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Development of roughened current collector by an electroplating method

Research Project

Project/Area Number 16H06838
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Device related chemistry
Research InstitutionShinshu University

Principal Investigator

SHIMIZU Masahiro  信州大学, 学術研究院工学系, 助教 (90780601)

Project Period (FY) 2016-08-26 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsナトリウムイオン電池 / Sn負極 / 粗面化基板 / ポリアクリル酸 / 集電体 / アンカー効果 / 粗面化集電体 / 電析 / 組織制御 / 吸着 / 電気めっき / スズ負極 / めっき / 蓄電池 / 多孔質集電体
Outline of Final Research Achievements

The use of high capacity electrode materials based on alloying and dealloying reactions with Na is very effective for improving energy density of batteries. However, their application brings on electrical isolation such as detachment of the electrode mixture layer from a current collector, causing rapid capacity fading. We found that Cu electrochemically grows in sheet form by electroplating in a CuSO4-based aqueous solution with polyacrylic acid (PAA). The STEM images and EBSD maps revealed that the Cu sheet was a single crystal, and the results obtained from XRD and the cathodic polarization behavior of Cu electrodeposition in PAA-containing solutions suggested that PAA molecules adsorbed onto Cu (100) to suppress the Cu growth on the plane, resulting in the formation of Cu sheets. The roughened-Cu substrate suppressed the detachment of the active material layer to maintain a high capacity of 685 mA h g-1 with good capacity retention of more than 90% by the anchor effect.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • Research Products

    (34 results)

All 2018 2017 2016 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 4 results,  Acknowledgement Compliant: 1 results) Presentation (18 results) (of which Int'l Joint Research: 3 results) Book (2 results) Remarks (6 results)

  • [Journal Article] Electrochemical preparation of free-standing carbon-nanotube/Sn composite paper2018

    • Author(s)
      Masahiro Shimizu, Shunya Shimizu, Arinobu Katada, Mitsugu Uejima, Susumu Arai
    • Journal Title

      Materials Letters

      Volume: 220 Pages: 182-185

    • DOI

      10.1016/j.matlet.2018.03.021

    • NAID

      120007099682

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Suppressing the effect of lithium dendritic growth by the addition of magnesium bis(trifluoromethanesulfonyl)amide2018

    • Author(s)
      Masahiro Shimizu, Makoto Umeki, Susumu Arai
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 20 Issue: 2 Pages: 1127-1133

    • DOI

      10.1039/c7cp06057b

    • NAID

      120007099683

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of Roughened Current Collector by Bottom-up Approach Using the Electroplating Technique: Charge?Discharge Performance of a Sn Negative-Electrode for Na-Ion Batteries2017

    • Author(s)
      Masahiro Shimizu, Ryosuke Yatsuzuka, Masaomi Horita, Takahiro Yamamoto, Susumu Arai
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 49 Pages: 27285-27294

    • DOI

      10.1021/acs.jpcc.7b08512

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Copper/Single-Walled Carbon Nanotube Composites by Electrodeposition Using Free-Standing Nanotube Film2017

    • Author(s)
      Susumu Arai, Kyohei Kirihata, Masahiro Shimizu, Miyoka Ueda, Arinobu Katada, Mitsugu Uejima
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 13 Pages: D922-D929

    • DOI

      10.1149/2.0041714jes

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electrochemical Na-Insertion/Extraction Property of Ni-Coated Black Phosphorus Prepared by an Electroless Deposition Method2017

    • Author(s)
      Masahiro Shimizu, Yuji Tsushima, Susumu Arai
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 8 Pages: 4306-4315

    • DOI

      10.1021/acsomega.7b00950

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Micro-Scale Columnar Architecture Composed of Copper Nano Sheets by Electrodeposition Technique2017

    • Author(s)
      Susumu Arai, Masaya Ozawa, Masahiro Shimizu
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 164 Issue: 2 Pages: D72-D74

    • DOI

      10.1149/2.1101702jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Li-insertion/extraction properties of three-dimensional Sn electrode prepared by facile electrodeposition method2017

    • Author(s)
      Masahiro Shimizu, Mendsaikhan Munkhbat, Susumu Arai
    • Journal Title

      Journal of Applied Electrochemistry

      Volume: 47 Issue: 6 Pages: 727-734

    • DOI

      10.1007/s10800-017-1075-0

    • NAID

      120007099684

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabricaion of Three-Dimensional (3D) Copper/Carbon Nanotube Composite Film by One-Step Electrodeposition2016

    • Author(s)
      Susumu Arai, Masaya Ozawa, Masahiro Shimizu
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 163 Issue: 14 Pages: D774-D779

    • DOI

      10.1149/2.0601614jes

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 電析法により作製した銅三次元構造体を集電体に用いたSn 負極の電気化学的Na 挿入-脱離特性2017

    • Author(s)
      八塚涼輔,清水雅裕,新井 進
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京,八王子
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 多価金属塩含有電解液中におけるリチウム金属負極の電気化学的挙動2017

    • Author(s)
      梅木 誠,清水雅裕,新井 進
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京,八王子
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 無電解めっき法によるナトリウムイオン電池負極用ニッケル被覆黒リンの創製2017

    • Author(s)
      津島湧使,清水雅裕,新井 進
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京,八王子
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] めっき法により作製した三次元銅構造体の形成メカニズム解析2017

