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Ionic liquid-type liquid electrolytes based on molten Li salt complexes

Research Project

Project/Area Number 16H06053
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionYokohama National University (2017-2019)
Yamaguchi University (2016)

Principal Investigator

Ueno Kazuhide  横浜国立大学, 大学院工学研究院, 准教授 (30637377)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥26,650,000 (Direct Cost: ¥20,500,000、Indirect Cost: ¥6,150,000)
Fiscal Year 2019: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2018: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2016: ¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Keywordsイオン液体 / リチウム二次電池 / 電解液 / 溶媒和イオン液体 / リチウムイオン輸率 / イオン伝導性 / 溶融錯体 / グライム / リチウム系二次電池 / 電解質 / リチウム系電池
Outline of Final Research Achievements

The purpose of this study is to propose a new design concept for liquid electrolytes of next-generation high-energy and high-power secondary batteries. In addition to establishing the concept of solvate ionic liquids, ionic conductivity of solvate ionic liquids was increases to that of conventional organic electrolytes with addition of low-polar and non-coordinating solvents. We also synthesized novel redox-active solvate ionic liquids composed solely of complex cations and anions, and semi-liquid type lithium secondary batteries were demonstrated with the redox-active solvate ionic liquids as catholyte. Furthermore, quasi-solid electrolytes of solvated ionic liquids were prepared by combining them with polymers and nanoparticles.

Academic Significance and Societal Importance of the Research Achievements

本研究では次世代高容量・高信頼性二次電池の実現に向けた新しい電解液の設計コンセプトを提案することを目的とした。具体例として、リチウム塩が高濃度で溶媒和と混合したリチウム塩溶媒和物の溶融状態を新しいイオン液体「溶媒和イオン液体」として捉え、従来の電解液との溶液構造的および機能的な類似点や相違点を実験的に明らかにした。これにより新たなイオン液体群としての溶媒和イオン液体の物性概念を各種実験パラメータによって整理した。また、この概念を元に、これまでにない新しい機能性電解液の設計指針を提案し、そのリチウム系二次電池としての優れた特性を示すことを明らかにした。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (33 results)

All 2020 2019 2018 2017 2016 2015 Other

All Journal Article (19 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 19 results,  Open Access: 10 results,  Acknowledgement Compliant: 4 results) Presentation (12 results) (of which Int'l Joint Research: 4 results,  Invited: 8 results) Remarks (2 results)

  • [Journal Article] Molten Li Salt Solvate-Silica Nanoparticle Composite Electrolytes with Tailored Rheological Properties2020

    • Author(s)
      MARIUM Mayeesha、UENO Kazuhide、DOKKO Kaoru、WATANABE Masayoshi
    • Journal Title

      Electrochemistry

      Volume: 88 Issue: 3 Pages: 174-177

    • DOI

      10.5796/electrochemistry.20-00016

    • NAID

      130007840150

    • ISSN
      1344-3542, 2186-2451
    • Year and Date
      2020-05-05
    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Redox-active glyme Li tetrahalogenoferrate(iii) solvate ionic liquids for semi-liquid lithium secondary batteries2020

    • Author(s)
      Kemmizaki Yuta、Katayama Yu、Tsutsumi Hiromori、Ueno Kazuhide
    • Journal Title

      RSC Advances

      Volume: 10 Issue: 7 Pages: 4129-4136

    • DOI

      10.1039/c9ra10149g

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ionic transport in highly concentrated lithium bis(fluorosulfonyl)amide electrolytes with keto ester solvents: structural implications for ion hopping conduction in liquid electrolytes2019

    • Author(s)
      Kondou Shinji、Thomas Morgan L.、Mandai Toshihiko、Ueno Kazuhide、Dokko Kaoru、Watanabe Masayoshi
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 21 Issue: 9 Pages: 5097-5105

    • DOI

      10.1039/c9cp00425d

    • NAID

      120006630604

    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Glyme?Li salt equimolar molten solvates with iodide/triiodide redox anions2019

    • Author(s)
      Shigenobu Keisuke、Nakanishi Azusa、Ueno Kazuhide、Dokko Kaoru、Watanabe Masayoshi
    • Journal Title

      RSC Advances

      Volume: 9 Issue: 39 Pages: 22668-22675

    • DOI

      10.1039/c9ra03580j

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Sulfolane-Based Highly Concentrated Electrolytes of Lithium Bis(trifluoromethanesulfonyl)amide: Ionic Transport, Li-Ion Coordination, and Li?S Battery Performance2019

    • Author(s)
      Nakanishi Azusa、Ueno Kazuhide、Watanabe Daiki、Ugata Yosuke、Matsumae Yoshiharu、Liu Jiali、Thomas Morgan L.、Dokko Kaoru、Watanabe Masayoshi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 123 Issue: 23 Pages: 14229-14238

