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Development of electrochemical devise by control of inner potential into proton conducting-oxide

Research Project

Project/Area Number 16H06124
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Metal making/Resorce production engineering
Research InstitutionUniversity of Miyazaki

Principal Investigator

OKUYAMA YUJI  宮崎大学, 工学部, 准教授 (80613281)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥24,180,000 (Direct Cost: ¥18,600,000、Indirect Cost: ¥5,580,000)
Fiscal Year 2018: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2016: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywordsプロトン / 燃料電池 / 水蒸気電解 / センサ / 電気伝導度 / 電気化学デバイス / プロトン伝導 / 高圧水蒸気 / プロトン伝導体
Outline of Final Research Achievements

In order to clarify the relation between the proton transport property and the potential gradient into oxide, the conductivity, and the electromotive force, the performance of electrochemical cell such as fuel cell and steam electrolysis cell were measured for proton-conducting oxide at various condition. The high proton conductivity was observed under high water vapor pressure. The electromotive force of gas concentration cell using proton-conducting oxide as electrolyte increased due to temperate gradient. This suggest to inhibit the influence of the hole conduction by the potential control. The fuel cell performance of bi-layered proton-conducting oxide was examined at 1073 K. The open circuit voltage increased but the improvement of the power density was not observed due to bi-layer structure.

Academic Significance and Societal Importance of the Research Achievements

本研究では次世代エネルギー変換デバイスとなりうるプロトン伝導体に着目し、現状のデバイス作動環境として想定されていない高水蒸気圧雰囲気や温度勾配、分圧勾配さらには組成勾配を伴う状況でのプロトン伝導特性およびデバイス性能を評価した。本研究成果によりこれまで明確になっていなかった高水蒸気圧下でのプロトン伝導特性を把握することができた。さらにプロトン伝導体を用いたデバイスにおいて高水蒸気下での高性能化や温度勾配下による正孔伝導性の低減などデバイス性能向上の可能性を見出した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (33 results)

All 2019 2018 2017 2016

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (25 results) (of which Int'l Joint Research: 8 results,  Invited: 5 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Experimental and theoretical approaches for the investigation of proton conductive characteristics of La1-Ba YbO3-δ2019

    • Author(s)
      Obukuro Yuki、Okuyama Yuji、Sakai Go、Matsushima Shigenori
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 770 Pages: 294-300

    • DOI

      10.1016/j.jallcom.2018.08.062

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Energy efficiency of ionic transport through proton conducting ceramics electrolytes for energy conversion applications2018

    • Author(s)
      Takashi Nakamura, Shusuke Mizunuma, Yuta Kimura, Yuichi Mikami, Kousuke Yamauchi, Tomohiro Kuroha, Noboru Taniguchi, Yoichiro Tsuji, Yuji Okuyama, Koji Amezawa
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 6 Issue: 32 Pages: 15771-15780

    • DOI

      10.1039/c8ta05373a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient intermediate-temperature steam electrolysis with Y:SrZrO3-SrCeO3 and Y:BaZrO3-BaCeO3 Proton Conducting perovskites2018

    • Author(s)
      K. Leonard, Y. Okuyama, Y. Takamura, Y. Lee, K. Miyazaki, M. E. Ivanova, W. A. Meulenberg and H. Matsumto
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 6 Issue: 39 Pages: 19113-19124

    • DOI

      10.1039/c8ta04019b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conduction and Incorporation into La<sub>1−</sub><i><sub>x</sub></i>Ba<i><sub>x</sub></i>Yb<sub>0.5</sub>In<sub>0.5</sub>O<sub>3−δ</sub>2018

    • Author(s)
      Yuji Okuyama, Takuya Yamaguchi, Naoki Matsunaga, Go Sakai
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 59 Issue: 1 Pages: 14-18

    • DOI

      10.2320/matertrans.MB201701

    • NAID

      130006279156

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 固体電解質センサによるディーゼル排気ガス中の水素濃度測定2017

    • Author(s)
      常吉孝治、高橋総子、岩井翔、奥山勇治
    • Journal Title

      自動車技術会論文

      Volume: 48 Pages: 1171-1175

    • NAID

      130006734334

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Direct Methane Fuel Cell with Double-Layered Electrolyte Using Proton Conducting Oxide2017

    • Author(s)
      Okuyama Yuji、Kawano Shigemichi、Sakai Go、Matsunaga Naoki、Mizutani Yasunobu
    • Journal Title

