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Fabrication of ordered bulk hetero junction photovoltaics using supercritical fluid

Research Project

Project/Area Number 16H06127
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Reaction engineering/Process system
Research InstitutionThe University of Tokyo

Principal Investigator

Momose Takeshi  東京大学, 大学院工学系研究科(工学部), 講師 (10611163)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥24,700,000 (Direct Cost: ¥19,000,000、Indirect Cost: ¥5,700,000)
Fiscal Year 2019: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2017: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2016: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Keywordsナノ充填 / 有機半導体 / 超臨界流体 / プロセス / 有機薄膜太陽電池 / 材料合成プロセス
Outline of Final Research Achievements

Nanofilling technology using supercritical fluid was investigated for the formation of three-dimensional organic photovoltaics. Supercritical fluid can drastically change the solubility of materials by tuning the temperature and pressure. In this study, the temperature dependence of the solubility of semiconductor molecules in supercritical fluid was utilized to allow the deposition. The formation of ultra-thin continuous films, which is difficult to achieve with conventional techniques, was successfully achieved using tetracene as a model substance. The obtained films had high crystallinity. It was possible to form the tetracene thin film onto microtrenches with an aspect ratio of 10, but it was not possible to fill the film. Further study is necessary.

Academic Significance and Societal Importance of the Research Achievements

超臨界流体中の物質の溶解度の温度依存性を活用することにより,テトラセンをモデル物質として,結晶性の高い極薄連続膜の堆積に成功した。従来技術に比べ,結晶サイズが大きく,結晶性が高いことから高い移動度が期待できる。有機半導体デバイスでの検証次第ではあるが,高い移動度が期待できる。また,埋め込み性に関しては完全な埋め込みには至らなかったが,従来技術ではアスペクト比1以下の構造でのみ充填が確認されており,有機薄膜太陽電池に限らず,ナノ充填技術として期待できる。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (4 results)

All 2019 2018 2017

All Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Presentation] Crystalline ultra-thin tetracene film formation by temperature-driven supercritical fluid deposition2019

    • Author(s)
      1.Yanshao Lee, Momoko Deura, Yusuke Shimoyama, Yukihiro Shimogaki, and Takeshi Momose
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress (APCChE 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ultra-thin continuous crystalline tetracene film formation by temperature-driven supercritical fluid deposition2019

    • Author(s)
      レイ ゲンショウ,出浦 桃子,下山 裕介,霜垣 幸浩,百瀬 健
    • Organizer
      化学工学会 第84年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Tetracene thin film formation for organic photovoltaics by temperature-driven supercritical fluid deposition2018

    • Author(s)
      黎 彦劭,出浦 桃子,下山 裕介,霜垣 幸浩,百瀬 健
    • Organizer
      化学工学会 第50回秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 超臨界流体の温度勾配を利用したテトラセン製膜技術の構築2017

    • Author(s)
      木下 圭,下山 裕介,霜垣 幸浩,百瀬 健
    • Organizer
      第19回化学工学会学生発表会
    • Place of Presentation
      東京農工大学,小金井,東京
    • Related Report
      2016 Annual Research Report

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Published: 2016-04-21   Modified: 2021-02-19  

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