    • DOI

      10.1021/acs.jpcc.9b02625

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Rheological and Ionic Transport Properties of Nanocomposite Electrolytes Based on Protic Ionic Liquids and Silica Nanoparticles2019

    • Author(s)
      Marium Mayeesha、Hoque Mahfuzul、Miran Muhammed Shah、Thomas Morgan L.、Kawamura Izuru、Ueno Kazuhide、Dokko Kaoru、Watanabe Masayoshi
    • Journal Title

      Langmuir

      Volume: 36 Issue: 1 Pages: 148-158

    • DOI

      10.1021/acs.langmuir.9b02848

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Redox Active Glyme-Li Salt Solvate Ionic Liquids Based on Tetrabromoferrate(III)2018

    • Author(s)
      Yuta Kemmizaki, Hiromori Tsutsumi, Kazuhide Ueno
    • Journal Title

      Electrochemistry

      Volume: 86 Issue: 2 Pages: 46-51

    • DOI

      10.5796/electrochemistry.17-00075

    • NAID

      130006434046

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2018 Annual Research Report 2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Soft materials based on colloidal self-assembly in ionic liquids2018

    • Author(s)
      Ueno Kazuhide
    • Journal Title

      Polymer Journal

      Volume: 50 Issue: 10 Pages: 951-958

    • DOI

      10.1038/s41428-018-0083-1

    • NAID

      120006812629

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced Electrochemical Stability of Molten Li Salt Hydrate Electrolytes by the Addition of Divalent Cations2018

    • Author(s)
      Kondou Shinji、Nozaki Erika、Terada Shoshi、Thomas Morgan L.、Ueno Kazuhide、Umebayashi Yasuhiro、Dokko Kaoru、Watanabe Masayoshi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 35 Pages: 20167-20175

    • DOI

      10.1021/acs.jpcc.8b06251

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] From Ionic Liquids to Solvate Ionic Liquids: Challenges and Opportunities for Next Generation Battery Electrolytes2018

    • Author(s)
      Watanabe Masayoshi、Dokko Kaoru、Ueno Kazuhide、Thomas Morgan L.
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 11 Pages: 1660-1682

    • DOI

      10.1246/bcsj.20180216

    • NAID

      130007511409

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Role of polar side chains in Li+ coordination and transport properties of polyoxetane-based polymer electrolytes2017

    • Author(s)
      Ryansu Sai , Kazuhide Ueno, Kenta Fujii , Yohei Nakano , Naho Shigaki and Hiromori Tsutsumi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 7 Pages: 51855194-51855194

    • DOI

      10.1039/c6cp08386b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices2017

    • Author(s)
      Masayoshi Watanabe, Morgan L. Thomas, Shiguo Zhang, Kazuhide Ueno, Tomohiro Yasuda, Kaoru Dokko
    • Journal Title

      Chem. Rev.

      Volume: 印刷中 Issue: 10 Pages: 7190-7239

    • DOI

      10.1021/acs.chemrev.6b00504

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Effect of Variation in Anion Type and Glyme Length on the Nanostructure of the Solvate Ionic Liquid/Graphite Interface as a Function of Potential2017

    • Author(s)
      Cook Andre、Ueno Kazuhide、Watanabe Masayoshi、Atkin Rob、Li Hua
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 29 Pages: 15728-15734

    • DOI

      10.1021/acs.jpcc.7b03414

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Steric effect on Li+ coordination and transport properties in polyoxetane-based polymer electrolytes bearing nitrile groups2017

    • Author(s)
      Sai Ryansu、Ueno Kazuhide、Fujii Kenta、Nakano Yohei、Tsutsumi Hiromori
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 60 Pages: 37975-37982

    • DOI

      10.1039/c7ra07636c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A Design Approach to Lithium-Ion Battery Electrolyte Based on Diluted Solvate Ionic Liquids2017

    • Author(s)
      Kazuhide Ueno, Junichi Murai, Heejoon Moon, Kaoru Dokko, and Masayoshi Watanabe
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 1 Pages: A6088-A6094

    • DOI

      10.1149/2.0121701jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Li+ local structure in hydrofluoroether diluted Li-glyme solvate ionic liquid2016

    • Author(s)
      Soshi Saito, Hikari Watanabe, Kazuhide Ueno, Toshihiko Mandai, Shiro Seki, Seiji Tsuzuki, Yasuo Kameda, Kaoru Dokko, Masayoshi Watanabe, Yasuhiro Umebayashi
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 120 Issue: 13 Pages: 3378-3387

    • DOI

      10.1021/acs.jpcb.5b12354

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Li+ local structure in Li-tetraglyme solvate ionic liquid revealed by neutron total scattering experiments with the 6/7Li isotopic substitution technique2016