      ECS Transactions

      Volume: 78 Issue: 1 Pages: 1953-1961

    • DOI

      10.1149/07801.1953ecst

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] プロトン伝導体を用いたメタン燃料電池特性と電解質二層化によるメタン耐性の向上2019

    • Author(s)
      奥山勇治,河野樹道,赤羽涼,長友都史, 松永直樹、酒井剛、小椋裕介, 水谷安伸
    • Organizer
      電気化学会第86回大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] NiOを含んだジルコン酸バリウムのプロトン・正孔部分伝導度と燃料電池効率2018

    • Author(s)
      奥山勇治、新名美城、首藤美月、酒井剛、松永直樹、山内孝祐、見神祐一、黒羽智宏
    • Organizer
      第44回固体イオニクス討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Proton transport properties of acceptor-doped barium zirconate containing NiO2018

    • Author(s)
      Yuji Okuyama, Yoshiki Niina, Mizuki Shudo, Go Sakai, Naoki Matsunaga, Kosuke Yamauchi, Mikami Yuichi, and Tomohiro Kuroha
    • Organizer
      19th Solid State Proton conductor
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mnを添加したCaZrO3を用いた水素センサの貴金属電極の検討2018

    • Author(s)
      奥山勇治、有川雄輝、酒井剛、松永直樹、岩井翔、常吉孝治
    • Organizer
      第14回固体イオニクスセミナー
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] プロトン伝導性酸化物の欠陥構造と電気化学デバイスへの応用2017

    • Author(s)
      奥山勇治
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大東京(東京都・八王子市)
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Proton transport and polarization properties of La-based perovskite oxide2017

    • Author(s)
      Yuji Okuyama
    • Organizer
      10th Petite Workshop, International workshop on defect chemistry for advanced energy and functional materials
    • Place of Presentation
      Seoul National University(Korea)
    • Year and Date
      2017-03-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 固体電解質センサによるディーゼル排気ガス中の水素濃度測定2017

    • Author(s)
      常吉孝治、高橋総子、岩井翔、奥山勇治
    • Organizer
      自動車技術会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of adding Ni on defect structure and proton transport properties of indium doped barium zirconate2017

    • Author(s)
      Yuji Okuyama, Yoshiki Niina, Mizuki Shudo, Go Sakai, Naoki Matsunaga, Kosuke Yamauchi, Mikami Yuichi, and Tomohiro Kuroha
    • Organizer
      21th international conference on Solid State Ionics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effect of dopant on reactivity between doped-BaZrO3 and NiO2017

    • Author(s)
      Yuichi Mikami*, Tomohiro Kuroha, Takehito Goto, Kosuke Yamauchi, Tomoya Kamata, Kaori Takeuchi1, Noboru Taniguchi, Yoichiro Tsuji, and Yuji Okuyama
    • Organizer
      21th international conference on Solid State Ionics
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ln0.9Sr0.1InO3-δ(Ln = La, Nd, Sm, Gd)のプロトン電導度へのカチオンサイズ効果2017

    • Author(s)
      加藤省吾、松永直樹、酒井剛、奥山勇治
    • Organizer
      第54回化学関連支部合同九州大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] A Direct Methane Fuel Cell with Double-Layered Electrolyte using Proton Conducting Oxide2017

    • Author(s)
      Yuji Okuyama, Shigemichi Kawano, Go Sakai, Naoki Matsunaga, Yasunobu Mizutani
    • Organizer
      SOFC15
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ln0.9Sr0.1InO3-δ(Ln = La, Nd, Sm, Gd)におけるプロトン・デューテロン同位体効果、2017

    • Author(s)
      加藤省吾、松永直樹、酒井剛、奥山勇治
    • Organizer
      電気化学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 2層構造を伴ったプロトン伝導性固体電解質のメタン燃料電池出力と耐性2017

    • Author(s)
      奥山勇治、河野樹道、赤羽涼、、松永直樹、酒井剛、水谷安伸
    • Organizer
      第43回固体イオニクス討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Evaluation of the electronic and local structure of proton-conducting oxide, (CaZr1-x,Mnx)O3-d, to elucidate a novel protonation mechanism2017

    • Author(s)
      Masatsugu Oishi, Takuya Doi, Takashi Yamamoto, Takashi Nakamura, and Yuji Okuyama
    • Organizer
      第43回固体イオニクス討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] BaCe0.6Zr0.2Y0.2O3-δを電解質とした燃料電池特性とNi固溶に伴う出力低下2016

