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Stacking Structure-dependent Photovoltaic Performance of Multilayer Thin Films Composed of Multinary Solid Solution Quantum Dots

Research Project

Project/Area Number 16H06052
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionNagoya University

Principal Investigator

Kameyama Tatsuya  名古屋大学, 工学研究科, 助教 (40646759)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2018: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2017: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2016: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
Keywords量子ドット / 半導体ナノ粒子 / 太陽電池 / エネルギー移動 / 近赤外応答 / 配列制御 / ナノ構造制御 / 発光材料 / 固溶体 / 光エネルギー変換 / ナノ粒子 / 半導体 / 配列構造
Outline of Final Research Achievements

Research on quantum dot solar cells is currently actively conducted around the world for the efficient use of solar energy. In this study, we changed the composition of solid solution type quantum dots such as ZnSe-AgInSe2 and prepared the quantum dot thin film structure while controlling the arrangement of energy gap of them. As a result, excitons were collected on the charge separation interface of the thin film via energy transfer, and the photoenergy conversion efficiency were improved by the exciton collection mechanism along the gradient of the energy gap. Such a system is expected to approach the high theoretical conversion efficiency of quantum dot solar cells.

Academic Significance and Societal Importance of the Research Achievements

エネルギー問題解決に向けて、太陽光エネルギーの効率的な利用が求められている。特に、高い理論効率が期待されている量子ドット太陽電池であるが、実デバイスとしての変換効率は低く、理論効率に近づけるための検討が求められている。本研究では、これを達成するため光合成系に似たエネルギー移動による光捕集機構を、量子ドットを配列させることにより構築することとした。薄膜太陽電池にこのようなメカニズムを導入することは新しく、学術的な興味も大きい。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (18 results)

All 2019 2018 2017 2016 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (14 results) (of which Int'l Joint Research: 7 results,  Invited: 5 results) Remarks (1 results)

  • [Journal Article] Advances in Colloidal I-III-VI<sub>2</sub>-Based Semiconductor Quantum Dots toward Tailorable Photofunctional Materials2018

    • Author(s)
      Kameyama, T
    • Journal Title

      Electrochemistry

      Volume: 86 Issue: 6 Pages: 291-297

    • DOI

      10.5796/electrochemistry.18-6-E2670

    • NAID

      130007504984

    • ISSN
      1344-3542, 2186-2451
    • Year and Date
      2018-11-05
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Photocatalytic Activity of Zn-Ag-In-S Semiconductor Nanocrystals with a Dumbbell-Shaped Heterostructure2018

    • Author(s)
      Tatsuya Kameyama, Seiya Koyama, Takahisa Yamamoto, Susumu Kuwabata, and Tsukasa Torimoto
    • Journal Title

      J. Phys. Chem. C

      Volume: 印刷中 Issue: 25 Pages: 13705-13715

    • DOI

      10.1021/acs.jpcc.8b00255

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rod-Shaped Zn-Ag-In-Te Nanocrystals with Wavelength-Tunable Band-Edge Photoluminescence in the Near-IR Region2018

    • Author(s)
      Tatsuya Kameyama, Kouta Sugiura, Yujiro Ishigami, Takahisa Yamamoto, Susumu Kuwabata, Tomoki Okuhata, Naoto Tamai, and Tsukasa Torimoto
    • Journal Title

      J. Mater. Chem. C.

      Volume: 6 Issue: 8 Pages: 2034-2042

    • DOI

      10.1039/c7tc05624a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 近赤外発光する新規半導体量子ドットの開発とその発光波長制御究2019

    • Author(s)
      亀山達矢
    • Organizer
      第36回無機材料に関する最近の研究成果発表会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Photocatalytic H2 Evolution Activity of Dumbbell-shaped Nanocrystals Composed of ZnS-AgInS2 Solid Solution2018

    • Author(s)
      T. Kameyama, S. Koyama, T. Yamamoto, S. Kuwabata, T. Torimoto
    • Organizer
      Materials Challenges in Alternative and Renewable Energy 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ZnS-AgInS2ナノ粒子へのヘテロ接合界面導入と光触媒活性への影響2018

    • Author(s)
      亀山達矢, 小山晟也, 桑畑 進, 鳥本 司
    • Organizer
      第37回固体・表面光化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ZnSe-AgInSe2固溶体量子ドット積層薄膜太陽電池の光電変換特性2018

    • Author(s)
      鵜飼 元貴, 亀山 達矢, 桑畑 進, 鳥本 司
    • Organizer
      2018年電気化学秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Stacking Structure-dependent Photovoltaic Performance of Multilayer Thin Films Composed of ZnSe-AgInSe2 Solid Solution Quantum Dots2018

    • Author(s)
      Genki Ukai, Tatsuya Kameyama, Susumu Kuwabata, Tsukasa Torimoto
    • Organizer
      10th Asian Photochemistry Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Controlling Chemical Composition of Dumbbell-Shaped ZnS-AgInS2 Nanocrystals for Efficient Photocatalytic Hydrogen Evolution2018

    • Author(s)
      Tatsuya Kameyama, Seiya Koyama, Takahisa Yamamoto, Susumu Kuwabata, Tsukasa Torimoto
    • Organizer
      10th Asian Photochemistry Conference
    • Related Report
      2018 Annual Research Report
  • [Presentation] Preparation of Low-Toxic Zn-Ag-In-Te Quantum Dots with Tunable Near-IR Emission Toward Optical Applications2018

    • Author(s)
      Tatsuya Kameyama, K. Sugiura, Y. Ishigami, T. Yamamoto, S. Kuwabata, T. Okuhata, N. Tamai, T. Torimoto
    • Organizer
      The 5th Optical Manipulation Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高度な光利用を可能にする低毒性半導体量子ドットの開発2018

    • Author(s)
      亀山達矢
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ZnSe-AgInSe2固溶体量子ドット固定電極の集積構造制御と光電変換特性向上2018

    • Author(s)
      鵜飼元貴、亀山達矢、桑畑進、鳥本司
    • Organizer
      電気化学会第85回大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Preparation and Photoelectrochemical Properties of Low-Toxic Ag-based Quantum Dots for Photoenergy Conversion System2018

    • Author(s)
      Tatsuya Kameyama
    • Organizer
      Asia international symposium in CSJ
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ZnSe-AgInSe2固溶体量子ドットの配列構造化による 励起エネルギー捕集と光電変換特性の向上2017

    • Author(s)
      鵜飼元貴、亀山達矢、桑畑進、鳥本司
    • Organizer
      2017年電気化学秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Size-Controlled Synthesis of Near-IR-Light-Emitting AgInTe2 Nanocrystals for Biological Imaging2016

    • Author(s)
      T. Kameyama, Y. Ishigami, S. Kuwabata, T. Torimoto
    • Organizer
      220th ECS Meeting
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoluminescence and Photoelectrochemical Properties of ZnTe-AgInTe2 Solid Solution Nanocrystals2016

    • Author(s)
      T. Kameyama, K. Sugiura, S. Kuwabata, T. Torimoto
    • Organizer
      PRiME 2016
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Composition Dependent Photoluminescence of ZnTe-AgInTe2 Solid Solution Nanocrystals in Near-Infrared Light Region2016

    • Author(s)
      T. Kameyama, K. Sugiura, S. Kuwabata, T. Torimoto
    • Organizer
      IMSE 2016
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] 名古屋大学鳥本研HP

    • URL

      http://www.apchem.nagoya-u.ac.jp/06-K-6/torimoto/index.html

    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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