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Structure Visualization of Nano-PdH in a Non-Equilibrium State by Synchrotron X-ray Total Scattering

Research Project

Project/Area Number 16K04870
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nanostructural chemistry
Research InstitutionInstitute of Physical and Chemical Research

Principal Investigator

Kato Kenichi  国立研究開発法人理化学研究所, 放射光科学研究センター, 専任研究員 (90344390)

Research Collaborator Yamauchi Miho  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords放射光全散乱 / PDF解析 / 水素吸蔵 / 水素吸蔵ナノ粒子 / 全散乱 / 検出器 / 系統誤差 / ナノPd / 放射光 / ナノ粒子
Outline of Final Research Achievements

We developed a total-scattering measurement system, which enables us to observe both crystal structure and its disorder, and applied it to one of hydrogen-storing metals, nano-Pd. Consequently, we found that hydrogen absorption was accompanied by anisotropy in disorder form the Pd fcc-lattice. The results can be understood to mean that diffusible hydrogen prefers the Pd octahedral site to the tetrahedral, which suggest that the anisotropy is a key factor in hydrogen-storing properties.

Academic Significance and Societal Importance of the Research Achievements

水素はクリーンなエネルギー源としての活用が期待されている。その期待に応えるには、安全かつ高密度に水素を貯蔵し、使いたいときに容易に取り出すことができる水素吸蔵材料の開発が必要である。水素吸蔵材料を対象にした研究は多岐にわたっているが、本研究では水素吸蔵プロセスにおける微細な結晶構造変化に着目することで、吸蔵メカニズムに対する理解を一歩進めることができた。今後、さらに研究を進めることで吸蔵特性と微細構造との関係が明らかになることが期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (8 results)

All 2019 2018 2017

All Journal Article (2 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (6 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] A statistical approach to correct X-ray response non-uniformity in microstrip detectors for high-accuracy and high-resolution total-scattering measurements2019

    • Author(s)
      Kato Kenichi、Tanaka Yoshihito、Yamauchi Miho、Ohara Koji、Hatsui Takaki
    • Journal Title

      Journal of Synchrotron Radiation

      Volume: 26 Issue: 3 Pages: 762-773

    • DOI

      10.1107/s1600577519002145

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 放射光全散乱で見るナノ構造2017

    • Author(s)
      加藤健一
    • Journal Title

      化学工業

      Volume: 68 Pages: 575-579

    • Related Report
      2017 Research-status Report
  • [Presentation] データ駆動型全散乱によるナノ材料の機能解明に向けて2019

    • Author(s)
      加藤健一
    • Organizer
      第32回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] Proper measurements of total scattering for visualizing heterogeneous reactions2019

    • Author(s)
      Kato Kenichi
    • Organizer
      PDF workshop at SPring-8
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 全散乱計測に不可欠な検出器の系統誤差補正2018

    • Author(s)
      加藤健一
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 放射光X線回折による構造可視化の最前線2017

    • Author(s)
      加藤健一
    • Organizer
      セミナー"化学千一夜"「あすの化学への夢を語ろう」
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Improving total scattering data in statistics through detector intensity calibration2017

    • Author(s)
      加藤健一
    • Organizer
      24th Congress and General Assembly of the International Union of Crystallography
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] マルチスケール高分解能PDF解析に向けた検出器の系統誤差補正2017

    • Author(s)
      加藤健一
    • Organizer
      平成29年度第1回放射光利用研究セミナー 兼 平成29年度第1回結晶PDF解析研究会
    • Related Report
      2017 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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