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Real-time operando observation of plasmonic chemical reactions using time-resolved ambient pressure X-ray photoelectron spectroscopy

Research Project

Project/Area Number 16H06027
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Yamamoto Susumu  東京大学, 物性研究所, 助教 (50554705)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥25,740,000 (Direct Cost: ¥19,800,000、Indirect Cost: ¥5,940,000)
Fiscal Year 2018: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2017: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2016: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Keywords触媒反応 / プラズモン / オペランド / 時間分解 / 放射光
Outline of Final Research Achievements

This study aimed to study plasmonic chemical reactions in real-time and in operando conditions using a newly-developed time-resolved ambient pressure X-ray photoelectron spectroscopy. At the interface of Au nanoparticle and TiO2 which is one of the representative plasmonic nano-materials, I have succeeded in monitoring carrier injection from Au nanoparticles that are excited by a plasmon resonance to the TiO2 substrate in real time. In addition, I have developed time-resolved ambient pressure X-ray photoelectron spectroscopy and have succeeded in the first test measurement.

Academic Significance and Societal Importance of the Research Achievements

本研究により開発された時間分解雰囲気X線光電子分光法は、光励起物質中におけるキャリア(電子、ホール)の動きをサイト選択的に追跡することを可能にする。また、本研究手法はプラズモニック化学反応だけでなく、太陽電池や人工光合成材料といった様々なエネルギー変換材料に適用可能で、これらのエネルギー変換過程の高効率化を実現する学理構築への貢献が期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Journal Article (9 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (18 results) (of which Int'l Joint Research: 6 results,  Invited: 6 results) Remarks (2 results)

  • [Journal Article] Direct Evidence of Interfacial Hydrogen Bonding in Proton-Electron Concerted 2D Organic Bilayer on Au Substrate2019

    • Author(s)
      Yamamoto Susumu、Kato Hiroyuki S.、Ueda Akira、Yoshimoto Shinya、Hirata Yasuyuki、Miyawaki Jun、Yamamoto Kohei、Harada Yoshihisa、Wadati Hiroki、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 17 Issue: 0 Pages: 49-55

    • DOI

      10.1380/ejssnt.2019.49

    • NAID

      130007638859

    • ISSN
      1348-0391
    • Year and Date
      2019-04-27
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] CO2 Activation and Reaction on Zn-Deposited Cu Surfaces Studied by Ambient-Pressure X-ray Photoelectron Spectroscopy2019

    • Author(s)
      Koitaya Takanori、Yamamoto Susumu、Shiozawa Yuichiro、Yoshikura Yuki、Hasegawa Masahiro、Tang Jiayi、Takeuchi Kaori、Mukai Kozo、Yoshimoto Shinya、Matsuda Iwao、Yoshinobu Jun
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 5 Pages: 4539-4550

    • DOI

      10.1021/acscatal.9b00041

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mass transport in the PdCu phase structures during hydrogen adsorption and absorption studied by XPS under hydrogen atmosphere2019

    • Author(s)
      Tang Jiayi、Yamamoto Susumu、Koitaya Takanori、Yoshigoe Akitaka、Tokunaga Takuma、Mukai Kozo、Matsuda Iwao、Yoshinobu Jun
    • Journal Title

      Applied Surface Science

      Volume: 480 Pages: 419-426

    • DOI

      10.1016/j.apsusc.2019.02.180

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhanced Photoresponsivity of Fullerene in the Presence of Phthalocyanine: A Time-Resolved X-ray Photoelectron Spectroscopy Study of Phthalocyanine/C60/TiO2(110)2019

    • Author(s)
      Kenichi Ozawa, Susumu Yamamoto, Marie D'angelo, Yuto Natsui, Naoya Terashima, Kazuhiko Mase, and Iwao Matsuda
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 7 Pages: 4388-4395

    • DOI

      10.1021/acs.jpcc.9b00186

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrogen adsorption and absorption on a Pd-Ag alloy surface studied using in-situ X-ray photoelectron spectroscopy under ultrahigh vacuum and ambient pressure2019

    • Author(s)
      Tang Jiayi、Yamamoto Susumu、Koitaya Takanori、Yoshikura Yuki、Mukai Kozo、Yoshimoto Shinya、Matsuda Iwao、Yoshinobu Jun
    • Journal Title

