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Nano-assembly method of the electrocatalyst for widening of operation condition of polymer electrolyte fuel cell

Research Project

Project/Area Number 16H06056
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Device related chemistry
Research InstitutionKyushu University

Principal Investigator

FUJIGAYA Tsuyohiko  九州大学, 工学研究院, 教授 (30444863)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2018: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2017: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords固体高分子型燃料電池 / 電極触媒 / プロトン伝導体 / 白金 / ポリベンズイミダゾール / 高分子電解質 / 表面改質 / カーボン担体 / プロトン電解質 / 炭素担体 / ナノカーボン / 燃料電池 / ナノチューブ / 高分子合成 / 低白金化 / ナノチューブ・フラーレン
Outline of Final Research Achievements

Development of the polymer electrolyte fuel cell (PEFC) operative under wider temperature as well as the lower humidity condition was carried out. In this project, new polymer electrolyte membrane based on polybenzimidazole (PBI) was developed. The PBI was grafted with the sulfonic acid side chains. We found that the increase of the graft distance increase the proton conductivity due to the effective hopping of the proton, which is promising for the high temperature and low humidity operation. The polymer was introduced into the electrocatalyst by taking advantage of the strong adsorption onto the carbon surface. The PBI grafted with sulfonic acid was coated onto the carbon black to offer the proton-conductive carbon black, which was new concept. After loading Pt on the new proton-conductive carbon black, we successfully fabricated the all-PBI based single cell. We found the cell was promising for the next generation operation.

Academic Significance and Societal Importance of the Research Achievements

燃料電池車の市販も開始され、固体高分子形燃料電池の重要性が高まっている。現在、普及に向けてさらなる「低コスト化」と「高活性化」が急務とされ、そのために、加湿器が不要となる「低湿度運転」と高活性化が見込める「高温化」が求められている。しかし、現行の高分子電解質は高温・低加湿での伝導度低下が大きいために、代替材料が求められていた。さらに現行炭素担体も高温での劣化が大きいことが知られているために、この両者を解決する必要があった。本研究では、高温で伝導度の高いプロトン電解質を開発し、炭素担体もカーボンナノチューブの使用を可能にし、材料側から次世代燃料電池の実現を可能にした点において意義が大きい。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (32 results)

All 2019 2018 2017 2016

All Journal Article (9 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 9 results,  Open Access: 1 results) Presentation (23 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results)

  • [Journal Article] Improved Thermoelectric Properties of Dispersant-Free Semiconducting Single-Walled Carbon Nanotubes Sorted by a Flavin Extraction Method2019

    • Author(s)
      W. Huang, F. Toshimitsu, K. Ozono, M. Matsumoto, A. Borah, Y. Motoishi, K-H. Park, J-W. Jang, T. Fujigaya
    • Journal Title

      Chemical Communications

      Volume: 55 Issue: 18 Pages: 2636-2639

    • DOI

      10.1039/c8cc10264c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Thermoelectric properties of sorted semiconducting single-walled carbon nanotube sheets2019

    • Author(s)
      W. Huang, E. Tokunaga, Y. Nakashima, T. Fujigaya
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 20 Issue: 1 Pages: 97-104

    • DOI

      10.1080/14686996.2019.1567107

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Selective Chemical Reaction of Flavin-Derivative-Wrapped Semiconducting Single-Walled Carbon Nanotubes Based on a Specific Recognition2018

    • Author(s)
      Ozono Keita、Fukuzawa Masashi、Toshimitsu Fumiyuki、Shiraki Tomohiro、Fujigaya Tsuyohiko、Nakashima Naotoshi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 91 Issue: 11 Pages: 1646-1651

    • DOI

      10.1246/bcsj.20180206

    • NAID

      130007511413

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Electronic Structure of a Polybenzimidazole-Wrapped Single-Wall Carbon Nanotube2018

    • Author(s)
      Ghuman Kulbir K.、Fujigaya Tsuyohiko
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 28 Pages: 15979-15985

    • DOI

      10.1021/acs.jpcc.8b00247

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Single-Walled Carbon Nanotubes Coated with Thiol-Reactive Gel via Emulsion Polymerization2018

    • Author(s)
      Nagai Yukiko、Tsutsumi Yusuke、Nakashima Naotoshi、Fujigaya Tsuyohiko
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 27 Pages: 8544-8550

    • DOI

      10.1021/jacs.8b03873

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] nsights into the Low Overpotential Electroreduction of CO2 to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer2018

    • Author(s)
      1.S. Verma, Y. Hamasaki, C-R. Kim, W. Huang, S. Lu, H-R. Molly Jhong, A. A. Gewirth, T. Fujigaya, N. Nakashima, P. J. A. Kenis
    • Journal Title

      ACS Energy Lett.

