化物を触媒担体に用いた三元触媒2019

    • Author(s)
      大西謙也・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第123回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ペロブスカイト型Sr-Ti系複合酸化物を担体とした自動車排ガス浄化用触媒の開発2019

    • Author(s)
      渡邉 力・細川 三郎・朝倉 博行・寺村 謙太郎・田中 庸裕
    • Organizer
      日本セラミックス協会2019年年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] browmmillerite型Ca2AlMnO5+δ担持Pd触媒による三元触媒反応2018

    • Author(s)
      押野雄大・別府孝介・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第122回触媒討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Sr-Ti系複合酸化物担持Pd触媒の三元触媒反応2018

    • Author(s)
      渡邉力, 出水章登, 細川三郎, 朝倉博行, 寺村謙太郎, 田中庸裕
    • Organizer
      第12回触媒道場
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd/Ca2AlMnO5+δ触媒の自動車排ガス浄化特性2018

    • Author(s)
      押野雄大・別府孝介・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第31回 日本セラミックス協会 秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Oxidation Characteristics of Mn-Modified Hexagonal YbFeO3 Synthesized by a Solvothermal Method2018

    • Author(s)
      Saburo Hosokawa, Shogo Matsumoto, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      6th international Solvothermal and Hydrothermal Association conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Pd/SrFe1-xTixO3触媒の自動車排気ガス浄化特性2018

    • Author(s)
      細川三郎・出水章登・別府孝介・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      セラミックス協会関西支部 平成30年度学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Dynamic Behavior of Pd Species on CeO2 during Three-Way Catalytic Reaction2018

    • Author(s)
      Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      3rd Fundamentals and applications of cerium dioxide in catalysis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fe-Nb系複合酸化物を用いた三元触媒反応2018

    • Author(s)
      大西謙也, 細川三郎, 朝倉博行, 寺村謙太郎, 田中庸裕
    • Organizer
      第7回 JACI/GSCシンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Pd/Sr3(Fe1-xNix)2O7-δ触媒によるNO選択還元2018

    • Author(s)
      別府孝介、細川三郎、朝倉博行、寺村謙太郎、田中庸裕
    • Organizer
      第121回 触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Ca2AlMnO5+δ担持Pd触媒による三元触媒反応2018

    • Author(s)
      押野雄大・別府孝介・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第121回 触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 貴金属使用量減量を指向した自動車排ガス浄化触媒2018

    • Author(s)
      田中庸裕
    • Organizer
      「自動車排気触媒システムの多様性への対応」シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ソルボサーマル合成した Mn 修飾六方晶 YbFeO3触媒を用いた三元触媒反応2017

    • Author(s)
      細川三郎・芝野卓也・多田稜平・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第119回 触媒討論会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2017-03-20
    • Related Report
      2016 Annual Research Report
  • [Presentation] ソルボサーマル合成したMn修飾六方晶YbFeO3触媒を用いたC3H6燃焼反応2017

    • Author(s)
      松本祥吾・芝野卓也・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学 駿河台キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Promoter effect of Pd species for oxygen storage capacity of Sr3Fe2O7-δ2017

    • Author(s)
      Kosuke Beppu, Saburo Hosokawa,Hiroyuki Asakura, Kentaro Teramura,Tsunehiro Tanaka
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      日本化学会第97春季年会
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Sr3Fe2O7-δ担持貴金属触媒を用いた三元触媒反応2017

    • Author(s)
      別府孝介、細川三郎、朝倉博行、寺村謙太郎、田中庸裕
    • Organizer
      日本セラミックス協会 第30回 秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] C3H6 combustion over Mn-modified hexagonal YbFeO32017

    • Author(s)
      Shogo Matsumoto, Takuya Shibano, Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      The 8th Japan-China Workshop on Environmental Catalysis
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SrFe1-xTixO3-dの酸素貯蔵能と担体効果2017

    • Author(s)
      出水章登・別府孝介・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第120回触媒討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Mn修飾六方晶YbFeO3触媒を用いたC3H6燃焼反応2017

    • Author(s)
      松本祥吾,芝野卓也,細川三郎,朝倉博行,寺村謙太郎,田中庸裕
    • Organizer
      第33回希土類討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 貴金属使用量減量を指向した自動車排ガス浄化触媒2016

    • Author(s)
      田中庸裕
    • Organizer
      合同研究発表会 日本エネルギー学会関西支部 第 61 回研究発表会 石油学会関西支部 第 25 回研究発表会
    • Place of Presentation
      京都大学桂キャンパス
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Mn修飾六方晶YbFeO3担持Pd触媒によるNO選択還元2016

    • Author(s)
      芝野卓也・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Cu/Al2O3触媒を用いたNO選択還元に対する貴金属添加効果2016

    • Author(s)
      松木和也・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mn修飾六方晶YbFeO3担持貴金属触媒によるC3H6酸化2016

    • Author(s)
      松本祥吾・芝野卓也・細川三郎・朝倉博行・寺村謙太郎・田中庸裕
    • Organizer
      第46回石油・石油化学討論会
    • Place of Presentation
      京都リサーチパーク
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mn修飾六方晶YbFeO3担持Pd触媒の三元触媒反応2016

    • Author(s)
      芝野卓也,細川三郎,朝倉博行,寺村謙太郎,田中庸裕
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学 理工学部
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Cu/Al2O3触媒のNO選択還元における貴金属添加効果2016

    • Author(s)
      松木和也、細川三郎、朝倉博行、寺村謙太郎、田中庸裕
    • Organizer
      第118回触媒討論会
    • Place of Presentation
      岩手大学 理工学部
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] Selective reduction of NO over Cu-based catalyst2016

    • Author(s)
      Kazuya Matsuki, Saburo Hosokawa, Hiroyuki Asakura, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      9th International Conference on Environmental Catalysis
    • Place of Presentation
      Newcastle, Australia
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Selective Reduction of NO over Mn-modified Hexagonal YbFeO32016

    • Author(s)
      Saburo Hosaokawa, Takuya Shibano, Ryohei Tada, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      9th International Conference on Environmental Catalysis
    • Place of Presentation
      Newcastle, Australia
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Three way catalytic reaction on Mn-modified hexagonal YbFeO32016

    • Author(s)
      Takuya Shibano, Saburo Hosokawa, Kentaro Teramura, Tsunehiro Tanaka
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2016-06-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 新規メカニズムに基づく触媒・電池材料の創成2016

    • Author(s)
      田中庸裕
    • Organizer
      シンポジウム「材料科学が拓く界面・不均一系の物性科学」
    • Place of Presentation
      金沢大学角間キャンパス
    • Related Report
      2016 Annual Research Report
    • Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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