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Silicene surrounded by oxide- Development using self-limitation of oxidation and oxidation-induced strain

Research Project

Project/Area Number 16H05969
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Ogawa Shuichi  東北大学, 多元物質科学研究所, 助教 (00579203)

Research Collaborator Takakuwa Yuji  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2018: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2017: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2016: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords熱酸化 / シリセン / 酸化誘起歪み / 点欠陥 / リアルタイム光電子分光 / 熱酸化プロセス / 酸化反応測度論 / 歪み誘起反応工学 / 半導体超微細化 / 電子・電気材料 / 酸化反応速度論 / 歪み計測 / 表面・界面物性 / 酸化反応自己停止 / シリコン熱酸化 / 歪み誘起反応制御
Outline of Final Research Achievements

In order to prepare silicene (a thin film of one atomic layer of silicon) with excellent electrical properties by oxidation of a silicon wafer, the mechanism of the oxidation self-termination which the progress of thermal oxidation stopped was investigated. As a result, it was found that the lattice strain included by oxidation was the cause. If there are no defects formed to relieve the strain, the oxidation reaction is limited, and it becomes possible to stop the reaction by leaving one atomic layer. However, it has also been found that oxidation does not self-limited in the presence of even a small amount of light.

Academic Significance and Societal Importance of the Research Achievements

本研究によりケイ素の酸化反応が自己停止する条件を明らかにすることができた。これにより、絶縁体かつ保護膜として機能するSiO2に囲まれたシリセンを作製できる可能性が高まった。酸化膜で囲まれたシリセンを酸化反応のみで作製できれば、現在の電子デバイスよりも低消費電力で高性能なものが作製可能である。しかしながら現状ではシリセンの電気特性など明らかになっていない点も多く残っているため、今後さらなる研究が必要とされる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (25 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Peer Reviewed: 6 results,  Open Access: 4 results,  Acknowledgement Compliant: 1 results) Presentation (15 results) (of which Int'l Joint Research: 9 results,  Invited: 3 results) Book (2 results)

  • [Int'l Joint Research] フリッツハーバー研究所(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] ケースウエスタンリザーブ大学(米国)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 光電子分光法によるSi表面酸化プロセス反応速度と 酸化誘起歪みの同時観察2019

    • Author(s)
      小川修一、吉越章隆、高桑雄二
    • Journal Title

      表面と真空

      Volume: 62

    • NAID

      130007662229

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Band alignment determination of bulk h-BN and graphene/h-BN laminates using photoelectron emission microscopy2019

    • Author(s)
      Ogawa Shuichi、Yamada Takatoshi、Kadowaki Ryo、Taniguchi Takashi、Abukawa Tadashi、Takakuwa Yuji
    • Journal Title

      Journal of Applied Physics

      Volume: 125 Issue: 14 Pages: 144303-144303

    • DOI

      10.1063/1.5093430

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Interfacial oxidation kinetics at SiO2/Si(001) mediated by the generation of point defects: Effect of raising O2 pressure2018

    • Author(s)
      Ogawa Shuichi、Takakuwa Yuji
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 7 Pages: 075119-075119

    • DOI

      10.1063/1.5034395

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polarity identification of ZnO(0001) surface by reflection high-energy electron diffraction2018

    • Author(s)
      Y. Horio, J. Yuhara, Y. Takakuwa, S. Ogawa, and K. Abe
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 57 Issue: 4 Pages: 045701-045701

    • DOI

      10.7567/jjap.57.045701

    • NAID

      210000148836

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhancement of SiO2/Si(001) interfacial oxidation induced by thermal strain during rapid thermal oxidation2016

    • Author(s)
      S. Ogawa, J. Tang, A. Yoshigoe, S. Ishidzuka, Y. Takakuwa
    • Journal Title

      The Journal of Chemical Physics

      Volume: 145 Issue: 11 Pages: 114701-114701

    • DOI

      10.1063/1.4962671

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Detection of molecular oxygen adsorbate during room-temperature oxidation of Si(100)2×1 surface: In situ synchrotron radiation photoemission study2016

    • Author(s)
      A. Yoshigoe, Y. Yamada, R. Taga, S. Ogawa, Y. Takakuwa
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 10 Pages: 100307-100307

    • DOI

      10.7567/jjap.55.100307

    • NAID

      210000147114

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] リアルタイムXPSによるSi表面酸化プロセスの反応速度・酸化誘起歪みの同時観察2018

    • Author(s)
      小川修一
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] O2 Pressure Dependence of Oxidation Rate on p- and n-Si(001) Surfaces2018