    • Author(s)
      蛯原紀明、奥山賢治、水谷安伸、酒井剛、松永直樹、奥山勇治
    • Organizer
      第42回固体イオニクス討論会
    • Place of Presentation
      名古屋国際会議場(愛知・名古屋市)
    • Year and Date
      2016-12-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] Proton transport properties of Mn doped CaZrO3 with redox protonation2016

    • Author(s)
      Yuji Okuyam, Shinya Nagamine, Muneyuki Shibuya, Akira Nakajima, Naoki Matsunag, Go Sakai, Tomoko Oshima, Fusako Takahashi, Koji Kimata, Koji Tsuneyoshi
    • Organizer
      MS&T2016
    • Place of Presentation
      Salt Place Convention Center (USA, UTAH)
    • Year and Date
      2016-10-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Proton transport properties of Mn doped CaZrO3 and its application to hydrogen sensor2016

    • Author(s)
      Yuji Okuyama, Shinya Nagamine, Muneyuki Shibuya, Yuki Arikawa, Akira Nakajima, Naoki Matsunag, Go Sakai, Tomoko Oshima, Fusako Takahashi, Koji Tsuneyoshi
    • Organizer
      The Solid State Electrochemistry Workshop 2016
    • Place of Presentation
      東京大学生産技術研究所(東京都・目黒区)
    • Year and Date
      2016-10-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アルカリ土類ジルコネート中のMn価数とプロトン溶解2016

    • Author(s)
      奥山勇治、有川雄輝、中島暉、酒井剛、松永直樹
    • Organizer
      第12回固体イオニクスセミナー
    • Place of Presentation
      休暇村指宿(鹿児島・指宿)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] BaCe0.6Zr0.2Y0.2O3-δの燃料電池特性とNi固溶に伴う性能低下2016

    • Author(s)
      蛯原紀明、奥山賢治、水谷安伸、酒井剛、松永直樹、奥山勇治
    • Organizer
      第12回固体イオニクスセミナー
    • Place of Presentation
      休暇村指宿(鹿児島・指宿)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] La0.9Sr0.1Yb0.8In0.2O3-δを電解質とした水素燃料電池と電極過電圧2016

    • Author(s)
      河野樹道、藤村玲央、奥山賢治、水谷安伸、酒井剛、松永直樹、奥山勇治
    • Organizer
      第12回固体イオニクスセミナー
    • Place of Presentation
      休暇村指宿(鹿児島・指宿)
    • Year and Date
      2016-09-27
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fuel cell performance and potential profile of lanthanum ytterbium based perovskite oxide2016

    • Author(s)
      Yuji Okuyama, Reo Fujimura, Kenji Okuyama, Yasunobu Mizutani, Naoki Matsunaga, Go Sakai
    • Organizer
      Solid State Proton Conductor 18
    • Place of Presentation
      Soria Moria conference center(Norway, Oslo)
    • Year and Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] Performance of Protonic Ceramic Fuel Cells using lanthanum ytterbium based perovskite oxide as electrolyte2016

    • Author(s)
      Yuji Okuyama, Reo Fujimura, Kenji Okuyama, Yasunobu Mizutani, Naoki Matsuna, Go Sakai
    • Organizer
      9th Pacific Rim International Conference on Advanced Materials and Processing (PRICIM9)
    • Place of Presentation
      京都国際会館(京都府・京都市)
    • Year and Date
      2016-08-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] プロトン導電性酸化物の基礎物性と環境デバイスへの応用2016

    • Author(s)
      奥山勇治
    • Organizer
      SOFC研究会
    • Place of Presentation
      笹川記念会館(東京・港区)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] BaCe0.6Zr0.2Y0.2O3-δを電解質とした燃料電池におけるホール伝導が与える性能への影響2016

    • Author(s)
      蛯原紀明、松永直樹、酒井剛、奥山勇治
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(福岡・北九州市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] BaCe0.6Zr0.2Y0.2O3-δの部分伝導度と分極特性2016

    • Author(s)
      蛯原紀明、松永直樹、酒井剛、奥山勇治
    • Organizer
      資源素材学会九州支部2016年若手研究者及び学生による研究発表会
    • Place of Presentation
      九州大学(福岡・福岡市)
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] プロトン伝導性固体電解質およびプロトン燃料電池2018

    • Inventor(s)
      奥山勇治,水谷安伸
    • Industrial Property Rights Holder
      奥山勇治,水谷安伸
    • Industrial Property Rights Type
      特許
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 水素濃度の検出方法及び水素センサ2017

    • Inventor(s)
      奥山勇治、常吉孝治、高橋聡子、岩井翔
    • Industrial Property Rights Holder
      奥山勇治、常吉孝治、高橋聡子、岩井翔
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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