| Budget Amount *help |
¥26,130,000 (Direct Cost: ¥20,100,000、Indirect Cost: ¥6,030,000)
Fiscal Year 2018: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2016: ¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
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| Outline of Final Research Achievements |
We performed a creation and exploration of porous materials that can adsorb molecules by light energy based on porous coordination polymers (PCP) composed of metal ions and organic ligands. We have succeeded to obtain new compounds that could transform their structure by the light stimulation, and their adsorption functions were able to be controlled as well. In addition, we synthesized new materials in which highly active species such as carbenes could be generated in the nanospace by light stimulation. It was found that these materials could selectively adsorb molecules owing to the interaction between the active species and guest molecules. Consequently, we found that it is possible to design nanospace-materials that adsorb molecules by light as well as the operation of temperature or pressure.
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