• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Thermal conductivity of giant magnetocaloric materials showing a first-order magnetic transition

Research Project

Project/Area Number 16K04932
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials
Research InstitutionKyushu University

Principal Investigator

Wada Hirofumi  九州大学, 理学研究院, 教授 (80191831)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords巨大磁気熱量効果 / 熱伝導 / 磁気冷凍 / 一次相転移 / 熱伝導度 / 磁気熱量効果 / 磁性
Outline of Final Research Achievements

We have studied the temperature dependence of the thermal conductivity \lambda of Mn-based giant magnetocaloric materials showing the first-order magnetic transition (FOMT) near room temperature. First, we synthesized high-quality (MnFeRu)2(PSi) samples by changing the compositions and the annealing temperature.
The thermal conductivity of (MnFeRu)2(PSi) is abruptly reduced on the first cooling due to the micro-cracks generated during the FOMT. On heating, the thermal conductivity smoothly increases with increasing temperature. It was found that the \lambda- T curve is not sensitive to the thermal cycle after the first cooling. This means that fewer micro-cracks were generated at subsequent phase transitions.The \lambda - T curves have small humps near the Curie temperature. We have proposed that the coexistence of a two-phase region by alloying is responsible for the humps in the \lambda - T curve.

Academic Significance and Societal Importance of the Research Achievements

本研究の意義は巨大磁気熱量効果を示すMn化合物について良質な試料を作製する最適条件を得たことと,熱伝導度の値が室温で2 W/m K程度であることを明らかにしたことである.前者は材料開発に,後者は磁気冷凍システムの開発に重要な情報を与えるものである.また,学術的な意義としては,熱伝導に対する格子,磁気,電子の寄与の温度依存性を考察することにより,一次相転移を示す磁性体のキュリー温度近傍の熱伝導異常に初めて物理的な説明を与えたことである.これは一次相転移を示す磁性体一般に適用できるので,その意義は大きい.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (14 results)

All 2019 2018 2017 2016

All Journal Article (6 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (8 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results)

  • [Journal Article] Thermal conductivity of giant magnetocaloric Mn compounds2019

    • Author(s)
      Wada Hirofumi、Fukuda Kosuke、Ohnishi Takayuki、Soejima Kei、Otsubo Kensuke、Yamashita Keiichiro
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 785 Pages: 445-451

    • DOI

      10.1016/j.jallcom.2019.01.188

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transport Properties of EuNi2Ge2 under High Pressure2018

    • Author(s)
      H. Wada, Y. Goki , A. Mitsuda
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 87 Issue: 3 Pages: 034707-034707

    • DOI

      10.7566/jpsj.87.034707

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetocaloric properties of (MnFeRu)2(PSi) as magnetic refrigerants near room temperature2017

    • Author(s)
      Takayuki Ohnishi, Kei Soejima, Keiichiro Yamashita and Hirofumi Wada
    • Journal Title

      Magnetochemistry

      Volume: 3 Issue: 1 Pages: 6-6

    • DOI

      10.3390/magnetochemistry3010006

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-field transport properties of itinerant electron metamagnetic Co(S1-xSex)22016

    • Author(s)
      Hirofumi Wada, Yoshiro Maekawa, Daichi Kawasaki
    • Journal Title

      Journal of Science: Advanced Materials and Devices

      Volume: 1 Issue: 2 Pages: 179-184

    • DOI

      10.1016/j.jsamd.2016.06.001

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetocaloric properties of (MnFe)2PGe and (MnFe)2PSi compounds fabricated by a melting method2016

    • Author(s)
      M. Hirashima and H. Wada
    • Journal Title

      AIP Conference Proceedings

      Volume: 1763 Pages: 020004-020004

    • DOI

      10.1063/1.4961337

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 固体の熱量効果による冷却技術2016

    • Author(s)
      I. タケウチ,K. サンデマン, 和田裕文 (訳)
    • Journal Title

      パリティ

      Volume: 31(11) Pages: 4-12

    • Related Report
      2016 Research-status Report
  • [Presentation] 遍歴電子メタ磁性体La(Fe1-xSix)13 のホール抵抗測定2019

    • Author(s)
      田邉巧祐, 光田暁弘, 和田裕文
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] EuRh2Si2 の圧力下ホール抵抗測定2019

    • Author(s)
      大山耕平, 光田暁弘, 和田裕文
    • Organizer
      日本物理学会第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ErCo2の高圧下のホール効果2017

    • Author(s)
      鳩山慎太郎, 和田裕文, 光田暁弘
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] EuT2P2(T=Ni,Co)の磁場中輸送現象2017

    • Author(s)
      田邉巧祐, 山本伊吹, 光田暁弘, 和田裕文
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Transport property of EuT2P2 (T = Ni, Co) in magnetic field2017

    • Author(s)
      K. Tanabe
    • Organizer
      International Workshop on Multipole Physics and Related Phenomena
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 巨大磁気熱耐効果を持つ Mn 系化合物の熱伝導度測定2017

    • Author(s)
      福田光祐,和田裕文
    • Organizer
      第123回日本物理学会九州支部例会
    • Related Report
      2017 Research-status Report
  • [Presentation] 巨大磁気熱量効果を示すMn化合物の磁性2017

    • Author(s)
      和田裕文
    • Organizer
      平成28年度磁性材料研究会
    • Place of Presentation
      東京エッサム神田ホール
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 磁気熱量効果と磁気冷凍―材料の立場から2016

    • Author(s)
      和田裕文
    • Organizer
      日本冷凍空調学会 2016年度年次大会
    • Place of Presentation
      神戸大学
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
    • Invited

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi