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Investigation on the behavior of anionic transition metal complexes and their application for the catalytic transformations

Research Project

Project/Area Number 16H06039
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionThe University of Tokyo (2018)
Osaka University (2016-2017)

Principal Investigator

Iwasaki Takanori  東京大学, 大学院工学系研究科(工学部), 准教授 (50550125)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥25,740,000 (Direct Cost: ¥19,800,000、Indirect Cost: ¥5,940,000)
Fiscal Year 2018: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2017: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Fiscal Year 2016: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Keywords遷移金属触媒 / アート型錯体 / 炭素ー炭素結合形成反応 / クロスカップリング反応 / 多成分連結反応 / クロスカップリング / 合成化学 / 有機金属化学 / ニッケル / コバルト / 鉄 / 銅 / 多成分反応 / C-F結合活性化 / アルキル化反応 / C-F結合 / パーフルオロアレーン
Outline of Final Research Achievements

We developed various catalytic systems which effectively promote cross-coupling reaction of alkyl halides with alkyl Grignard reagents to construct saturated hydrocarbon frameworks. As a functionalization of 1,3-butadiene, we developed internal carbon selective alkylation reaction by copper catalyst with alkyl fluorides. When Ni was used instead of Cu, dimerization and double functionalization by carbon nucleophiles and carbon electrophiles proceeded to give mulit component coupling products.
In these catalytic reactions, anionic transition metal complexes arising from transition metal complex with organometallic reagents were found to be the catalytic active species.

Academic Significance and Societal Importance of the Research Achievements

遷移金属触媒において「遷移金属をアニオン性錯体にする」というコンセプトのもと、高難度分子変換反応を実現した。従来の遷移金属触媒の多くは中性およびカチオン性の遷移金属錯体が用いられてきたが、これをアニオン性とし、対カチオンとの協同触媒効果を利活用することにより、炭素ーフッ素結合といった極めて結合切断が困難な化学結合すら有機合成化学に利用できることを明らかにした。さらに、この化学的に強固な結合を合成化学に利用することにより、従来手法では困難な合成戦略を提案することが可能である。
これらの成果は、新たな触媒設計指針として有機合成化学・触媒化学分野に貢献するものである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (70 results)

All 2018 2017 2016 Other

All Int'l Joint Research (6 results) Journal Article (14 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 13 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (43 results) (of which Int'l Joint Research: 13 results,  Invited: 12 results) Book (1 results) Remarks (6 results)

  • [Int'l Joint Research] Philipps-Universit¨at Marburg(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Hunan University(中国)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] CSIR-National Chemical Laboratory(インド)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Hunan University/Wenzhou University(中国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] CSIR-National Chemical Laboratory(インド)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Philipps-Universit¨at Marburg(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Nickel-Catalyzed Coupling Reaction of Alkyl Halides with Aryl Grignard Reagents in the Presence of 1,3-Butadiene: Mechanistic Studies of Four-Component Coupling and Competing Cross-Coupling Reactions2018

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Wataru Yokoyama, Xin Min, Ichiro Hisaki, Tao Yang, Masahiro Ehara, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Chem. Sci.

      Volume: 9 Issue: 8 Pages: 2195-2211

    • DOI

      10.1039/c7sc04675h

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents Catalyzed by Cp-Iron Complexes in the Presence of 1,3-Butadiene2018

    • Author(s)
      Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 6 Pages: 763-766

    • DOI

      10.1246/cl.180201

    • NAID

      130007384484

    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ni-Catalyzed Dimerization and Hydroperfluoroarylation of 1,3-Dienes2018

    • Author(s)
      Iwasaki Takanori、Min Xin、Fukuoka Asuka、Zhu Longzhi、Qiu Renhua、Yang Tao、Ehara Masahiro、Sudalai Arumugam、Kambe Nobuaki
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 83 Issue: 16 Pages: 9267-9277

    • DOI

      10.1021/acs.joc.8b01266

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Cyclopropane Fatty Acids by C(sp 3)?C(sp 3) Cross-Coupling Reaction and Formal Synthesis of α-Mycolic Acid2018

    • Author(s)
      Iwasaki Takanori、Terahigashi Shohei、Wang Yufei、Tanaka Arisa、Zhao Hanqing、Fujimoto Yukari、Fukase Koichi、Kambe Nobuaki
    • Journal Title

      Advanced Synthesis & Catalysis

      Volume: 360 Issue: 19 Pages: 3810-3817

    • DOI

      10.1002/adsc.201800901

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Cu-Catalyzed Reductive Coupling of Perfluoroarenes with 1,3-Dienes2017

    • Author(s)
      Takanori Iwasaki, Kanako Okamoto, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 10 Pages: 1504-1507

    • DOI

      10.1246/cl.170650

    • NAID

      130006140012

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents2017

    • Author(s)
      Takanori Iwasaki, Koji Yamashita, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Org. Lett.

