| Project/Area Number |
16J11545
|
|---|
| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 国内 |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
朝 魯門 京都大学, 化学研究所, 特別研究員(PD)
|
|---|
| Project Period (FY) |
2016-04-22 – 2018-03-31
|
| Project Status |
Discontinued (Fiscal Year 2017)
|
| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2017: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2016: ¥1,200,000 (Direct Cost: ¥1,200,000)
|
|---|
| Keywords | Radical Anion / Dianion / CP-PAHs / the Scholl reaction / tetracene |
|---|
| Outline of Annual Research Achievements |
In this research, electron-deficient characters of cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAHs) have studied by lithium reduction. After Lithium reduction, radical anion and dianion crystals of benzene-fused tetracene were separated, which were confirmed by single crystal analysis. In addition radical anion of thiophene-fused tetracene was also separated in the same condition and analyzed by X-ray analysis. The study of electron accepting properties of CP-PAHs is of great important to investigate their potential application in the field of Li battery. The photopysical and electronic properties of these reduced species are in under investigation.
|
| Research Progress Status |
29年度が最終年度であるため、記入しない。
|
| Strategy for Future Research Activity |
29年度が最終年度であるため、記入しない。
|
