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Synthesis of functionally graded surface and interface on diamond powders structures by a chemical vapor deposition technique and investigation on their sintering principle

Research Project

Project/Area Number 16H06121
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Material processing/Microstructural control engineering
Research InstitutionNational Institute of Advanced Industrial Science and Technology (2017-2018)
Tohoku University (2016)

Principal Investigator

Katsui Hirokazu  国立研究開発法人産業技術総合研究所, 材料・化学領域, 主任研究員 (70610202)

Research Collaborator GOTO takashi  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥24,310,000 (Direct Cost: ¥18,700,000、Indirect Cost: ¥5,610,000)
Fiscal Year 2018: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2017: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Keywords化学気相析出 / ダイヤモンド / 粉体コーティング / 炭化珪素 / シリカ / 異相界面 / 放電プラズマ焼結 / 微細組織 / 傾斜機能 / 炭化ケイ素 / 粉末コーティング / 組織制御 / 硬質 / 複合材 / 焼結 / 高速焼結
Outline of Final Research Achievements

This study aimed to synthesize highly dense diamond composites by designing functionally graded interface and surface structures on the diamond via chemical vapor deposition (CVD) of ceramic layers and to examine the sintering behavior. We have developed the coating process of SiC layers on the surface diamond powders with various particle sizes. The diamond powders with SiC coating layers were consolidated with SiO2 powders to dense compacts by spark plasma sintering at temperatures of 1873-1923 K, forming well adhesive heterophase interfaces of SiO2/SiC/diamond with no crack and pores. The dense structure was attributed to the rapid viscous flow of SiO2 and functionally graded structue with excellent compatibilty and wettarabilty between the multiphases. Besides, we have successfully achieved the laminated coating of SiC and SiO2 multi-layers on diamond particles by CVD to form functionally graded structure on the diamond particle surfaces, prior to the sintering process.

Academic Significance and Societal Importance of the Research Achievements

本研究では、粉体粒子表面での化学気相成長技術を発展させ、ダイヤモンド粒子表面におけるセラミックス層の気相成長や構造制御および傾斜機能化に成功した点は、粉体工学や結晶成長学等の学術面での発展に貢献する。また、これら気相成長層や傾斜機能構造を利用してダイヤモンド粉体を低加圧焼結プロセスで高密度化した点は、焼結科学やプロセス工学への発展にも寄与する。また、ダイヤモンド焼結体の大型化や製造プロセスの低コスト化を期待できだけでなく、本手法や原理は他の硬質材料や難焼結性材料にも展開可能なことから実学的にも意義深いものと考える。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (18 results)

All 2019 2018 2017 2016

All Journal Article (7 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 1 results,  Invited: 3 results) Book (1 results)

  • [Journal Article] Coatings on ceramic powders by rotary chemical vapor deposition and sintering of the coated powders2018

    • Author(s)
      KATSUI Hirokazu、GOTO Takashi
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 6 Pages: 413-420

    • DOI

      10.2109/jcersj2.17279

    • NAID

      130007382843

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-06-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SPS焼結によるダイヤモンド基コンポジットの作製2018

    • Author(s)
      後藤孝、且井宏和
    • Journal Title

      セラミックス

      Volume: 53 Pages: 607-610

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Functional Ceramics and Coatings on Powders by CVD Techniques2018

    • Author(s)
      KATSUI Hirokazu、GOTO Takashi
    • Journal Title

      JOURNAL OF THE JAPAN WELDING SOCIETY

      Volume: 87 Issue: 2 Pages: 97-100

    • DOI

      10.2207/jjws.87.97

    • NAID

      130006489426

    • ISSN
      0021-4787, 1883-7204
    • Related Report
      2017 Annual Research Report
  • [Journal Article] Spark plasma sintering of SiC-coated large-size diamond powder2017

    • Author(s)
      Kitiwan Mettaya、Katsui Hirokazu、Goto Takashi
    • Journal Title

      Materials Today: Proceedings

      Volume: 4 Issue: 11 Pages: 11453-11456

    • DOI

      10.1016/j.matpr.2017.09.027

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Consolidation of Diamond Composites Using Silicon Carbide-Coated Diamond Powder2017

    • Author(s)
      Kitiwan Mettaya、Katsui Hirokazu、Goto Takashi
    • Journal Title

      Science of Advanced Materials

      Volume: 9 Issue: 7 Pages: 1093-1098

    • DOI

      10.1166/sam.2017.3095

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of nano-grain SiO 2 glass prepared by spark plasma sintering2017

    • Author(s)
      He Zhenhua、Katsui Hirokazu、Goto Takashi
    • Journal Title

      Journal of the European Ceramic Society

      Volume: 37 Issue: 2 Pages: 721-725

    • DOI

      10.1016/j.jeurceramsoc.2016.09.020

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly (111)-oriented SiC films on glassy carbon prepared by laser chemical vapor deposition2016

    • Author(s)
      Y. Li, H. Katsui, T. Goto
    • Journal Title

      Journal of the Korean Ceramic Society

      Volume: 53 Issue: 6 Pages: 647-651

    • DOI

      10.4191/kcers.2016.53.6.647

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Consolidation of diamond powders with CVD-coated ceramic layers2019

    • Author(s)
      Hirokazu KATSUI, Takashi GOTO, Naoki KONDO
    • Organizer
      43nd International Conference and Expo on Advanced Ceramics and Composites (ICACC2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 通電加圧焼結による難焼結性セラミックスの高密度化と微細組織制御2018

    • Author(s)
      且井宏和
    • Organizer
      第176委員会 第37回研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 化学気相析出による高付加価値セラミックスコーティング2018

    • Author(s)
      且井宏和、後藤孝
    • Organizer
      表面改質技術研究委員会 30 周年記念シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] CVDによる高機能成膜とマイクロ界面制御2017

    • Author(s)
      且井宏和、後藤孝
    • Organizer
      第120回マイクロ接合研究委員会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 化学気相析出による機能性セラミックス薄膜成長と粉体表面改質2017

    • Author(s)
      且井 宏和、後藤孝
    • Organizer
      日本セラミックス協会 2017年年会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 回転CVD法による繊維・粉体表面への炭化ケイ素コーティング2017

    • Author(s)
      堀大樹、且井 宏和、後藤 孝
    • Organizer
      第55回セラミックス基礎科学討論会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 回転CVDにより繊維基材にコーティングしたSiC膜の微細組織2017

    • Author(s)
      堀大樹、且井 宏和、後藤 孝
    • Organizer
      日本セラミックス協会 2017年年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Consolidation of diamond-SiO2 by SPS using bimodal size SiC-coated diamond2017

    • Author(s)
      Mettaya Kitiwan, Hirokazu Katsui, Takashi Goto
    • Organizer
      日本セラミックス協会 2017年年会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 回転CVD による繊維系材料表面へのSiC コーティング2016

    • Author(s)
      堀大樹、且井 宏和、後藤 孝
    • Organizer
      日本セラミックス協会 東北北海道支部研究発表会
    • Related Report
      2016 Annual Research Report
  • [Presentation] SPS Densification of SiC-coated Diamond and Mullite-Silica Composites2016

    • Author(s)
      Mettaya Kitiwan, Hirokazu Katsui, Takashi Goto
    • Organizer
      粉体粉末冶金協会 平成28年秋季大会
    • Related Report
      2016 Annual Research Report
  • [Book] 多次元アディティブ・マニュファクチャリング2018

    • Author(s)
      且井宏和、後藤孝
    • Total Pages
      188
    • Publisher
      日本溶接協会表面改質技術研究委員会
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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