      Volume: 19 Pages: 3691-3694

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nickel-Catalyzed Direct Alkylation of Thiophenes via Double C(sp3)-H/C(sp2)-H Bond Cleavage: The Importance of KH2PO42017

    • Author(s)
      Xie Wang, Peipei Xie, Renhua Qiu, Longzhi Zhu, Ting Liu, You Li, Takanori Iwasaki, Chak-Tong Au, Xinhua Xu, Yuanzhi Xia, Shuang-Feng Yin, and Nobuaki Kambe
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 59 Pages: 8316-8319

    • DOI

      10.1039/c7cc04252c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Intramolecular, Site-Selective, Iodine-Mediated, Amination of Unactivated (sp3)C-H Bonds for the Synthesis of Indoline Derivatives2017

    • Author(s)
      Jinguo Long, Xin Cao, Longzhi Zhu, Renhua Qiu, Chak-Tang Au, Shuang-Feng Yin, Takanori Iwasaki, and Nobuaki Kambe
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 11 Pages: 2793-2796

    • DOI

      10.1021/acs.orglett.7b00846

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, and Nobuaki
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 18 Pages: 5550-5554

    • DOI

      10.1002/ange.201601126

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 20 Pages: 2834-2837

    • DOI

      10.1002/asia.201600972

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex2016

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Xin Min, Wataru Yokoyama, Hitoshi Kuniyasu, and Nobuaki Kambe
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 19 Pages: 4868-4871

    • DOI

      10.1021/acs.orglett.6b02343

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ni-Catalyzed C-C Couplings Using Alkyl Electrophiles2016

    • Author(s)
      Takanori Iwasaki, and Nobuaki Kambe
    • Journal Title

      Top. Curr. Chem.

      Volume: 374 Issue: 5 Pages: 1-36

    • DOI

      10.1007/s41061-016-0067-6

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 光を用いてNiの酸化状態を制御する-Ni触媒を用いたクロスカップリング反応の新展開2016

    • Author(s)
      岩﨑孝紀,神戸宣明
    • Journal Title

      化学

      Volume: 71 Pages: 70-71

    • Related Report
      2016 Annual Research Report
  • [Journal Article] 極性転換が導く遷移金属の新機能-アニオン性有機金属化学種を活用する合成反応2016

    • Author(s)
      岩﨑孝紀
    • Journal Title

      化学と工業

      Volume: 69 Pages: 979-980

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] ニッケル触媒によるパーフルオロアレーン、ジエン、グリニャール試薬の多成分反応2018

    • Author(s)
      岩﨑孝紀、福岡明日香、閔 欣、横山 航、国安 均、神戸宣明
    • Organizer
      第16回次世代を担う有機化学シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] コバルト触媒によるフッ化アルキルとアルキルグリニャール試薬とのクロスカップリング反応―フッ素の特性を活かしたLate-Stageアルキル化2018

    • Author(s)
      岩﨑孝紀,山下晃司、国安均、神戸宣明
    • Organizer
      第113回有機合成シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Rh-catalyzed cross-coupling reaction of cyclic ethers with Grignard reagents via site-selective C-O bond cleavage2018

    • Author(s)
      石賀渉、岩﨑孝紀、神戸宣明
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Rh-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents via C-O bond cleavage: improvement of catalytic efficiency based on mechanistic study2018

    • Author(s)
      岩﨑孝紀、赤星百映、神戸宣明
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of an anionic diaryliridium(I) complex bearing COD ligand and its structure2018

