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CH-π相互作用による液膜保持を用いた滑水性防氷膜の作製

Research Project

Project/Area Number 16J06070
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKeio University

Principal Investigator

天神林 瑞樹  慶應義塾大学, 理工学部, 特別研究員(PD)

Project Period (FY) 2016-04-22 – 2019-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2017: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 2016: ¥700,000 (Direct Cost: ¥700,000)
Keywords撥水 / 濡れ / 薄膜 / 防氷 / 滑液 / SLIPS / 液膜 / π相互作用 / 防氷コーティング / 滑落コーティング / 表面 / 界面 / 生態模倣
Outline of Annual Research Achievements

本課題の研究は非常に順調に進み,本課題での年度計画を全て完遂した.さらに,挑戦課題として設けていた研究計画を遂行した.2年間を持って研究を完遂した.
液体の滑落特性がCH-π相互作用に由来する分子の”柔軟性”に起因することを明らかにし,液体の付着力と相互作用の関係を定量化した.本成果はアメリカ化学会のACS Applied Materials & Interfaces誌に掲載された.また,液膜表面での濡れ特性が滑液対象液体の運動エネルギーに相関することを見出し,液体の付着メカニズムを解明した.本成果はアメリカ化学会のLangmuir誌の表紙として掲載された.本課題で作製した高機能性滑液膜は,通称SPLASH (surface with π -interaction liquid adsorption, smoothness, and hydrophobicity)膜として前年度に報告した.そしてSPLASH膜は防氷特性にとどまらず,様々な応用可能性を示した.そこでSPLASH膜が,微小液体を滑落させる特性を利用して熱交換器に応用した.本成果はアメリカ化学会のLangmuir誌に掲載された.また,本表面を濡れ性スイッチ可能なスマートウェッティングシステム,液体輸送表面コーティングへ応用した.
本課題で作製した滑液膜は液膜の枯渇によって機能性が失われてしまうことが分かった.そこで挑戦課題として液膜を長期的に安定させる表面の構築を検討した.
液膜を多孔質層でサンドイッチするような3層構造として,通称LIMITS (lubricant-inserted (sandwiched) microporous triple-layered surface)を提案し,連続水接触環境下で1000時間以上安定した液膜保持機能を可能とした.本成果はアメリカ化学会のLangmuir誌に掲載された.

Research Progress Status

翌年度、交付申請を辞退するため、記入しない。

Strategy for Future Research Activity

翌年度、交付申請を辞退するため、記入しない。

Report

(2 results)
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • Research Products

    (34 results)

All 2018 2017 2016 Other

All Journal Article (15 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 14 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Int'l Joint Research: 9 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Electrothermally Triggered Broadband Optical Switch Films with Extremely Low Power Consumption2018

    • Author(s)
      Ryohei Yoshikawa, Mizuki Tenjimbayashi, and Seimei Shiratori
    • Journal Title

      ACS Applied Energy Materials

      Volume: 印刷中 Issue: 4 Pages: 1429-1434

    • DOI

      10.1021/acsaem.8b00251

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A new ‘sticking’ coating method for the in situ formation of nanofiber networks on micrometer to millimeter-sized surfaces2018

    • Author(s)
      Mizuki Tenjimbayashi, Ryohei Yoshikawa, Jun-Yong Park, Yuta Kobayashi, Yasuaki Monnai, Jun Muto, and Seimei Shiratori
    • Journal Title

      Nanoscale

      Volume: 印刷中 Issue: 14 Pages: 6277-6281

    • DOI

      10.1039/c8nr01613e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Facile synthesis of high electrical and ion conductivity junction-less 3D carbon sponge electrode for self-standing lithium ion battery anode2018

    • Author(s)
      Jyunichiro Abe, Yuta Kobayashi, Koki Kawase, Mizuki Tenjimbayashi, Seimei Shiratori
    • Journal Title

      RSC advances

      Volume: 8 Issue: 12 Pages: 6390-6396

    • DOI

      10.1039/c7ra12759f

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A Fluorine-free Slippery Surface with Hot Water Repellency and Improved Stability against Boiling2018

    • Author(s)
      Togasawa Ryo、Tenjimbayashi Mizuki、Matsubayashi Takeshi、Moriya Takeo、Manabe Kengo、Shiratori Seimei
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 10 Issue: 4 Pages: 4198-4205

    • DOI

      10.1021/acsami.7b15689

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Designing a Flexible and Transparent Ultrarapid Electrothermogenic Film Based on Thermal Loss Suppression Effect: A Self-Fused Cu/Ni Composite Junctionless Nanonetwork for Effective Deicing Heater2018

    • Author(s)
      Yoshikawa Ryohei、Tenjimbayashi Mizuki、Matsubayashi Takeshi、Manabe Kengo、Magagnin Luca、Monnai Yasuaki、Shiratori Seimei
    • Journal Title