      Applied Surface Science

      Volume: 463 Pages: 1161-1167

    • DOI

      10.1016/j.apsusc.2018.07.078

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interfacial carrier dynamics of graphene on SiC, traced by the full-range time-resolved core-level photoemission spectroscopy2018

    • Author(s)
      Someya T.、Fukidome H.、Endo N.、Takahashi K.、Yamamoto S.、Matsuda I.
    • Journal Title

      Applied Physics Letters

      Volume: 113 Issue: 5 Pages: 051601-051601

    • DOI

      10.1063/1.5043223

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of CO2 adsorption on oxygen-functionalized epitaxial graphene surface under near-ambient conditions2018

    • Author(s)
      Yamamoto Susumu、Takeuchi Kaori、Hamamoto Yuji、Liu Ro-Ya、Shiozawa Yuichiro、Koitaya Takanori、Someya Takashi、Tashima Keiichiro、Fukidome Hirokazu、Mukai Kozo、Yoshimoto Shinya、Suemitsu Maki、Morikawa Yoshitada、Yoshinobu Jun、Matsuda Iwao
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 29 Pages: 19532-19538

    • DOI

      10.1039/c8cp03251c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Controlling the surface photovoltage on WSe2 by surface chemical modification2018

    • Author(s)
      Liu Ro-Ya、Ozawa Kenichi、Terashima Naoya、Natsui Yuto、Feng Baojie、Ito Suguru、Chen Wei-Chuan、Cheng Cheng-Maw、Yamamoto Susumu、Kato Hiroo、Chiang Tai-Chang、Matsuda Iwao
    • Journal Title

      Applied Physics Letters

      Volume: 112 Issue: 21 Pages: 211603-211603

    • DOI

      10.1063/1.5026351

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Correlation between Photocatalytic Activity and Carrier Lifetime: Acetic Acid on Single-Crystal Surfaces of Anatase and Rutile TiO22018

    • Author(s)
      Kenichi Ozawa, Susumu Yamamoto, Ryu Yukawa, Ro-Ya Liu, Naoya Terashima, Yuto Natsui, Hiroo Kato, Kazuhiko Mase, and Iwao Matsuda
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 17 Pages: 9562-9569

    • DOI

      10.1021/acs.jpcc.8b02259

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Presentation] シリカ担持ニッケル触媒表面におけるサバティエ反応の軟X線オペランド観測2019

    • Author(s)
      山本達、 宮脇淳、 唐佳藝、 小板谷貴典、 徳永拓馬、 柴田悠宇、 小瀬川友香、 山添康介、 向井孝三、 吉本真也、 吉信淳、 松田巌、
    • Organizer
      第32回放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] オペランド軟X線分光を用いた触媒研究:現状と次世代放射光施設における展望2018

    • Author(s)
      山本達
    • Organizer
      物性研究所短期研究会「軟X線放射光科学のアップシフト」
    • Related Report
      2018 Annual Research Report
  • [Presentation] オペランド軟X線分光を用いた触媒研究の現状と将来展望2018

    • Author(s)
      山本達
    • Organizer
      2018年日本表面真空学会学術講演会 放射光表面科学研究部会セッション「最先端放射光表面科学の現状と新3GeV光源における研究展望」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 放射光を利用した表面分析2018

    • Author(s)
      山本達
    • Organizer
      第66回 表面科学基礎講座「表面・界面分析の基礎と応用」
    • Related Report
      2018 Annual Research Report
  • [Presentation] Sabatier reaction on a Ni/SiO2 catalyst studied by operando soft X-ray spectroscopies2018

    • Author(s)
      S. Yamamoto、 J. Miyawaki、 J. Tang、 T. Koitaya、 T. Tokunaga、 Y. Shibata、 Y. Kosegawa、 K. Yamazoe、 K. Mukai、 S. Yoshimoto、 Y. Harada、 J. Yoshinobu、 I. Matsuda、
    • Organizer
      The 14th International Conference on Electronic Spectroscopy and Structure (ICESS-14)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 反応中の触媒をみる-軟X線オペランド分光による化学状態分析-2018

    • Author(s)
      山本達
    • Organizer
      SPring-8ユーザー協同体顕微ナノ材料科学研究会・日本表面科学会放射光表面科学研究部会・日本表面科学会プローブ顕微鏡研究部会 合同シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] シリカ担持ニッケル触媒表面におけるサバティエ反応の軟X線オペランド観測2018

