| Project/Area Number |
16H06862
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2016-08-26 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | ラジカル / ホウ素 / 一電子移動 / ルイス酸 / ルイス塩基 / 光触媒 / 有機化学 / ラジカル触媒 / 触媒活性制御 / チイルラジカル / 置換基効果 / ルイス酸・塩基複合体 |
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| Outline of Final Research Achievements |
In order to verify the transformation of radical reactivity depending on the coordination number of a boron center, some radical compounds with a boryl group were synthesized.In this process, we found the generation of Lewis radical-ion pairs via the single electron transfer between a Lewis acid and a base under photoirradiation. Although an additional condition, photoirradiation, is essential, the result indicates that the generation of boron-centered radical can be controlled by the presence and absence of a Lewis base. The finding will remove the barrier of structural limitation of Lewis pairs inducing single electron transfer and have a potential to accelerate the application to organic transformation and catalysis. In fact, we revealed the photocatalytic ability of electron-deficient borane, which could be a mile stone for catalysis of Lewis radical-ion pairs.
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