      ACS Applied Nano Materials

      Volume: 1 Issue: 2 Pages: 860-868

    • DOI

      10.1021/acsanm.7b00268

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Lubricant-Sandwiched Coating with Long-Term Stable Anticorrosion Performance2018

    • Author(s)
      Tenjimbayashi Mizuki、Nishioka Sachiko、Kobayashi Yuta、Kawase Koki、Li Jiatu、Abe Jyunichiro、Shiratori Seimei
    • Journal Title

      Langmuir

      Volume: 34 Issue: 4 Pages: 1386-1393

    • DOI

      10.1021/acs.langmuir.7b03913

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bioinspired Hand-Operated Smart-Wetting Systems Using Smooth Liquid Coatings2017

    • Author(s)
      Tenjimbayashi Mizuki、Matsubayashi Takeshi、Moriya Takeo、Shiratori Seimei
    • Journal Title

      Langmuir

      Volume: 33 Issue: 50 Pages: 14445-14450

    • DOI

      10.1021/acs.langmuir.7b01600

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Liquid-Infused Smooth Surface for Improved Condensation Heat Transfer2017

    • Author(s)
      Tsuchiya Hirotaka、Tenjimbayashi Mizuki、Moriya Takeo、Yoshikawa Ryohei、Sasaki Kaichi、Togasawa Ryo、Yamazaki Taku、Manabe Kengo、Shiratori Seimei
    • Journal Title

      Langmuir

      Volume: 33 Issue: 36 Pages: 8950-8960

    • DOI

      10.1021/acs.langmuir.7b01991

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bioinspired Hydrogel-Coated Mesh with Superhydrophilicity and Underwater Superoleophobicity for Efficient and Ultrafast Oil/Water Separation in Harsh Environments2017

    • Author(s)
      Matsubayashi Takeshi、Tenjimbayashi Mizuki、Komine Masatsugu、Manabe Kengo、Shiratori Seimei
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 24 Pages: 7080-7085

    • DOI

      10.1021/acs.iecr.7b01619

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Oleophobic/Adhesive Janus Self-Standing Films Modified with Bifurcated Short Fluorocarbon Chains as Transparent Oil Stain-Free Coating with Attachability2017

    • Author(s)
      Nakashima Taichi、Tenjimbayashi Mizuki、Matsubayashi Takeshi、Manabe Kengo、Fujita Masato、Kamiya Takeshi、Honda Tsunetoshi、Shiratori Seimei
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 14 Pages: 3928-3936

    • DOI

      10.1021/acs.iecr.7b00164

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Droplet Motion Control on Dynamically Hydrophobic Patterned Surfaces as Multifunctional Liquid Manipulators2017

    • Author(s)
      Tenjimbayashi Mizuki、Higashi Masaki、Yamazaki Taku、Takenaka Issei、Matsubayashi Takeshi、Moriya Takeo、Komine Masatsugu、Yoshikawa Ryohei、Manabe Kengo、Shiratori Seimei
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 9 Issue: 12 Pages: 10371-10377

    • DOI

      10.1021/acsami.7b01641

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Improvement of heat transfer by promoting dropwise condensation using electrospun polytetrafluoroethylene thin films2017

    • Author(s)
      Hirotaka Tsuchiya, Kengo Manabe, Thomas Gaudelet, Takeo Moriya, Ken Suwabe, Mizuki Tenjimbayashi, Kyu-Hong Kyung, Frederic Gillot, and Seimei Shiratori
    • Journal Title

      New Journal of Chemistry

      Volume: 41 Issue: 3 Pages: 982-991

    • DOI

      10.1039/c6nj03566c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A biologically inspired attachable, self-standing nanofibrous membrane for versatile use in oil-water separation2016

    • Author(s)
      Mizuki Tenjimbayashi, Kaichi Sasaki, Takeshi Matsubayashi, Jyunichiro Abe, Kengo Manabe, Sachiko Nishioka, and Seimei Shiratori
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 21 Pages: 10922-10927

    • DOI

      10.1039/c6nr03349k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Liquid-infused smooth coating with transparency, super-durability, and extraordinary hydrophobicity2016

    • Author(s)
      Mizuki Tenjimbayashi, Ryo Togasawa, Kengo Manabe, Takeshi Matsubayashi, Takeo Moriya, Masatsugu Komine, and Seimei Shiratori
    • Journal Title

      Advanced Functional Materials

      Volume: 26 Issue: 37 Pages: 6693-6702

    • DOI

      10.1002/adfm.201602546

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] オムニフォビシティ滑液表面2016

    • Author(s)
      天神林 瑞樹, 守谷 赳夫, 白鳥 世明
    • Journal Title

      表面技術

      Volume: 67 Pages: 461-466

    • NAID

      130006094372

    • Related Report
      2016 Annual Research Report
  • [Presentation] Unidirectional Wetting Phenomenon on the Snake Scales2018

    • Author(s)
      Kohei Kawamura, Mizuki Tenjimbayashi, Daiki Watanabe, Daniel Citterio, Seimei Shiratori
    • Organizer
      255th American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Superhydrophobic and Hygroscopic Surface as an Effective Anti-icing Coating2018

