| Project/Area Number |
16K00659
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Design and evaluation of sustainable and environmental conscious system
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| Research Institution | Tokyo City University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
塩月 雅士 東京都市大学, 工学部, 准教授 (30362453)
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| Research Collaborator |
TAKASAKI masato
MOTOKI shunsaku
Hashimoto shudai
IWATA kazuma
TOKIWA yudai
OSADA naoki
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 分子レゴブロック / ケミカルリサイクル / 高分子合成 / 重合 / 解重合 / トリフェニルイミダゾール / ヘキサアリールビスイミダゾール / Diels-Alder反応 / アップグレードリサイクル / 物質循環システム / 環境材料 / 環境技術 |
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| Outline of Final Research Achievements |
Molecular LEGO blocks having two reversible covalent bond moieties were employed to synthesize corresponding molecular LEGO block polymers. Specifically, molecular LEGO blocks forming Diels-Alder adduct were synthesized. Moreover, molecular LEGO blocks having triphenylimidazole moieties were also synthesized. These molecular LEGO blocks were polymerized under various conditions. The resulting molecular LEGO block polymers were obtained in good yield. The molecular LEGO block polymers were depolymerized under various conditions. In the future, chemical recycling of polymer materials may become possible by this molecular LEGO block recycling system.
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| Academic Significance and Societal Importance of the Research Achievements |
分子レゴブロックという概念を利用したポリマーは、比較的高いリサイクル性を有することが明らかになったことからケミカルリサイクルに有効な手法になりうると期待される。このことは、高分子化学や環境科学の分野に有用な知見をもたらすことに加え、廃棄物処理の負荷低減、環境保全、温室効果ガスの排出抑制、循環型社会の構築に意義があると考えられる。
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