    • Author(s)
      Soshi Saito, Hikari Watanabe, Yutaka Hayashi, Masaru Matsugami, Seiji Tsuzuki, Shiro Seki, Jose N Canongia Lopes, Rob Atkin, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe, Yasuo Kameda, Yasuhiro Umebayashi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 120 Issue: 14 Pages: 2832-2837

    • DOI

      10.1021/acs.jpclett.6b01266

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Categorizing Molten Salt Complexes as Ionic Liquids and Their Applications to Battery Electrolytes2016

    • Author(s)
      Kazuhide Ueno
    • Journal Title

      Electrochemistry

      Volume: 84 Issue: 9 Pages: 674-680

    • DOI

      10.5796/electrochemistry.84.674

    • NAID

      130005409021

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Li+ solvation and ionic transport in lithium solvate ionic liquids diluted by molecular solvents2015

    • Author(s)
      Kazuhide Ueno, Junichi Murai, Kohei Ikeda, Seiji Tsuzuki, Mizuho Tsuchiya, Ryoichi Tatara, Toshihiko Mandai, Yasuhiro Umebayashi, Kaoru Dokko, Masayoshi Watanabe
    • Journal Title

      J. Phys. Chem. C

      Volume: ASAP Issue: 29 Pages: 15792-15802

    • DOI

      10.1021/acs.jpcc.5b11642

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 溶媒和イオン液体及び高濃度電解液における Li イオン輸送特性支配因子2020

    • Author(s)
      重信 圭佑、上野 和英、獨古 薫、渡邉 正義
    • Organizer
      第87回電気化学会春季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 溶融リチウム塩錯体電解液の溶媒和構造とリチウムイオン輸送特性2019

    • Author(s)
      上野 和英
    • Organizer
      日本化学会 電気化学ディビジョン 化学電池材料研究会 第44回講演会・夏の学校
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Solvation structure and Li ion transport in molten Li salt solvate electrolytes2019

    • Author(s)
      Kazuhide Ueno
    • Organizer
      ACS Spring 2019 National Meeting & Exposition
    • Related Report
      2019 Annual Research Report 2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Correlations between Molecular Structures and Transport Properties of Highly Concentrated Li Salt Electrolytes2019

    • Author(s)
      Keisuke Shigenobu, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe
    • Organizer
      Asian Conference on Electrochemical Power Sources (ACEPS10)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 溶媒和イオン液体における L i イオン輸率支配因子の解明2019

    • Author(s)
      重信 圭佑、上野 和英、獨古 薫、渡邉 正義
    • Organizer
      第10回イオン液体討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 酸化還元特性を有するリチウム溶媒和イオン液体の創製2018

    • Author(s)
      上野 和英
    • Organizer
      第49回セミコンファレンス, 第31回東北若手の会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 常温溶融錯体のイオン液体への分類とエネルギー貯蔵デバイスへの応用2018

    • Author(s)
      上野 和英
    • Organizer
      日本分析化学会第67年会 溶液反応化学研究懇談会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Categorizing Molten Salt Complexes as Ionic Liquids and Their Applications to Battery Electrolytes2017

    • Author(s)
      Kazuhide Ueno
    • Organizer
      International Symposium on Molecular Science - Physical Chemistry/ Theoretical Chemistry, Chemoinformatics, Computational Chemistry - Cosponsored by Japan Society for Molecular Science
    • Place of Presentation
      慶応大学(神奈川県横浜市)
    • Year and Date
      2017-03-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] リチウム溶媒和イオン液体電解質の開発とその電池適用2017

    • Author(s)
      上野和英,獨古薫,渡邉正義
    • Organizer
      クリーンエネルギー材料技術フォーラム (神奈川県立産業技術総合研究所) 産技総研/横浜国立大学グリーンマテリアルイノベーション(GMI)研究拠点
    • Related Report
      2017 Annual Research Report
  • [Presentation] リチウム系二次電池用電解質としての溶媒和イオン液体の設計2016

    • Author(s)
      上野和英
    • Organizer
      関西電気化学研究会
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2016-10-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] グライム-Li塩溶融錯体:イオン液体への分類とリチウム二次電池電解質としての応用2016

    • Author(s)
      上野和英
    • Organizer
      トークイン・シャワー九州2016
    • Place of Presentation
      防長苑(山口県山口市)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Glyme-Li salt molten complexes: classification into ionic liquids and use as electrolyte in lilthium-sulfur batteries2016

    • Author(s)
      Kazuhide Ueno
    • Organizer
      7th Australian Symposium on Ionic Liquids
    • Place of Presentation
      Newcastle, Australia
    • Year and Date
      2016-05-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] Watanabe Laboratory

    • URL

      https://mwatalab.xsrv.jp/index.html

    • Related Report
      2018 Annual Research Report
  • [Remarks] Watanabe Laboratory

    • URL

      http://mwatalab.xsrv.jp/

    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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