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Establishment of semiconductor-oxide composite nanowires and its application to photocatalyst

Research Project

Project/Area Number 16H05970
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Nanomaterials engineering
Research InstitutionEhime University

Principal Investigator

Ishikawa Fumitaro  愛媛大学, 理工学研究科(工学系), 准教授 (60456994)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
Fiscal Year 2018: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2017: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2016: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywordsナノワイヤ / 分子線エピタキシー / 化合物半導体 / 酸化物 / 半導体 / 白色発光 / ナノ材料
Outline of Final Research Achievements

We establish a new nanowire material that combines GaAs-based compound semiconductors having high electronic and optical properties with oxides of the various and stable properties.
We succeeded in extending the GaAs nanowire function by adding nitrogen and bismuth. In addition, we succeeded in forming GaAs/AlGaOx heterostructure nanowires by simple natural oxidation. ALso, we have fabricated high-precision GaAs/TiO heterostructure nanowires by combining crystal growth and sputtering. We demonstrated that the GaAs nanowire array fabricated on the cm-sized Si substrate acts as a photoanode.

Academic Significance and Societal Importance of the Research Achievements

Si基板上に形成されたGaAs系ナノワイヤの高機能化は、現在のLSI技術を飛躍的に向上させる可能性がある。本研究では、2インチのSi基板全域に高い光・電子機能を有するGaAsナノワイヤを形成することで、その融合可能性を示した。さらに、多様な元素・材料の添加、積層によりその機能が拡張できることを示した。窒素およびビスマスの添加では近赤外域の応用域・機能を拡大することで通信・センシングの動作性能の向上が見込まれる。AlGaOx自然酸化層はこれらの性能と安定性を向上させられる可能性がある。光アノード機能の実証とTiO酸化物の融合は、エネルギー創出のための光触媒応用に有望である。

Report

(4 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (45 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (12 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 6 results,  Open Access: 1 results) Presentation (26 results) (of which Int'l Joint Research: 18 results,  Invited: 3 results) Book (1 results) Remarks (2 results)

  • [Int'l Joint Research] Linkoping University(スウェーデン)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Michigan University(米国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Linkoping University(スウェーデン)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Wroclaw University(ポーランド)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Effects of growth temperature and thermal annealing on optical quality of GaNAs nanowires emitting in the near-infrared spectral range2020

    • Author(s)
      Jan Eric Stehr, Roman Balagula, Mattias Jansson, Mitsuki Yukimune, Ryo Fujiwara, Fumitaro Ishikawa, Weimin Chen, Irina A Buyanova
    • Journal Title

      Nanotechnology

      Volume: 31 Issue: 19

    • DOI

      10.1063/1.5092524

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Controlling Bi Provoked Nanostructure Formation in GaAs/GaAsBi Core-Shell Nanowires2019

    • Author(s)
      Teruyoshi Matsuda, Kyohei Takada, Kosuke Yano, Rikuo Tsutsumi, Kohei Yoshikawa, Satoshi Shimomura, Yumiko Shimizu, Kazuki Nagashima,Takeshi Yanagida, Fumitaro Ishikawa
    • Journal Title

      Nano Letters

      Volume: 19 Issue: 12 Pages: 8510-8510

    • DOI

      10.1021/acs.nanolett.9b02932

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of Thin Film Concepts to Explore Additional Compound Semiconductor Nanowires2019

    • Author(s)
      石川史太郎
    • Journal Title

      Journal of the Japanese Association for Crystal Growth

      Volume: 46 Issue: 2 Pages: n/a

    • DOI

      10.19009/jjacg.46-2-04

    • NAID

      130007688852

    • ISSN
      0385-6275, 2187-8366
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphological and chemical instabilities of nitrogen delta-doped GaAs/(Al, Ga)As quantum wells2017

    • Author(s)
      E. Luna, R. Gargallo-Caballero, F. Ishikawa, and A. Trampert
    • Journal Title

