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Mesoscopic investigation of nuclide sorption behavior on clay minerals by X-ray and neutron scattering

Research Project

Project/Area Number 16H04640
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

Endo Hitoshi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 准教授 (40447313)

Co-Investigator(Kenkyū-buntansha) 元川 竜平  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門 原子力科学研究所 物質科学研究センター, 研究主幹 (50414579)
斉藤 拓巳  東京大学, 大学院工学系研究科(工学部), 准教授 (90436543)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2016: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywordsバックエンド / 地層処分 / 粘土鉱物 / 水のダイナミクス / X線小角散乱 / 中性子準弾性散乱 / 中性子散乱 / ベントナイト / 小角散乱
Outline of Final Research Achievements

Deep geological disposal of high-level radioactive waste (HLW) from used nuclear fuel is currently the most realistic method in the world. On the other hand, there are still a lot of difficulties to proceed the method. One of the significant difficulties is the adequate assessment of its long-term stability. With the deep geological disposal, HLW is insulated from our living area by two barriers, that is, natural barrier represented by host rock and engineered barrier with vitrified waste, overpack seal, and consolidated bentonite buffer. Clay minerals are the major component in not only the host rock but also the buffer materials, so that sorption behavior of radioactive nuclear species and water in the clay materials are of urgent importance for the application of the deep geological disposal. In this study, the mesoscopic structure of clay minerals and the water dynamics in them were studied by small-angle x-ray scattering and quasi-elastic neutron.

Academic Significance and Societal Importance of the Research Achievements

本研究により粘土鉱物のメゾスコピックな構造及び水の状態に関する情報と放射性核種の収着・移行現象の相関を解明することで,これまでブラックボックス化されていたミクロとマクロを繋ぐ,より科学的に妥当なパラメータを与える.また,近年,シェールガス採掘のための資源探査の分野でも,岩石のメゾスコピック構造評価にSAXSが利用され始めており, 本研究を,今後,工学的な利用が進むと考えられる深部地質媒体という場の理解に小角散乱実験手法を用いる端緒と位置付けることもでき,関係分野への大きな波及も期待出来る.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (12 results)

All 2019 2018 Other

All Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 3 results) Presentation (5 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] A Telescoping View of Solute Architectures in a Complex Fluid System2019

    • Author(s)
      Ryuhei Motokawa, Tohru Kobayashi, Hitoshi Endo,, Junju Mu, Christopher D. Williams, Andrew J. Masters, Mark R. Antonio, William T. Heller, Michihiro Nagao
    • Journal Title

      ACS Central Science

      Volume: 5 Issue: 1 Pages: 85-96

    • DOI

      10.1021/acscentsci.8b00669

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Status of neutron spectrometers at J-PARC2019

    • Author(s)
      Ryoichi Kajimoto, Tetsuya Yokoo, Mitsutaka Nakamura, Yukinobu Kawakita, Masato Matsuura, Hitoshi Endo, Hideki Seto, Shinichi Itoh, Kenji Nakajima, Seiko Ohira-Kawamura
    • Journal Title

      Physica B

      Volume: 562 Pages: 148-152

    • DOI

      10.1016/j.physb.2018.11.061

    • NAID

      120007153036

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Current Status of the Neutron Resonance Spin Echo Spectrometer on BL06 "VIN ROSE" at MLF, J-PARC2019

    • Author(s)
      Hitoshi Endo, Tatsuro Oda, Masahiro Hino, Takuya Hosobata
    • Journal Title

      Physica B

      Volume: 564 Pages: 91-93

    • DOI

      10.1016/j.physb.2018.11.069

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Precision Mechanical Design of 900?mm Long Ellipsoidal Neutron-focusing Supermirror for VIN ROSE at J-PARC/MLF2018

    • Author(s)
      Hosobata Takuya、Hino Masahiro、Yoshinaga Hisao、Kawai Toshihide、Endo Hitoshi、Yamagata Yutaka、Yamada Norifumi L.、Takeda Shin
    • Journal Title

      JPS Conf. Proc.

      Volume: 22

    • DOI

      10.7566/jpscp.22.011010

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A focusing test of a multiple segmented ellipsoidal neutron-focusing mirror for a compact-focusing SANS instrument2018

    • Author(s)
      Shin TAKEDA, Takuya HOSOBATA, Yutaka YAMAGATA, Masahiro HINO, Tatsuro ODA, Hitoshi Endoh, Norifumi L. YAMADA, Shin-ya MORITA, Michihiro Furusaka
    • Journal Title

      JPS Conf. Proc.

      Volume: 22

    • DOI

      10.7566/jpscp.22.011013

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of 400-kHz TOF-MIEZE Signals2018

    • Author(s)
      Tatsuro Oda, Masahiro Hino, Hitoshi Endo, Norifumi L. Yamada, Yuji Kawabata, Hideki Seto
    • Journal Title

      JPS Conf. Proc.

      Volume: 22 Pages: 011029-011029

    • DOI

      10.7566/jpscp.22.011029

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] J-PARC MLF BL06 VIN ROSEにおける NRSE開発状況2019

    • Author(s)
      遠藤仁、日野正裕、小田達郎、細畠 拓也
    • Organizer
      量子ビームサイエンスフェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] Current status of neutron resonance spin echo spectrometers BL06 “VIN ROSE” at MLF, J-PARC2018

    • Author(s)
      Hitoshi Endo
    • Organizer
      The 8th workshop on Inelastic Neutron Spectrometers - WINS2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Current Status of BL06 VIN ROSE at MLF J-PARC2018

    • Author(s)
      Hitoshi Endo
    • Organizer
      International Workshop on Neutron Spin-Echo Spectroscopy 2018; 40 years of NSE user operation
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] MLF BL06 VIN ROSEにおけるNRSE開発状況2018

    • Author(s)
      遠藤仁、小田達郎、日野正裕、細畠 拓也
    • Organizer
      日本中性子科学会第18回年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 小角X線散乱を用いた圧密ベントナイトのメゾスコピック構造評価2018

    • Author(s)
      斉藤 拓巳、永井 菜月、元川 竜平、遠藤 仁
    • Organizer
      日本原子力学会2018年春の年会
    • Related Report
      2017 Annual Research Report
  • [Remarks] researchmap

    • URL

      https://researchmap.jp/hitendo/

    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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