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Hierarchical dynamics of crystal-melt interfaces

Research Project

Project/Area Number 16H05979
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Crystal engineering
Research InstitutionHokkaido University

Principal Investigator

Ken-ichiro Murata  北海道大学, 低温科学研究所, 助教 (60646272)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥25,610,000 (Direct Cost: ¥19,700,000、Indirect Cost: ¥5,910,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Fiscal Year 2016: ¥14,040,000 (Direct Cost: ¥10,800,000、Indirect Cost: ¥3,240,000)
Keywords結晶成長 / 融液成長 / その場観察 / ステップバンチング / 擬似液体層 / 表面・界面物性 / 共焦点顕微鏡 / 相転移ダイナミクス
Outline of Final Research Achievements

We have made in situ observations of ice-water interfaces with laser confocal microscopy combined with differential interference microscopy (LCM-DIM), whose resolution in the height direction reaches the order of an angstrom. We have demonstrated the microscopic structure of these interfaces and the hierarchical dynamics of ice interfaces during the melt growth. Specifically, we have revealed that there exist elementary (mono-molecular) steps even in supercooled water and these elementary steps often exhibit the bunching instability on the vicinal basal face, depending on experimental conditions.

In addition, with the aid of LCM-DIM, we have made direct observations of the formation of quasi liquid layers (QLLs) on ice surfaces, which allows us to elucidate a thermodynamic origin of surface melting of ice crystals. We also succeeded in making in situ observations of the perfect spiral growth during the vapor growth of ice.

Academic Significance and Societal Importance of the Research Achievements

同じ凝縮相である(即ち密度差が小さい)結晶相と液体相がその界面どのように区別されるのか、という基礎的な問いに答えることで、融液成長が環境相の異なる気相成長、溶液成長と同じ物理的基盤を有すること示した。本研究結果は、結晶成長メカニズムに対するより包括的な視座を提供するものである。また、本研究の対象である氷は、水と共に地球上にあまねく存在し、氷やその表面を覆う擬似液体層が主役になる自然現象は枚挙に暇がない。例えば、降雪、雲形成、氷上の潤滑、雷雲での電気の発生機構などはその代表例である。本研究により得られた知見は、これらの自然現象の基礎的理解の進展に寄与するものと期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (22 results)

All 2019 2018 2017 2016

All Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results)

  • [Journal Article] How Do Ice Crystals Grow inside Quasiliquid Layers?2019

    • Author(s)
      Murata K, Nagashima K, Sazaki G
    • Journal Title

      Phys. Rev. Lett.

      Volume: 122 Issue: 9 Pages: 26102-26102

    • DOI

      10.1103/physrevmaterials.2.093402

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quasi-liquid layers can exist on polycrystalline ice thin films at a temperature significantly lower than on ice single crystals.2019

    • Author(s)
      Chen J, Nagashima K, Murata K, Sazaki G
    • Journal Title

      Crystal Growth & Design

      Volume: 19(1) Issue: 1 Pages: 116-124

    • DOI

      10.1021/acs.cgd.8b01091

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uptake Mechanism of Atmospheric Hydrogen Chloride Gas in Ice Crystals via Hydrochloric Acid Droplets.2018

    • Author(s)
      Nagashima K, Sazaki G, Hama T, Murata K, Furukawa Y
    • Journal Title

      Crystal Growth & Design

      Volume: 18(7) Issue: 7 Pages: 4117-4122

    • DOI

      10.1021/acs.cgd.8b00531

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In-situ observation of spiral growth on ice crystal surfaces.2018

    • Author(s)
      Murata K, Nagashima K, Sazaki G
    • Journal Title

      Phys. Rev. Matt.

