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Mechanical control of molecules at the dynamic 2D interface

Research Project

Project/Area Number 16H07435
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

NAKANISHI Waka  国立研究開発法人物質・材料研究機構, 国際ナノアーキテクトニクス研究拠点, 主任研究員 (20401010)

Project Period (FY) 2016-08-26 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords気水界面 / 蛍光 / 界面 / 表面・界面物性 / 超分子化学 / 超薄膜 / 分子機械 / 合成化学 / 分子構造 / 脂質
Outline of Final Research Achievements

Molecules have random orientations in 3D solutions. On the other hand, molecules can align at the 2D air-water interface depending on their polarity. Using this character of the molecule, conformation of molecule can be tuned by external lateral force. In this work, the motion of these molecules at the air water interface was analyzed. Here amphiphilic fluorescent molecules were used, which show strong fluorescence by inhibition of internal molecular rotation.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • Research Products

    (14 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (5 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 5 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 1 results)

  • [Int'l Joint Research] National University of Ireland Galway(アイルランド)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Solid surface vs. liquid surface: nanoarchitectonics, molecular machines, and DNA origami2017

    • Author(s)
      Ariga Katsuhiko、Mori Taizo、Nakanishi Waka、Hill Jonathan P.
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 19 Issue: 35 Pages: 23658-23676

    • DOI

      10.1039/c7cp02280h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conformation Manipulation and Motion of a Double Paddle Molecule on an Au(111) Surface2017

    • Author(s)
      Soe We-Hyo、Shirai Yasuhiro、Durand Corentin、Yonamine Yusuke、Minami Kosuke、Bouju Xavier、Kolmer Marek、Ariga Katsuhiko、Joachim Christian、Nakanishi Waka
    • Journal Title

      ACS Nano

      Volume: 11 Issue: 10 Pages: 10357-10365

    • DOI

      10.1021/acsnano.7b05314

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Symmertic Raman Tensor Contributes to Chiral Vibrational Sum Frequency Generation from Binaphthyl Amphilphile Monolayers on Water -Study of Electronic Resonance Amplitude and Phase Profiles-2017

    • Author(s)
      4.M. Okuno, D. Ishikawa, W. Nakanishi, K. Ariga and T. Ishibashi
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 121 Issue: 21 Pages: 11241-11250

    • DOI

      10.1021/acs.jpcc.6b12664

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanically Induced Opening-Closing Action of Binaphthyl Molecular Pliers: Digital Phase Transition vs. Continuous Conformational Change2017

    • Author(s)
      T. Mori, D. Ishikawa, Y. Yonamine, Y. Fujii, J. P. Hill, I. Ichinose, K. Ariga, W. Nakanishi
    • Journal Title

      ChemPhysChem

      Volume: 印刷中 Issue: 11 Pages: 1470-1474

    • DOI

      10.1002/cphc.201601144

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Driving nanocars and nanomachines at interfaces: From concept of nanoarchitectonics to actual use in world wide race and hand operation2016

    • Author(s)
      Yasuhiro Shirai; Kosuke Minami; Waka Nakanishi; Yusuke Yonamine; Christian Joachim; Katsuhiko Ariga
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 55 Issue: 11 Pages: 1102A2-1102A2

    • DOI

      10.7567/jjap.55.1102a2

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Control of Molecular Conformation at Interfaces: Structure and Motion2018

    • Author(s)
      NAKANISHI, Waka, We-Hyo Soe, Marek Kolmer, Xavier Bouju, SHIRAI, Yasuhiro, MINAMI, Kosuke, Joachim, Christian, ARIGA, Katsuhiko
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Conformation Manipulation and Motion of a Double Paddle Nanocar for the International Nanocar Race.2018

    • Author(s)
      NAKANISHI, Waka, We-Hyo Soe, Marek Kolmer, Xavier Bouju, SHIRAI, Yasuhiro, MINAMI, Kosuke, Joachim, Christian, ARIGA, Katsuhiko
    • Organizer
      MANA International Symposium
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nanocar race: Conformation manipulation and motion of a single molecule2018

    • Author(s)
      中西 和嘉
    • Organizer
      WCCU-SMAジョイントシンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of molecular machines by conformation manipulations at interfaces.2018

    • Author(s)
      中西 和嘉
    • Organizer
      New Frontiers of Supramolecular Chemistry in Non-equilibrium Sys.
    • Related Report
      2017 Annual Research Report
  • [Presentation] Conformation manipulation of binaphthyl-dimer with a low temperature STM2017

    • Author(s)
      e-Hyo Soe, Marek Kolmer, Xavier Bouju, Y. Shirai, K. Minami, K. Ariga, W. Nakanishi
    • Organizer
      The Annual Spring meeting of the German Physical Society
    • Place of Presentation
      German
    • Year and Date
      2017-03-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 界面における分子・分子集合体の動的構造制御と機能2017

    • Author(s)
      中西 和嘉
    • Organizer
      第68回コロイドおよび界面化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of molecular machines at the interface2017

    • Author(s)
      中西 和嘉
    • Organizer
      日本化学会第97春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Control of molecular machines at interfaces2017

    • Author(s)
      中西 和嘉
    • Organizer
      90th JSCM Anniversary Conference
    • Related Report
      2017 Annual Research Report

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Published: 2016-09-02   Modified: 2019-03-29  

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