    • Author(s)
      赤岩寿一、岩﨑孝紀、神戸宣明
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アニオン性ニッケル錯体による共役ジエンの多成分連結反応2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      第51回有機金属若手の会夏の学校
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] クロスカップリング反応による第四級炭素構築手法2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      第38回有機合成若手セミナー 明日の有機合成を担う人のために
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ニッケル触媒による炭素―フッ素結合の切断過程に関する理論研究2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      文部科学省ナノテクノロジープラットフォーム平成30年度利用成果発表会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ニッケル触媒によるブタジエンの新規活性化手法の開発と反応機構研究2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      分子・物質合成プラットフォーム 平成30年度 シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] アニオン性遷移金属錯体による触媒的クロスカップリングおよび多成分連結反応2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      早稲田大学
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] フッ化アルキルをアルキル化剤とする触媒反応ー炭素-フッ素結合の特徴を利用した分子変換反応ー2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      日本化学会第98春季年会(2018)Reaxys Prize Club シンポジウム in Japan 2018
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] フッ素の特徴を活かした触媒的炭素-炭素結合形成反応 -フッ素だから出来ること、フッ素にしか出来ないこと-2018

    • Author(s)
      岩﨑孝紀
    • Organizer
      近畿化学協会ヘテロ原子部会第3回懇話会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ロジウム触媒を用いた環状エーテルとグリニャール試薬とのクロスカップリング反応2018

    • Author(s)
      日本化学会第98春季年会(2018)
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] アニオン性ジアリールイリジウム錯体の合成と構造2018

    • Author(s)
      赤岩 寿一・岩﨑 孝紀・神戸 宜明
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
  • [Presentation] キラルアルコールを用いた有機亜鉛試薬のアルデヒドへの付加反応における不斉認識に関する研究2018

    • Author(s)
      西尾 美保・岩﨑 孝紀・神戸 宣明
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 銅およびニッケル触媒による1,3-ジエン類の位置選択的アルキル化反応2017

    • Author(s)
      岩﨑孝紀、清水良平、今西怜子、福岡明日香、閔欣、国安均、神戸宣明
    • Organizer
      日本薬学会第137年会
    • Place of Presentation
      宮城
    • Year and Date
      2017-03-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] ニッケル触媒を用いたパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンの多成分反応とその機構研究2017

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] コバルト触媒によるフッ化アルキルとアルキルグリニャール試薬とのクロスカップリング反応2017

    • Author(s)
      山下晃司、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Multicomponent Coupling Reaction of Alkyl Halides, Aryl Grignard Reagents, and Two Molecules of 1,3-Dienes Catalyzed by an Anionic Ni Complex2017

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Wataru Yokoyama, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fe-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents2017

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      Biotechnology and Chemistry for Green Growth
    • Place of Presentation
      Hyogo
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Alkyl Fluorides as Promising Alkylating Reagents for the Alkylation of 1,3-Dienes2017

    • Author(s)
      Takanori Iwasaki, Ryohei Shimizu, Reiko Imanishi, Asuka Fukuoka, Xin Min, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The 8th International Meeting on Halogen Chemistry (HALCHEM VIII)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nickel‐Catalyzed Multicomponent Coupling Reaction through Dimerization of 1,3‐ Dienes2017

    • Author(s)
      Takanori Iwasaki
    • Organizer
      International Symposium on Pure & Applied Chemistry 2017 (ISPAC 2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] フッ化アルキルを用いたジエンの触媒的アルキル化反応2017

    • Author(s)
      岩﨑孝紀、神戸宣明
    • Organizer
      第67回フッ素化学若手の会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Co-catalyzed Cross-coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents2017

    • Author(s)
      山下晃司、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第67回フッ素化学若手の会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ニッケル触媒による1,3-ブタジエン存在下におけるハロゲン化アルキルとアリールグリニャール試薬との反応における4成分およびクロスカップリング反応に関する機構研究2017

    • Author(s)
      岩﨑孝紀、福岡明日香、横山航、閔欣、タオヤン、江原正博、国安均、神戸宣明
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Co-catalyzed Cross-coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents2017

    • Author(s)
      山下晃司、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第64回有機金属化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Anionic Ni(II) Complex Promoted Multicomponent Coupling Reactions2017

    • Author(s)
      Takanori Iwasaki, Xin, Min, Asuka Fukuoka, Wataru Yokoyama, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      錯体化学会第67回討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nickel-Catalyzed Multicomponent Coupling Reaction of 1,3-Dienes2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Wataru Yokoyama, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      The 10th International Symposium on Integrated Synthesis (ISONIS-10)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-12-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ニッケル触媒によるパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンとの多成分反応2016

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第25回石油学会関西支部第61回日本エネルギー学会関西支部合同研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] ハロゲン化アルキルによるアレン類のアルキル化反応2016

