• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Electrochemical etching approarch to ultrathin films

Research Project

Project/Area Number 16H05981
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTohoku University

Principal Investigator

Shiogai Junichi  東北大学, 金属材料研究所, 助教 (30734066)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥26,650,000 (Direct Cost: ¥20,500,000、Indirect Cost: ¥6,150,000)
Fiscal Year 2017: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2016: ¥22,620,000 (Direct Cost: ¥17,400,000、Indirect Cost: ¥5,220,000)
Keywords層状物質 / カルコゲナイド物質 / 超伝導 / 電気化学反応 / 電気二重層トランジスタ / セレン化鉄 / 電気化学エッチング / 高温超伝導 / 薄膜新材料
Outline of Final Research Achievements

Electrochemical etching technique has been applied to layered materials in electric-double layer transistor. Exotic physical properties, absent in bulk form, are expected to emerge in ultrathin limit. A one of the typical examples is layered superconducting iron selenide (FeSe), with superconducting transition temperature (Tc) of 8 K in bulk. The monolayer-thick FeSe exhibits high-Tc at 65 K as discovered by spectroscopic measurements. In this work, we applied electrochemical etching to FeSe films to reveal superconducting critical parameters in high-Tc state in ultrathin limit. We found that the isotropic upper critical field (Hc2) in bulk FeSe is converted to highly anisotropy one in high-Tc state. Based on Ginzburg-Landau model, anisotropic Hc2 exhibits three-dimensional nature rather than two dimensional one, which indicates strong confinement of Cooper pair within FeSe sheet. We consider that this confinement effect stabilizes the high-Tc state of FeSe in monolayer-thick limit.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • Research Products

    (16 results)

All 2018 2017 2016 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 8 results,  Invited: 6 results) Remarks (1 results)

  • [Journal Article] Critical current enhancement driven by suppression of superconducting fluctuation in ion-gated ultrathin FeSe2018

    • Author(s)
      Harada T、Shiogai J、Miyakawa T、Nojima T、Tsukazaki A
    • Journal Title

      Superconductor Science and Technology

      Volume: 31 Issue: 5 Pages: 055003-055003

    • DOI

      10.1088/1361-6668/aab4ea

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of superconducting transition temperature in FeSe electric-double-layer transistor with multivalent ionic liquids2018

    • Author(s)
      Tomoki Miyakawa, Junichi Shiogai, Sunao Shimizu, Michio Matsumoto, Yukihiro Ito, Takayuki Harada, Kohei Fujiwara, Tsutomu Nojima, Yoshimitsu Itoh, Takuzo Aida, Yoshihiro Iwasa, Atsushi Tsukazaki
    • Journal Title

      Phys. Rev. Materials

      Volume: 2 Issue: 3 Pages: 031801-031801

    • DOI

      10.1103/physrevmaterials.2.031801

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of tetragonal FeSe/FeS alloy films with high sulfur contents by alternate deposition2017

    • Author(s)
      Fujiwara Kohei、Shiogai Junichi、Tsukazaki Atsushi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 10 Pages: 100308-100308

    • DOI

      10.7567/jjap.56.100308

    • NAID

      210000148314

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Unified trend of superconducting transition temperature versus Hall coefficient for ultrathin FeSe films prepared on different oxide substrates2017

    • Author(s)
      Junichi Shiogai, Tomoki Miyakawa, Yukihiro Ito, Tsutomu Nojima, and Atsushi Tsukazaki
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 11 Pages: 115101-115101

    • DOI

      10.1103/physrevb.95.115101

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical-Etching Approach to Achieving Ultrathin FeSe Films2016

    • Author(s)
      塩貝 純一, 野島 勉, 塚﨑 敦
    • Journal Title

      Hyomen Kagaku

      Volume: 37 Issue: 11 Pages: 541-546

    • DOI

      10.1380/jsssj.37.541

    • NAID

      130005284288

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] A universal trend in Hall coefficient and superconducting transition temperature in FeSe electric double layer transistors2018

    • Author(s)
      J. Shiogai, T. Miyakawa, T. Harada, T. Nojima, A. Tsukazaki
    • Organizer
      APS March Meeting 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A universal relationship of superconducting transition temperature and Hall coefficient in etching-induced superconductivity in FeSe electric double layer transistors2017

    • Author(s)
      J. Shiogai, T. Miyakawa, T. Nojima, and A. Tsukazaki
    • Organizer
      CEMS-QPEC Symposium on Emergent Quantum Materials
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電気化学エッチングを用いたFeSe薄膜高温超伝導2017

    • Author(s)
      塩貝純一、宮川智樹、伊藤恭太、野島勉、塚﨑敦
    • Organizer
      日本物理学会・第72回年次大会
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Invited
  • [Presentation] High-temperature superconductivity in ion-gated ultrathin FeSe films2017

    • Author(s)
      J. Shiogai, T. Miyakawa, Y. Ito, T. Nojima, and A. Tsukazaki
    • Organizer
      IUMRS-ICAM 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrochemical etching induced high temperature superconductivity in FeSe electric double layer transistors2016

    • Author(s)
      J. Shiogai, T. Miyakawa, Y. Ito, T. Nojima, and A. Tsukazaki
    • Organizer
      ISS 2016 - 29th International Symposium on Superconductivity
    • Place of Presentation
      東京国際フォーラム(東京都千代田区)
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrochemical approach to achieving ultrathin FeSe using electric double layer transistor2016

    • Author(s)
      J. Shiogai, T. Miyakawa, Y. Ito, T. Mitsuhashi, T. Nojima, and A. Tsukazaki
    • Organizer
      2016 MRS Fall Meeting
    • Place of Presentation
      ボストン(米国)
    • Year and Date
      2016-11-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electrochemical etching approach to ultrathin FeSe films using electric double layer transistor2016

    • Author(s)
      J. Shiogai, T. Miyakawa, Y. Ito, T. Nojima and A. Tsukazaki
    • Organizer
      JSPS-EPSRC Tohoku-Cambridge-CNRS Core to Core program Symposium "Two dimensional electronics/spintronics devices"
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High temperature superconductivity in electrochemically-etched FeSe thin films2016

    • Author(s)
      J. Shiogai, T. Miyakawa, Y. Ito, T. Mitsuhashi, T. Nojima, and A. Tsukazaki
    • Organizer
      International Symposium on Revolutionary Atomic-Layer Materials
    • Place of Presentation
      東北大学(宮城県仙台市)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] FeSe EDLTで誘起される超伝導転移のイオン液体依存性2016

    • Author(s)
      宮川智樹、伊藤恭太、塩貝純一、野島勉、松本道生、清水直、岩佐義宏、相田卓三、塚﨑敦
    • Organizer
      日本物理学会・2016年秋季大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] High-Tc Superconductivity at 40 K observed in electrochemically etched FeSe films2016

    • Author(s)
      J. Shiogai, Y. Ito, T. Mitsuhashi, T. Nojima, and A. Tsukazaki
    • Organizer
      ICSM 2016 - The 5th International Conference of Superconductivity and Magnetism
    • Place of Presentation
      フェトヒイェ(トルコ共和国)
    • Year and Date
      2016-04-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks]

    • URL

      http://mu.imr.tohoku.ac.jp/memberlist_shiogai.html

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi