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Crystal growth control of organolead halide perovskite for high efficiency solar cells

Research Project

Project/Area Number 16H05978
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Applied materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Miyadera Tetsuhiko  国立研究開発法人産業技術総合研究所, エネルギー・環境領域, 主任研究員 (30443039)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2018: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2017: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2016: ¥12,350,000 (Direct Cost: ¥9,500,000、Indirect Cost: ¥2,850,000)
Keywordsペロブスカイト太陽電池 / 結晶成長 / 有機無機ハイブリッド材料 / 有機単結晶 / エピタキシャル成長 / 太陽電池 / X線回折 / 有機鉛ペロブスカイト / エピタキシー / レーザー蒸着 / 有機デバイス
Outline of Final Research Achievements

For the further development of the efficiency of perovskite solar cells, we focused on the crystallization control of organolead-halide perovskite. We attempted the growth of perovskite on the single crystal rubrene, which is typical organic semiconducting materials. We succeeded in the construction of epitaxial perovskite film with high crystallinity and atomically ordered morphology. Next, the system to conduct real-time X-ray diffraction measurement was constructed. The real-time analysis of crystallization process of organolead-halide perovskite was conducted and some feature for the crystallization dynamics are successfully obtained.

Academic Significance and Societal Importance of the Research Achievements

ペロブスカイト太陽電池は光電変換効率が急速に向上しており、次世代太陽電池として注目を集めているが、結晶成長に関する基礎的な知見が得られておらず、各研究機関のノウハウに頼った研究開発となっているのが現状である。本研究では有機鉛ペロブスカイトの結晶成長制御手法の確立および結晶成長メカニズムの解明に成功した。これらの成果は今後のプロセス開発や素子開発に重要な知見を与え、ペロブスカイト太陽電池のさらなる発展に資するものである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (10 results)

All 2019 2018 2017 2016

All Presentation (10 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results)

  • [Presentation] 有機鉛ペロブスカイトの結晶成長2019

    • Author(s)
      宮寺哲彦
    • Organizer
      ハロゲン化金属ペロブスカイト 研究の最前線
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 有機鉛ペロブスカイトの結晶成長2018

    • Author(s)
      宮寺哲彦
    • Organizer
      第79回応用物理学会秋季学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 真空プロセスによる有機鉛ペロブスカイトの結晶成長制御2018

    • Author(s)
      宮寺哲彦、阿内悠人、小金澤智之、矢口裕之、吉田郵司、近松真之
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Epitaxial growth of organolead-halide perovskite on rubrene single crystals2018

    • Author(s)
      Yuto Auchi, Tetsuhiko Miyadera, Tomoyuki Koganezawa Hiroyuki Yaguchi, Masayuki Chikamatsu, and Yuji Yoshida
    • Organizer
      Solid state device meeting 2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] 正逆光電子分光による有機鉛ペロブスカイト/ホール輸送層界面の 電子状態解析2018

    • Author(s)
      宮寺哲彦 他
    • Organizer
      応用物理学会第65回春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Crystallization of organolead halide perovskite: vacuum deposition and real-time analysis2017

    • Author(s)
      宮寺哲彦
    • Organizer
      7th Korea-Japan Joint Symposium on Semiconductor Physics and Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ルブレン単結晶上の有機鉛ペロブスカイトのエピタキシャル成長2017

    • Author(s)
      阿内悠人、宮寺哲彦、小金澤智之, 近松真之
    • Organizer
      第64回 春季応用物理学会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Real Time Analysis of the Crystallization Dynamics of Organilead Halide Perovskite2016

    • Author(s)
      宮寺哲彦
    • Organizer
      Electrochemical Society Fall Meeting
    • Place of Presentation
      Honolulu(アメリカ合衆国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of coevaporation technique for the organic solar cells2016

    • Author(s)
      宮寺哲彦
    • Organizer
      Energy Materials Nanotechnology East Meeting
    • Place of Presentation
      北京(中華人民共和国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Laser deposition for the highly controlled co-deposition of organolead halide perovskite2016

    • Author(s)
      宮寺哲彦、杉田武、反保衆志、松原浩司、近松真之
    • Organizer
      Materials Research Society Fall Meeting
    • Place of Presentation
      Boston(アメリカ合衆国)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2020-03-30  

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