| Project/Area Number |
16H06887
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
Nogi Keisuke 京都大学, 理学研究科, 助教 (60779148)
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| Research Collaborator |
YORIMITSU Hideki 京都大学, 大学院理学研究科, 教授
Otsuka Shinya 京都大学, 大学院理学研究科, 大学院生
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| Project Period (FY) |
2016-08-26 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 遷移金属触媒 / 有機金属化合物 / 脱カルボニル / ホウ素化 / ニッケル / パラジウム / エステル / 亜鉛化 / ホウ素化反応 / 亜鉛化反応 |
|---|
| Outline of Final Research Achievements |
We investigated decarbonylative transformations of esters to organometallic species such as organoboron or zinc compounds. During the investigation, instead of the target transformations, we succeeded in development of C-S bond cleaving transformations of aryl sulfoxides including Negishi-type arylation, Sonogashira-type alkynylation, Buchwald-Hartwig-type amination, Miyaura-type borylation. C-S bonds are considered as “inert” bond as same as C-O bonds, and our results would afford important perceptions for further investigation of C-S bond cleaving transformations.
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