    • Author(s)
      山本貴大,清水雅裕,新井 進
    • Organizer
      第135回表面技術協会
    • Place of Presentation
      東洋大学,埼玉
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 粗面化集電体の電気化学的創製およびナトリウムイオン電池用 Sn 負極への適用2017

    • Author(s)
      清水雅裕,八塚涼輔,新井 進
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 粗面化集電体の電気化学的創製とナトリウムイオン電池用Sn負極への応用2017

    • Author(s)
      清水雅裕,八塚涼輔,新井 進
    • Organizer
      第48回 中部化学関係学協会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Effect of Various Surfactants on Morphology of Cu/SWCNT Electroplating films2017

    • Author(s)
      Masahiro Shimizu, Takayuki Ogasawara, Susumu Arai
    • Organizer
      The 30th International Microprocesses and Nanotechnology Conference (MNC 2017)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 電析法により作製した粗面化集電体のナトリウムイオン電池用Sn負極への適用2017

    • Author(s)
      八塚涼輔,清水雅裕,新井 進
    • Organizer
      第136回表面技術協会講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] CNT/Sn自立膜複合体の電気化学的創製およびそのリチウムイオン電池負極特性2017

    • Author(s)
      清水俊也,清水雅裕,上島 貢,新井 進
    • Organizer
      2017年電気化学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 多価金属塩含有電解液中におけるリチウムの析出挙動2017

    • Author(s)
      梅木 誠,清水雅裕,新井 進
    • Organizer
      2017年電気化学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 無電解析出法により作製したNi被覆黒リン電極の電気化学的Na吸蔵-放出特性2017

    • Author(s)
      津島湧使,清水雅裕,新井 進
    • Organizer
      2017年電気化学会秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 無電解めっき法によるリチウムイオン電池用Cu-Sn三次元構造体負極の創製2016

    • Author(s)
      伊藤達哉,清水雅裕,植田美代加,新井 進
    • Organizer
      日本化学会秋季事業 第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀,東京
    • Year and Date
      2016-11-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 次世代リチウム二次電池用高容量負極材料の創成2016

    • Author(s)
      清水雅裕
    • Organizer
      表面技術協会 関東支部 第92回講演会&日本材料学会 北陸信越支部 特別講演会
    • Place of Presentation
      信州大学国際科学イノベーションセンター,長野
    • Year and Date
      2016-11-11
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication and Electrochemical Evaluation of Tin PlatedThree-dimensional Copper Nanostructured Anode for Lithium Ion Battery2016

    • Author(s)
      Munkhbat Mendsaikhan, Masahiro Shimizu, Susumu Arai
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME2016)
    • Place of Presentation
      Hawaii Convention Center, United States of America (USA), Honolulu, Hawaii
    • Year and Date
      2016-10-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of Tin-Plated Three-Dimensional Copper Nanostructure Using Electroless Plating and Its Anode Performance in Lithium-Ion Battery2016

    • Author(s)
      Tatsuya Itoh, Masahiro. Shimizu, Susumu Arai
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME2016)
    • Place of Presentation
      Hawaii Convention Center, United States of America (USA), Honolulu, Hawaii
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of Na-Storage Inorganic Compounds and their Anode Properties for Rechargeable Battery2016

    • Author(s)
      Masahiro Shimizu, Hiroyuki Usui, Yasuhiro Domi, Takayuki Yamamoto, Toshiyuki Nohira, Rika Hagiwara, Hiroki Sakaguchi
    • Organizer
      The 7th International Symposium of Advanced Energy Science
    • Place of Presentation
      International Conference Halls, Kyoto University, Japan, Kyoto
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 置換めっき法を用いたCu-Sn三次元構造体の作製2016

    • Author(s)
      伊藤達哉,清水雅裕,植田美代加,新井 進
    • Organizer
      第134回表面技術協会
    • Place of Presentation
      東北大学,仙台
    • Year and Date
      2016-09-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] 各種CNTが三次元Cu/CNT複合めっき膜の構造に与える影響2016

    • Author(s)
      小澤雅也,清水雅裕,植田美代加,新井 進
    • Organizer
      第134回表面技術協会
    • Place of Presentation
      東北大学,仙台
    • Year and Date
      2016-09-02
    • Related Report
      2016 Annual Research Report
  • [Book] 次世代電池用電極材料の高エネルギー密度、高出力化-リチウム過剰系正極、三元系正極、シリコン系負極、ポストリチウムイオン電池-2017

    • Author(s)
      清水雅裕,新井 進
    • Total Pages
      602
    • Publisher
      情報技術協会
    • ISBN
      9784861046858
    • Related Report
      2017 Annual Research Report
  • [Book] 最新フォトレジスト材料開発とプロセス最適化技術2017

    • Author(s)
      新井 進,清水雅裕
    • Total Pages
      320
    • Publisher
      CMC出版
    • ISBN
      9784781312637
    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      https://masahiros0310.wixsite.com/masahiro-shimizu

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://arai-shimizu-lab.org/

    • Related Report
      2017 Annual Research Report
  • [Remarks]

    • URL

      http://arai-shimizu-lab.org/

    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      https://masahiros0310.wixsite.com/masahiro-shimizu

    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://soar-rd.shinshu-u.ac.jp/profile/ja.gCkVbUkh.html

    • Related Report
      2016 Annual Research Report

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Published: 2016-09-02   Modified: 2019-03-29  

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