    • Author(s)
      Hiroki Nakamura, Taku Yamazaki, Mizuki Tenjimbayashi, Seimei Shiratori
    • Organizer
      255th American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Extreme switch in wettability inspired by nature2017

    • Author(s)
      Mizuki Tenjimbayashi, Seimei Shiratori
    • Organizer
      6th Nagoya Biomimetics International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Control of dynamic wetting behaviors on smooth surface for liquid manipulator and slippery surface with multi functionality2017

    • Author(s)
      Mizuki Tenjimbayashi, Ryo Togasawa, Masaki Higashi, Seimei Shiratori
    • Organizer
      253rd American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Uloborus walckenaerius bioinspired attachable self-standing nanofibrous membrane for versatile use in oil water separation2017

    • Author(s)
      Mizuki Tenjimbayashi, Kaichi Sasaki, Jyunichiro Abe, Seimei Shiratori
    • Organizer
      253rd American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of antifreeze infused hydrophilic polymer/nanoparticle composite anti-icing coating for solar cells via spray Layer by Layer method2017

    • Author(s)
      T. Yamazaki, T. Moriya, T. Matsubayashi, M. Komine, M. Tenjimbayashi, S. Shiratori
    • Organizer
      253rd American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Single step dipping method of fabricating Fe3O4/PVDF-HFP composite porous material for magnetically controllable oil-water separation2017

    • Author(s)
      Jiatu Li, Mizuki Tenjimbayashi, Seimei Shiratori
    • Organizer
      253rd American Chemical Society NATIONAL MEETING & EXPOSITION
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of thermoresponsive nanofibers for cell separation2017

    • Author(s)
      Tomomi Konishi, Mizuki Tenjimbayashi, Jiatu Li, Kenta Homma, Ko Matsukawa, Aya Akimoto, Seimei Shiratori
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hybrid surface of hydrophobic nanoparticles and hygroscopic polymers for effective anti-icing applications2017

    • Author(s)
      Hiroki Nakamura, Taku Yamazaki, Mizuki Tenjimbayashi, Seimei Shiratori
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Uni-directional wetting properties on snake ventral scales2017

    • Author(s)
      Kohei Kawamura, Mizuki Tenjimbayashi, Ryo Togasawa, Seimei Shiratori
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] In Situ Monitoring of Cell Adhesion on Thermally Responsive Nanofiber Coatings Using Quartz Crystal Microbalance2017

    • Author(s)
      Jiatu Li, Mizuki Tenjimbayashi, Yuki Tokura, Ko Matsukawa, Kenta Homma, Aya Mizutani Akimoto and Seimei Shiratori
    • Organizer
      The 34th sensor symposium
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dynamic wettability control on smooth surface for liquid manipulator and slippery coating with multi-functionality2017

    • Author(s)
      天神林 瑞樹, 戸賀沢 稜, 東 昌樹, 白鳥 世明
    • Organizer
      日本化学会 第97回春季年会
    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Presentation] A BIOLOGICALLY INSPIRED ATTACHABLE, SELF-STANDING NANOFIBRE SHEET FOR VERSATILE USE IN OIL-WATER SEPARATION2016

    • Author(s)
      Mizuki Tenjimbayashi, Kaichi Sasaki, Jyunichiro Abe, Seimei Shiratori
    • Organizer
      2016 Asian Workshop on Polymer Processing
    • Place of Presentation
      Melbourne(Austoralia)
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] π電子相互作用により撥水液体を吸着した平坦表面2016

    • Author(s)
      天神林 瑞樹, 戸賀沢 稜, 白鳥 世明
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] エレクトロスピニング法による自立型ナノファイバーの作製と油水分離膜への応用2016

    • Author(s)
      天神林 瑞樹, 佐々木 開地, 阿部 純一郎, 真部 研吾, 白鳥 世明
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場 (兵庫県神戸市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fluorine-Free Slippery Surface with Hot Water Repellency and Durability against Boiling2016

    • Author(s)
      R. Togasawa, M. Tenjimbayashi, T. Matsubayashi, T. Moriya, K. Fujimoto, S. Shiratori
    • Organizer
      The Materials Research Society of Japan
    • Place of Presentation
      横浜開港記念会館(Yokohama, Kanagawa, Japan)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] ウェットプロセスナノコーティングによる超撥水・超親水性薄膜の作製2018

    • Author(s)
      Mizuki Tenjimbayashi, Seimei Shiratori
    • Total Pages
      8
    • Publisher
      Fine Chemical Japan
    • Related Report
      2017 Annual Research Report
  • [Remarks] マヨネーズも雪もはじく、慶大がはっ水技術 0.5度傾ければスルリ

    • URL

      https://www.nikkei.com/article/DGXLZO11461310Y7A100C1TJM000/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 白鳥研究室HP

    • URL

      https://www.appi.keio.ac.jp/shiratori/index.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2016-05-17   Modified: 2024-03-26  

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