      Applied Physics Letters

      Volume: 110 Issue: 20

    • DOI

      10.1063/1.4983837

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Material conversion of GaAs nanowires2017

    • Author(s)
      Kohei Nishioka, Hidetoshi Suzuki, Kentaro Sakai, Fumitaro Ishikawa
    • Journal Title

      Physica Status Solidi b

      Volume: 254 Issue: 2

    • DOI

      10.1002/pssb.201600522

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dilute Nitride Nanowire Lasers Based on a GaAs/GaNAs Core/Shell Structure2017

    • Author(s)
      Shula Chen, Mattias Jansson, Jan E. Stehr, Yuqing Huang, Fumitaro Ishikawa, Weimin M. Chen, Irina A. Buyanova
    • Journal Title

      Nano Letters

      Volume: 17 Issue: 3 Pages: 1775-1781

    • DOI

      10.1021/acs.nanolett.6b05097

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] White-Light Emitters: (Al,Ga)Ox Microwire Ensembles on Si Exhibiting Luminescence over the Entire Visible Wavelength Range2016

    • Author(s)
      Fumitaro Ishikawa, Pierre Corfdir, Uwe Jahn, Oliver Brandt
    • Journal Title

      Advanced Optical Materials

      Volume: 4 Issue: 12 Pages: 2016-2016

    • DOI

      10.1002/adom.201670068

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] (Al,Ga)Ox Microwire Ensembles on Si Exhibiting Luminescence over the Entire Visible Wavelength Range2016

    • Author(s)
      Fumitaro Ishikawa, Pierre Corfdir, Uwe Jahn, Oliver Brandt
    • Journal Title

      Advanced Optical Materials

      Volume: 4 Issue: 12 Pages: 2017-2020

    • DOI

      10.1002/adom.201600695

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Defect formation in GaAs/GaNxAs1-x core/shell nanowires2016

    • Author(s)
      Jan E. Stehr, Shula Chen, Mattias Jansson, Fumitaro Ishikawa, Weimin M. Chen, Irina A. Buyanova
    • Journal Title

      Applied Physics Letters

      Volume: 109 Issue: 20

    • DOI

      10.1063/1.4967721

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Photoacoustic spectroscopy of absorption edge for GaAsBi/GaAs nanowires grown on Si substrate2016

    • Author(s)
      Szymon J. Zelewski, Jan Kopaczek, Wojciech M. Linhart, Fumitaro Ishikawa, Satoshi Shimomura, Robert Kudrawiec
    • Journal Title

      Applied Physics Letters

      Volume: 109 Issue: 18

    • DOI

      10.1063/1.4966901

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Strongly polarized quantum-dot-like light emitters embedded in GaAs/GaNAs core/shell nanowires2016

    • Author(s)
      S Filippov, M Jansson, J E Stehr, J Palisaitis, P Persson, F Ishikawa, W M Chen, I Buyanova
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 35 Pages: 15939-15947

    • DOI

      10.1039/c6nr05168e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Core shell carrier and exciton transfer in GaAs/GaNAs coaxial nanowires2016

    • Author(s)
      Shula Chen, Mattias Jansson, Stanislav Filippov, Fumitaro Ishikawa, Weimin M. Chen, Irina A. Buyanova
    • Journal Title

      Journal of Vacuum Science & Technology B

      Volume: 34 Issue: 4

    • DOI

      10.1116/1.4953184

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Growth of Dilute Nitride Core-Multishell Heterostructured Nanowires2019

    • Author(s)
      M. Yukimune, R. Fujiwara, F. Ishikawa
    • Organizer
      International School and Symposium on Nanoscale Transport and phoTonics 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaAs Nanowires on Si for its application to photoanodes2019

    • Author(s)
      T. Ohno, M. Yukimune, R. Fujiwara,Y. Wang, Z. Mi, F. Ishikawa
    • Organizer
      Micro Nano Conference 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth of Dilute Nitride Core-Multishell Nanowires2019

