Creation of light and adsorption energy transformation materials utilizing dynamic properties of the metal complex nanospaces
| Project/Area Number |
16H06032
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Single-year Grants |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Research Collaborator |
Sato Hiroshi
Sato Osamu
Kosaka Wataru
Tanaka Hideki
Takata Masaki
Hori Akihiro
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥26,130,000 (Direct Cost: ¥20,100,000、Indirect Cost: ¥6,030,000)
Fiscal Year 2018: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2017: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2016: ¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
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| Keywords | ナノ空間 / 多孔性材料 / 金属錯体 / 配位高分子 / 吸着 / 光反応 / ナノポーラス金属錯体 / 光 / 多孔体 / 吸着熱 / ナノポーラス錯体 / 多孔性金属錯体 / MOF / エネルギー変換 / 光応答 / 錯体 |
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| Outline of Final Research Achievements |
We performed a creation and exploration of porous materials that can adsorb molecules by light energy based on porous coordination polymers (PCP) composed of metal ions and organic ligands. We have succeeded to obtain new compounds that could transform their structure by the light stimulation, and their adsorption functions were able to be controlled as well. In addition, we synthesized new materials in which highly active species such as carbenes could be generated in the nanospace by light stimulation. It was found that these materials could selectively adsorb molecules owing to the interaction between the active species and guest molecules. Consequently, we found that it is possible to design nanospace-materials that adsorb molecules by light as well as the operation of temperature or pressure.
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| Academic Significance and Societal Importance of the Research Achievements |
分子や物質の分離操作には大量のエネルギーが消費されており、分子分離を効率化する材料や、プロセスの開発は、産業の省エネルギー化に大きく貢献するものです。多孔性材料は小分子の吸着分離が可能な機能性物質として、私たちの身の回りで広く用いられています。従って、新しい多孔性材料を開発し、新しい分子分離機能の開拓を行うことは、省エネルギー社会の実現のために非常に重要なものといえます。分子吸着は従来、温度や圧力を操作して行うものでしたが、本研究では光に着目し、光で分子の吸着を行う物質の開発に成功しました。本物質で新しい分子分離システムの構築が可能なものと期待されます。
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Report
(4 results)
Research Products
(103 results)
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[Journal Article] Density Gradation of Open Metal Sites in the Mesospace of Porous Coordination Polymers2017
Author(s)
Jingui Duan, Masakazu Higuchi, Jiajia Zheng, Shin-ichiro Noro, I-Ya Chang, Kim Hyeon-Deuk, Simon Mathew, Shinpei Kusaka, Easan Sivaniah, Ryotaro Matsuda, Shigeyoshi Sakaki, and Susumu Kitagawa
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Journal Title
J. Am. Chem. Soc.
Volume: 139
Issue: 33
Pages: 11576-11583
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Constant Volume Gate-Opening by Freezing Rotational Dynamics in Microporous Organically Pillared Layered Silicates2017
Author(s)
Kilian Barwinkel, Markus M. Herling, Martin RieB, Hiroshi Sato, Liangchun Li, Yamini S. Avadhut, Tobias W. Kemnitzer, Hussein Kalo, Jurgen Senker, Ryotaro Matsuda, Susumu Kitagawa, Josef Breu
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Journal Title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume: 139
Issue: 2
Pages: 904-909
DOI
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Rhodium-Organic Cuboctahedra as Porous Solids with Strong Binding Sites2016
Author(s)
Furukawa Shuhei, Horike Nao, Kondo Mio, Hijikata Yuh, Carne-Sanchez Arnau, Larpent Patrick, Louvain Nicolas, Diring Stephane, Sato Hiroshi, Matsuda Ryotaro, Kawano Ryuji, Kitagawe Susumu
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Journal Title
INORGANIC CHEMISTRY
Volume: 55
Issue: 21
Pages: 10843-10846
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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