    • Author(s)
      Y. Sekihata, S. Ogawa and Y. Takakuwa
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Behavior of Ni Vacancy during Oxidation on Ni(111) Surfaces2018

    • Author(s)
      Binguo Zhang, Shuichi Ogawa, Yuji Takakuwa
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] O2 pressure dependence of initial oxidation kinetics on Ni(111) surfaces2018

    • Author(s)
      S. Ogawa, R. Taga, T. Ozaki, A. Yoshigoe, and Y. Takakuwa
    • Organizer
      The 34th European Conference on Surface Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photo-induced enhancement of oxidation on p- and n-type Si(001) surfaces2018

    • Author(s)
      Y. Sekihata, S. Ogawa, A. Yoshigoe, R. Taga, A. Klyushin, E. Carbonio, A. Knop-Gericke, and Y. Takakuwa
    • Organizer
      The 34th European Conference on Surface Science
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リアルタイム光電子分光による表面反応プロセスの解明2018

    • Author(s)
      小川修一
    • Organizer
      2018年度微細構造解析プラットフォームシンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 酸化Ni(111)表面の還元過程:真空およびH2中加熱の比較2018

    • Author(s)
      多賀 稜,小川 修一,尾崎 司,吉田 光,吉越 章隆,髙桑 雄二
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] リアルタイム光電子分光による Si(001)基板初期酸化過程における p 型 n 型伝導度依存の解明2017

    • Author(s)
      堰端勇樹,多賀稜,小川修一,髙桑雄二
    • Organizer
      平成28年度日本表面科学会東北・北海道支部講演会
    • Place of Presentation
      秋田大学(秋田県秋田市)
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 圧力急増によるSiO2/Si(001)界面酸化促進とその律速過程の解明2017

    • Author(s)
      小川修一, 高桑雄二
    • Organizer
      第78回応用物理学会 秋季学術講演会,
    • Related Report
      2017 Annual Research Report
  • [Presentation] Comparison of Initial Oxidation Kinetics between p- and n-type Si(001) Surfaces Studied by Real-time Photoelectron Spectroscopy2017

    • Author(s)
      Y. Sekihata, S. Ogawa, A. Yoshigoe, R. Taga, S. Ishidzuka, Y. Takakuwa
    • Organizer
      AVS 64th International Symposium & Exhibition 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] O2 Pressure Dependence of SiO2/Si Interfacial Oxidation Rate Studied by Real-time Photoelectron Spectroscopy2017

    • Author(s)
      S. Ogawa, A. Yoshigoe, S. Ishidzuka, Y. Takakuwa
    • Organizer
      AVS 64th International Symposium & Exhibition 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photo-Induced Enhancement of Oxidation on p- and n-type Si(001) surfaces2017

    • Author(s)
      Y. Sekihata, S. Ogawa, Y. Akitaka, R. Taga, A. Klyushin, E. Carbonio, A. Knop-Gericke, Y. Takakuwa
    • Organizer
      2017 International Workshop on Dielectric Thin Films for Future Electron Devices
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Si(100)表面室温酸化中の「分子状吸着酸素」の発見 -放射光が30年来の謎を解く-2016

    • Author(s)
      吉越章隆、多賀稜、小川修一、高桑雄二
    • Organizer
      第16回東北大学多元物質科学研究所 研究発表会
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2016-12-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Interface oxidation enhancement at SiO2/Si(001) by raising O2 pressure2016

    • Author(s)
      S. Ogawa, J. Tang, R. Taga, Y. Takakuwa
    • Organizer
      The 13th International Conference on Atomically Controlled Surfaces
    • Place of Presentation
      Rome, Italy
    • Year and Date
      2016-10-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Comparative Study of O2 Adsorption Kinetics on p- and n-Si(001) Surfaces at Room Temperature2016

    • Author(s)
      R. Taga, K. Nishimoto, J. Tang, Z. Yu, S. Ogawa, Y. Takakuwa
    • Organizer
      The 20th International Vacuum Congress
    • Place of Presentation
      釜山、韓国
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] 放射光利用の手引き2019

    • Author(s)
      東北放射光施設推進会議推進室
    • Total Pages
      344
    • Publisher
      アグネ技術センター
    • ISBN
      9784901496957
    • Related Report
      2018 Annual Research Report
  • [Book] X線光電子分光法2018

    • Author(s)
      小川修一(分担執筆)
    • Total Pages
      368
    • Publisher
      講談社サイエンティフィク
    • ISBN
      9784065140475
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2022-05-23  

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