    • Author(s)
      Ryo Fujiwara, Mitsuki Yukimune, Fumitaro Ishikawa
    • Organizer
      7th International Workshop on Epitaxial Growth and Fundamental Properties of Semiconductor Nanostructures, SemiconNano 2019,
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Outermost Native Oxide AlGaOx Shell for GaAs Related Core-Shell Nanowires2019

    • Author(s)
      Naoki Tsuda, Fumitaro Ishikawa
    • Organizer
      7th International Workshop on Epitaxial Growth and Fundamental Properties of Semiconductor Nanostructures, SemiconNano 2019,
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi segregation in GaAs/GaAsBi/GaAs core-multishell nanowires2019

    • Author(s)
      Teruyoshi Matsuda,Kosuke Yano, Satoshi Shimomura, Yumiko Shimizu, Fumitaro Ishikawa
    • Organizer
      Nanowire Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polytypism transfer observed in GaAs/GaNAs core-shell nanowires2019

    • Author(s)
      M. Yukimune, R. Fujiwara, T. Mita, F. Ishikawa
    • Organizer
      Nanowire Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] T. Mita, R. Fujiwara, M. Yukimune, R. Tsutsumi, F. Ishikawa2019

    • Author(s)
      Molecular beam epitaxial growth of various diluted nitride nanowires
    • Organizer
      Nanowire Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of GaAs/TiO2 composite nanowires2019

    • Author(s)
      Tomoki Ohno, Mitsuki Yukimune, Ryo Fujiwara, Kazuki Nagashima, Takeshi Yanagida, Fumitaro Ishikawa
    • Organizer
      Nanowire Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristics of GaAs/AlGaAs core-multishell structures having native oxide AlGaO Outermost shell2019

    • Author(s)
      R. Tsutsumi, N. Tsuda, B. Zhang, W. M. Chen, I. A Buyanova, F. Ishikawa
    • Organizer
      Nanowire Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaAs/AlGaAs Core-Multishell Structure Covered by Native oxide AlGaOx2019

    • Author(s)
      R. Tsutsumi, N. Tsuda, F.Ishikawa
    • Organizer
      2019 international conference on solid state devices and materials SSDM
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bi localization in GaAs/GaAsBi/GaAs heterostructured nanowires2019

    • Author(s)
      Teruyoshi Matsuda, Kosuke Yano, Satoshi Shimomura, Fumitaro Ishikawa
    • Organizer
      The 10th International Workshop on Bismuth-Containing Semiconductors
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Dilute Nitride GaNAs Nanowires for Optoelectronics”Growth of GaAs/GaNAs/GaAs Core-Multishell Nanowires Lasing at 1-micro m2019

    • Author(s)
      Mitsuki Yukimune, Ryo Fujiwara, Fumitaro Ishikawa, Shula Chen, Mattias Jansson, Weimin M. Chen, Irina A. Buyanova
    • Organizer
      EDISON 21; The 21st International Conference Electron Dynamics in Semiconductors, Optoelectronics and Nanostructures
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] GaAs/GaAsBi Core-Multishell Nanowires Forming Quantum Confined Structure2019

    • Author(s)
      Teruyuki Matsuda, Kosuke Yano, Satoshi Shimomura, Fumitaro Ishikawa
    • Organizer
      EDISON 21; The 21st International Conference Electron Dynamics in Semiconductors, Optoelectronics and Nanostructures
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth of GaAs/GaNAs/GaAs Core-Multishell Nanowires Lasing at 1-micro m2019

    • Author(s)
      Mitsuki Yukimune, Ryo Fujiwara, Fumitaro Ishikawa, Shula Chen, Weimin M. Chen, Irina A. Buyanova
    • Organizer
      Compound Semiconductor Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Crystal structures of GaAs/GaNAs core-multishell nanowires2019

    • Author(s)
      Takaya Mita, Ryo Fujiwara, Mitsuki Yukimune, Fumitaro Ishikawa
    • Organizer
      Compound Semiconductor Week 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] AlGaOxナノワイヤの発光特性2018