    • Author(s)
      山本達, 唐佳芸, 小板谷貴典, 徳永拓馬, 柴田悠宇, 向井孝三, 吉本真也, 吉信淳, 松田巌,
    • Organizer
      日本物理学会第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] オペランド軟X線分光の高度化・協奏が拓く触媒科学2018

    • Author(s)
      山本達, 原田慈久, 松田巌, 吉信淳,
    • Organizer
      ISSP workshop「SPring-8 BL07LSUの現状と次世代軟X線科学創成への戦略」
    • Related Report
      2017 Annual Research Report
  • [Presentation] プラズモンナノ材料におけるキャリアダイナミクスの実時間観測:時間分解軟X線光電子分光法による研究2018

    • Author(s)
      山本達, 小澤健一, 寺島矢, 夏井祐人, M. D'Angelo, 加藤博雄, 松田巌,
    • Organizer
      第31回放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] VUV・軟X線光源を用いた物質科学研究の現状と展望2017

    • Author(s)
      山本達
    • Organizer
      物質構造科学研究所 設立20周年記念シンポジウム「物質構造科学の過去・現在・未来」
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Adsorption and reaction of CO2 on graphene studied by ambient pressure XPS2017

    • Author(s)
      S. Yamamoto, K. Takeuchi, R.-Y. Liu, Y. Shiozawa, T. Koitaya, T. Someya, K. Tashima, H. Fukidome, K. Mukai, S. Yoshimoto, M. Suemitsu, J. Yoshinobu, I. Matsuda,
    • Organizer
      The 5th Ito International Research Conference "Forefront of Molecular Dynamics at Surfaces and Interfaces: From a single molecule to catalytic reaction"
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorption and reaction of CO2 on graphene studied by ambient pressure XPS2017

    • Author(s)
      S. Yamamoto, K. Takeuchi, R.-Y. Liu, Y. Shiozawa, T. Koitaya, T. Someya, K. Tashima, H. Fukidome, K. Mukai, S. Yoshimoto, M. Suemitsu, J. Yoshinobu, I. Matsuda,
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Adsorption and reaction of CO2 on graphene studied by ambient pressure XPS2017

    • Author(s)
      S. Yamamoto, K. Takeuchi, R.-Y. Liu, Y. Shiozawa, T. Koitaya, T. Someya, K. Tashima, H. Fukidome, K. Mukai, S. Yoshimoto, M. Suemitsu, J. Yoshinobu, I. Matsuda,
    • Organizer
      33rd European Conference on Surface Science (ECOSS-33)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] オペランド軟X線分光の高度化・協奏が拓く触媒科学2017

    • Author(s)
      山本達, 原田慈久, 松田巌, 吉信淳
    • Organizer
      ISSP workshop「SPring-8 BL07LSUが照らしだす物質機能の起源」
    • Place of Presentation
      東京大学物性研究所(千葉県柏市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 放射光軟X線光電子分光法を用いた表面キャリア・分子ダイナミクス研究2017

    • Author(s)
      山本達
    • Organizer
      第1回表界面計測技術研究会-電子と光子をプローブとした表界面計測-
    • Place of Presentation
      湘南国際村センター(神奈川県三浦郡)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Tracking photo-excited carriers on semiconductor surfaces by VUV and soft X-ray pulses2016

    • Author(s)
      S. Yamamoto
    • Organizer
      8th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications (ASOMEA-VIII)
    • Place of Presentation
      Okazaki Conference Center (Okazaki, Aichi)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 放射光軟X線光電子分光法を用いた表面キャリア・分子ダイナミクス研究2016

    • Author(s)
      山本達
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Tracking photo-excited carriers on semiconductor surfaces by VUV and soft X-ray pulses2016

    • Author(s)
      S. Yamamoto
    • Organizer
      Workshop "Fundamental X-ray Science and its Application to Catalysis and Water Research: Future Directions"
    • Place of Presentation
      Stockholm university (Stockholm, Sweden)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 山本達研究用HP

    • URL

      http://www.issp.u-tokyo.ac.jp/labs/sor/s-yamamoto/

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
  • [Remarks] 山本達研究用ホームページ

    • URL

      http://www.issp.u-tokyo.ac.jp/labs/sor/s-yamamoto/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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