    • Author(s)
      佐々木惟莉亜、岩﨑孝紀、国安均、神戸宣明
    • Organizer
      第25回石油学会関西支部第61回日本エネルギー学会関西支部合同研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fe-catalyzed cross-coupling reaction of vinylic ethers with aryl Grignard reagents2016

    • Author(s)
      Takanori Iwasaki, Ryo Akimoto, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nickel-catalyzed multicomponent reaction of perfluoroarenes, aryl Grignard reagents, and two molecules of 1,3-butadiene2016

    • Author(s)
      Wataru Yokoyama, Asuka Fukuoka, Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co-catalyzed cross-coupling reaction of alkyl fluorides with alkyl Grignard reagents2016

    • Author(s)
      Koji Yamashita, Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      International Symposium on C-O Activation (ISCO 2016)
    • Place of Presentation
      Hyogo
    • Year and Date
      2016-10-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ニッケル触媒による二量化を伴った1,3-ジエンのアルキルアリール化反応2016

    • Author(s)
      岩﨑孝紀、閔欣、福岡明日香、国安 均、神戸宣明
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ニッケル触媒による1,3-ブタジエンの二量化を伴ったパーフルオロアレーン、アリールグリニャール試薬、1,3-ブタジエンとの多成分反応2016

    • Author(s)
      横山航、福岡明日香、閔欣、岩﨑孝紀、国安 均、神戸宣明
    • Organizer
      第63回有機金属化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Asuka Fukuoka, Xin Min, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      Joint Symposium Aachen-Osaka
    • Place of Presentation
      Aachen, Germany
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Alkylation reactions based on nucleophilic activation of unsaturated hydrocarbons by anionic transition-metal complexes2016

    • Author(s)
      Takanori Iwasaki
    • Organizer
      OC-Kolloquium, RWTU Aachen
    • Place of Presentation
      RWTU Aachen (Germany)
    • Year and Date
      2016-09-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents2016

    • Author(s)
      Takanori Iwasaki, Xin Min, Asuka Fukuoka, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Nickel-Catalyzed Multicomponent Reaction of Perfluoroarenes, Aryl Grignard Reagents, and 1,3-Butadiene through Dimerization of 1,3-Butadiene2016

    • Author(s)
      Wataru Yokoyama, Asuka Fukuoka, Xin Min, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Tertiary Alkyl Grignard Reagents2016

    • Author(s)
      Koji Yamashita, Takanori Iwasaki, Hitoshi Kuniyasu, Nobuaki Kambe
    • Organizer
      20th International Symposium on Homogeneous Catalysis
    • Place of Presentation
      Kyoto
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ブタジエンのα―オレフィンへの触媒的変換手法の開発2016

    • Author(s)
      岩﨑孝紀、神戸宣明
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      兵庫
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] ニッケル触媒による二量化を伴った1,3-ジエンのアルキルアリール化反応2016

    • Author(s)
      岩﨑孝紀、閔欣、福岡明日香、国安 均、神戸宣明
    • Organizer
      第109回有機合成シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Catalytic C-H Bond Functionalization Using Dichalcogenides and Chalcogenophenes2016

    • Author(s)
      Takanori Iwasaki, Vutukuri Prakash Reddy, Renhua Qiu, Nobuaki Kambe
    • Organizer
      The 13th International Conference on the Chemistry of Selenium and Tellurium
    • Place of Presentation
      Gifu
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] 触媒化学 ―基礎から応用まで2017

    • Author(s)
      田中 庸裕、山下 弘巳、薩摩 篤、町田 正人、宍戸 哲也、神戸 宣明、岩崎 孝紀、江原 正博、森 浩亮、三浦 大樹
    • Total Pages
      288
    • Publisher
      講談社
    • ISBN
      4061568116
    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/member/biography_iwasaki.html

    • Related Report
      2018 Annual Research Report
  • [Remarks]

    • URL

      http://park.itc.u-tokyo.ac.jp/nozakilab/publication/publist_iwasaki.html

    • Related Report
      2018 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.eng.osaka-u.ac.jp/ibmt/index.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] 所属研究室HP

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~catsyn/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 所属機関若手研究者による研究組織

    • URL

      http://www.chem.eng.osaka-u.ac.jp/ibmt/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 所属研究室のHP

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~catsyn/

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2022-08-05  

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