    • Author(s)
      夏井 潤、山本 直紀、石川 史太郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 自然酸化AlGaOx最外殻とGaAs/AlGaAsヘテロ構造を用いたGaAsナノワイヤパッシベーション構造の作製2018

    • Author(s)
      津田 眞、石川 史太郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Si(111) 基板上GaAs/GaAsBiヘテロ構造ナノワイヤにおける微細構造成長2018

    • Author(s)
      矢野 康介、高田 恭兵、Patil Pallavi、下村 哲、清水 夕美子、長島 一樹、柳田 剛、石川 史太郎
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Vertically coherent lattice deformation in GaAs/GaAsBi heterostructural nanowires2017

    • Author(s)
      Kyohei Takada, Kosuke Yano, Takeshi Hayakawa, Kohei Nishioka, Pallavi Patil, Fumitaro Ishikawa, Satoshi Shimomura, Kazuki Nagashima, Takeshi Yanagida
    • Organizer
      8th International Workshop on Bismuth-Containing Semiconductors
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Branch formation in GaAs/GaAsBi nanowires on Si(111)2017

    • Author(s)
      Kohsuke Yano, Takeshi Hayakawa, Kyohei Takada, Kohei Nishioka, Pallavi Patil, Fumitaro Ishikawa, Satoshi Shimomura, Kazuki Nagashima, Takeshi Yanagida
    • Organizer
      Compound Semiconductor Week 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] GaAs/GaAsBi nanowire growth on Si(111)2017

    • Author(s)
      K. Yano, K. Takada, K. Nishioka, P. Patil, F. Ishikawa, S. Shimomura, K. Nagashima, and T. Yanagida
    • Organizer
      第36回電子材料シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of GaAs-related multishell nanowires with native oxide AlGaOx outermost shell2017

    • Author(s)
      N. Tsuda and F. Ishikawa
    • Organizer
      第36回電子材料シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] GaAs/GaAsBi歪コアーシェルナノワイヤ側壁での垂直格子定数合致型コヒーレント成長2017

    • Author(s)
      矢野 康介、高田 恭兵、Pallavi Patil、石川 史太郎、下村 哲、長島 一樹、柳田 剛
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Additional GaAs related nanowires2016

    • Author(s)
      Fumitaro Ishikawa
    • Organizer
      JSPS workshop on Japan-Sweden frontiers in spin and photon functionalities of semiconductor nanostructures,
    • Place of Presentation
      Jozankei Grand Hotel, Sapporo, Japan.
    • Year and Date
      2016-08-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel GaNAs and GaNP-Based Nanowires ・Promising Materials for Optoelectronics and Photonics2016

    • Author(s)
      Irina Buyanova, Fumitaro Ishikawa, Charles Tu, Weimin Chen
    • Organizer
      IEEE NANO 2016- 16th International Conference On Nanotechnology
    • Place of Presentation
      Sendai International Center, Sendai, Japan
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] GaAsBi Heterostructured Nanowires Grown by Molecular Beam Epitaxy2016

    • Author(s)
      Fumitaro Ishikawa and Satoshi Shimomura
    • Organizer
      The 7th International Workshop on Bismuth-Containing Semiconductors
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2016-07-24
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Book] Novel Compound Semiconductor Nanowires - Materials, Devices, and Applications2017

    • Author(s)
      Fumitaro Ishikawa and Irina A. Buyanova
    • Total Pages
      527
    • Publisher
      Pan Stanford Publishing
    • ISBN
      9789814745765
    • Related Report
      2017 Annual Research Report
  • [Remarks] 愛媛大学 融合電子材料工学研究室webページ

    • URL

      http://www.ee.ehime-u.ac.jp/yugo/index.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 愛媛大学 ナノエレクトロニクス研究室ホームページ

    • URL

      http://www.ee.ehime-u.ac.jp/nano/index.html

    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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