      Volume: 2(9) Issue: 2

    • DOI

      10.1103/physrevlett.122.026102

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature Dependence of the Growth Kinetics of Elementary Spiral Steps on Ice Basal Faces Grown from Water Vapor2018

    • Author(s)
      Inomata Masahiro、Murata Ken-ichiro、Asakawa Harutoshi、Nagashima Ken、Nakatsubo Shunichi、Furukawa Yoshinori、Sazaki Gen
    • Journal Title

      Crystal Growth & Design

      Volume: 18 Issue: 2 Pages: 786-793

    • DOI

      10.1021/acs.cgd.7b01251

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Liquid-like behavior of UV-irradiated interstellar ice analog at low temperatures2017

    • Author(s)
      Tachibana Shogo、Kouchi Akira、Hama Tetsuya、Oba Yasuhiro、Piani Laurette、Sugawara Iyo、Endo Yukiko、Hidaka Hiroshi、Kimura Yuki、Murata Ken-ichiro、Yurimoto Hisayoshi、Watanabe Naoki
    • Journal Title

      Science Advances

      Volume: 3 Issue: 9

    • DOI

      10.1126/sciadv.aao2538

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oscillations and accelerations of ice crystal growth rates in microgravity in presence of antifreeze glycoprotein impurity in supercooled water2017

    • Author(s)
      Yoshinori Furukawa, Ken Nagashima, Shun-ichi Nakatsubo, Izumi Yoshizaki, Haruka Tamaru, Taro Shimaoka, Takehiko Sone, Etsuro Yokoyama, Salvador Zepeda, Takanori Terasawa, Harutoshi Asakawa, Ken-ichiro Murata and Gen Sazaki
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 43157-43157

    • DOI

      10.1038/srep43157

    • NAID

      120006305557

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A new thermodynamic origin of surface melting on ice crystals2016

    • Author(s)
      K. Murata, H. Asakawa, K. Nagashima, Y. Furukawa
    • Journal Title

      Proc. Nat. Acad. Sci. USA.

      Volume: 113 Issue: 44

    • DOI

      10.1073/pnas.1608888113

    • NAID

      130005974889

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] In situ observation of ice crystal growth inside quasi-liquid layers2019

    • Author(s)
      Ken-ichiro Murata
    • Organizer
      IMS symposium "Water at interfaces 2018"
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 氷-水成長界面におけるステップダイナミクス2019

    • Author(s)
      村田 憲一郎
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Why is the surface of ice wet?2018

    • Author(s)
      Ken-ichiro Murata
    • Organizer
      Water on Materials Surface 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高分解光学顕微鏡で見る氷-水成長・融解界面の構造とダイナミクス2018

    • Author(s)
      村田 憲一郎
    • Organizer
      第47回結晶成長国内会議
    • Related Report
      2018 Annual Research Report
  • [Presentation] In situ observation of ice-water interfaces by advanced optical microscopy2018

    • Author(s)
      Ken-ichiro Murata
    • Organizer
      14th International Conference on the Physics and Chemistry of Ice
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分解光学顕微鏡で見る氷-水成長・融解界面の構造とダイナミクス2018

    • Author(s)
      村田憲一郎
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 氷結晶上における擬似液体層の濡れダイナミクス2017

    • Author(s)
      村田 憲一郎
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学 豊中キャンパス(大阪府 豊中市)
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] 氷の表面融解における新しい熱力学的起源2017

    • Author(s)
      村田憲一郎
    • Organizer
      2017年真空・表面科学合同講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高分解光学顕微鏡による結晶 融液界面のその場観察2017

    • Author(s)
      村田憲一郎
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高分解光学顕微鏡による氷-水成長・融 解界面のその場観察2017

    • Author(s)
      村田憲一郎
    • Organizer
      第46回結晶成長国内会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 氷の表面融解における新しい熱力学的起源2016

    • Author(s)
      村田 憲一郎
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館(神奈川県 横浜市)
    • Year and Date
      2016-12-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 氷表面上における擬似液体層の濡れダイナミクス:顕微鏡その場観察による擬似液体層の物性測定2016

    • Author(s)
      村田 憲一郎
    • Organizer
      日本物理学会 2016年秋季大会領域9シンポジウム :表面界面ナノ構造のその場観察
    • Place of Presentation
      金沢大学 角間キャンパス(石川県 金沢市)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 氷結晶における表面融解の新しい熱力学的起源2016

    • Author(s)
      村田 憲一郎
    • Organizer
      公益社団法人日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス(広島県 東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] A simple physical model of surface melting on ice crystals2016

    • Author(s)
      Ken-ichiro Murata
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy
    • Place of Presentation
      Nagoya Congress Center(愛知県 名古屋市)
    • Year and Date
      2016-08-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2020-03-30  

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