      Volume: 3 Issue: 1 Pages: 193-198

    • DOI

      10.1021/acsenergylett.7b01096

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ionomer Grafting to Polymer-wrapped Carbon Nanotubes for Polymer Electrolyte Membrane Fuel Cell Electrocatalyst2018

    • Author(s)
      T. Fujigaya, C. Saito, Z. Han, N. Nakashima
    • Journal Title

      Chem. Lett

      Volume: 47 Issue: 11 Pages: 261-264

    • DOI

      10.1246/cl.170744

    • NAID

      130006837426

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A highly efficient and durable carbon nanotube-based anode electrocatalyst for water electrolyzers2017

    • Author(s)
      T. Fujigaya, Y. Shi, J. Yang, H. Li, K. Ito, N. Nakashima
    • Journal Title

      J. Mater. Chem. A

      Volume: 5 Issue: 21 Pages: 10584-10590

    • DOI

      10.1039/c7ta01318c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Decorating unoxidized-carbon nanotubes with homogeneous Ni-Co spinel nanocrystals show superior performance for oxygen evolution/reduction reactions2017

    • Author(s)
      J. Yang, T. Fujigaya, N. Nakashima
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 45384-45384

    • DOI

      10.1038/srep45384

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Solvent dependence of photoluminescence energy shifts at locally functionalized sites of single-walled carbon nanotubes2019

    • Author(s)
      新留 嘉彬
    • Organizer
      第56回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis of Single-Walled Carbon Nanotubes Coated with Thiol-Reactive Gel via Emulsion Polymerization for Cancer Active Targeting2019

    • Author(s)
      永井 薫子
    • Organizer
      第56回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Controlling Thermal Conductivity of Carbon Nanotubes by Side-Wall Functionalization to Improve the Figure of Merit2019

    • Author(s)
      BORAH ANGANA
    • Organizer
      第56回 フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Microenvironmental Effect on Near Infra-red Photoluminescence Wavelength of Locally Functionalized Single-Walled Carbon Nanotubes2018

    • Author(s)
      新留 嘉彬
    • Organizer
      第55回化学関連支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Photoluminescence modulation of single-walled carbon nanotubes based on structural differences in bis-aryldiazonium modifiers2018

    • Author(s)
      余 博達
    • Organizer
      第55回化学関連支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 被覆ゲル層のクリック化学を用いたカーボンナノチューブの新規修飾法の開発2018

    • Author(s)
      永井 薫子
    • Organizer
      第55回化学関連支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 後修飾に基づく化学修飾サイトの分子デザインに応答した単層カーボンナノチューブの多段階フォトルミネッセンス変調2018

    • Author(s)
      志賀 為仁
    • Organizer
      第55回化学関連支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Self-assembled organic nanowires of diaminoanthraquinone and surface modification2018

    • Author(s)
      金 佳怜
    • Organizer
      第55回化学関連支部合同大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] カーボンブラックに対する高分子被覆の触媒活性および耐久性に対する効果2018

    • Author(s)
      藤ヶ谷 剛彦
    • Organizer
      2018年電気化学会秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 2018年電気化学会秋季大会2018

    • Author(s)
      吉原 崚
    • Organizer
      酸修飾カーボンブラックの固体高分子形燃料電池触媒層への利用
    • Related Report
      2018 Annual Research Report
  • [Presentation] 被覆ゲル層のチオール-エン反応を用いた新規カーボンナノチューブ修飾法の開発とたんぱく質修飾2018

    • Author(s)
      永井 薫子
    • Organizer
      九州地区高分子若手研究会・冬の講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Organic Solvent-induced Spectral Shifts of Near Infrared Photoluminescence of Locally Functionalized Single-walled Carbon Nanotubes2018

    • Author(s)
      新留 嘉彬
    • Organizer
      2018 MRS Fall Meeting & Exhibit
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 乳化重合によるチオール基反応性ゲル被覆カーボンナノチューブの合成2018

    • Author(s)
      永井 薫子
    • Organizer
      第28回日本MRS年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] スルホン酸側鎖を持つABPBI膜からなる電解質膜の作製およびプロトン伝導度の評価2017

    • Author(s)
      韓 薫、中嶋直敏、藤ヶ谷剛彦
    • Organizer
      第54回化学関連支部合同大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Enhanced Pt utilization in polybenzimidazole-wrapped carbon black for polymer electrolyte membrane fuel cells2017

    • Author(s)
      Samindi Jayawickrama, Fujigaya Tsuyohiko, Naotoshi Nakashima
    • Organizer
      第54回化学関連支部合同大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Influence of new ionomer and carbon support on PEMFC operation at high temperature2017

    • Author(s)
      Euiji Joy Choi, Fujigaya Tsuyohiko
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ナノカーボンの電池材料への実用化に向けて2017

    • Author(s)
      藤ヶ谷剛彦
    • Organizer
      プラスチック成形加工学会第28回年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 炭素担体の高分子被覆による燃料電池触媒活性への影響2017

    • Author(s)
      藤ヶ谷剛彦
    • Organizer
      2017年度水素・燃料電池材料研究会講座
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Development of High Temperature Polymer Electrolyte Membrane Based on Polybenzimidazoles Grafted by Alkylsulfonic Acid2016

    • Author(s)
      韓 薫、中嶋直敏、藤ヶ谷剛彦
    • Organizer
      化学関連支部合同大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルキルスルホン酸でグラフトしたポリベンズイミダゾール膜からなる電解質膜の作製2016

    • Author(s)
      韓 薫、中嶋直敏、藤ヶ谷剛彦
    • Organizer
      高分子学会年次大会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication of Acid-Grafted Polybenzimidozole Membranes for High Temperature Polymer Fuel Cell and Their Properties2016

    • Author(s)
      韓 薫、中嶋直敏、藤ヶ谷剛彦
    • Organizer
      Electrochemical Society
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Polymer-functionalized carbon support for highly durable polymer electrolyte fuel cell catalyst2016

    • Author(s)
      藤ヶ谷剛彦
    • Organizer
      E-MRS
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of Ionomer Structure for Oxygen Reduction Reaction in Acidic Media and Fuel Cell Performance2016

    • Author(s)
      藤ヶ谷剛彦
    • Organizer
      Electrochemical Society
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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